河南科技大学材料科学与工程学院;河南省科学院;
Cu-Ni-Si系合金以其优异的导电率、强度和抗应力松弛性能,已成为电子信息、新能源汽车和航空航天等领域中不可或缺的关键材料。然而,高性能Cu-Ni-Si系合金的成分设计优化、制备加工工艺的改进以及综合性能协同提升机制的探索等方面仍面临诸多挑战。因此本文通过对近年来Cu-Ni-Si系合金的科研成果进行分析总结,深入探讨了合金元素的种类、含量及其配比,以及形变热处理工艺对其导电率、强度和抗应力松弛性能的影响及作用机理,并对其未来的研究方向进行了展望。
63 | 0 | 18 |
下载次数 | 被引频次 | 阅读次数 |
[1] Li Y H,Chen S F,Song H W,et al.Enhanced mechanical properties and strengthening mechanism of Cu-Ni-Si alloy with trace chromium addition[J].Materials Today Communications,2024,38:107729.
[2] Ma M,Li Z,Xiao Z,et al.Microstructure and properties of Cu-Ni-Co-Si-Cr-Mg alloys with different Si contents after multi-step thermo-mechanical treatment[J].Materials Science and Engineering A,2022,850:143532.
[3] Carral á.D,Xu X,Gravelle S,et al.Stability of binary precipitates in Cu-Ni-Si-Cr alloys investigated through active learning[J].Materials Chemistry and Physics,2023,306:128053.
[4] Kim H,Ahn J H,Han S Z,et al.Microstructural characterization of cold-drawn Cu-Ni-Si alloy having high strength and high conductivity[J].Journal of Alloys and Compounds,2020,832:155059.
[5] Gholami M,Vesely J,Altenberger I,et al.Effects of microstructure on mechanical properties of CuNiSi alloys[J].Journal of Alloys and Compounds,2017,696:201-212.
[6] Sun Y Q,Peng L J,Huang G J,et al.Effect of Mg on the stress relaxation resistance of Cu-Cr alloys[J].Materials Science and Engineering A,2021,799:140144.
[7] Yi J,Jia Y L,Zhao Y Y,et al.Precipitation behavior of Cu-3.0Ni-0.72Si alloy[J].Acta Materialia,2019,166:261-270.
[8] Geng Y F,Li X,Zhou H L,et al.Effect of Ti addition on microstructure evolution and precipitation in Cu-Co-Si alloy during hot deformation[J].Journal of Alloys and Compounds,2020,821:153518.
[9] Hu T,Chen J H,Liu J Z,et al.The crystallographic and morphological evolution of the strengthening precipitates in Cu-Ni-Si alloys[J].Acta Materialia,2013,61(4):1210-1219.
[10] 李周,肖柱,姜雁斌,等.高强导电铜合金的成分设计、相变与制备[J].中国有色金属学报,2019,29(9):2009-2049.LI Zhou,XIAO Zhu,JIANG Yan-bin,et al.Composition design,phase transition and fabrication of copper alloys with high strength and electrical conductivity[J].The Chinese Journal of Nonferrous Metals,2019,29(9):2009-2049.
[11] Corson M G.Electrical conductor alloy[J].Electrical World,1927,83(1):137-139.
[12] Li J,Huang G J,Mi X J,et al.Influence of the Ni/Co mass ratio on the microstructure and properties of quaternary Cu-Ni-Co-Si alloys[J].Materials (Basel),2019,12(18):2855-2872.
[13] Ozawa A,Watanabe C,Monzen R.Influence of Co on strength of Cu-Ni-Co-Si alloy[J].Materials Science Forum,2014,783-786:2468-2473.
[14] Ban Y J,Zhang Y,Tian B H,et al.EBSD analysis of hot deformation behavior of Cu-Ni-Co-Si-Cr alloy[J].Materials Characterization,2020,169:110656.
[15] Geng Y F,Ban Y J,Li X,et al.Excellent mechanical properties and high electrical conductivity of Cu-Co-Si-Ti alloy due to multiple strengthening[J].Materials Science and Engineering A,2021,821:141639.
[16] Huang J Z,Xiao Z,Dai J,et al.Microstructure and properties of a novel Cu-Ni-Co-Si-Mg alloy with super-high strength and conductivity[J].Materials Science and Engineering A,2019,744:754-763.
[17] Li J,Huang G J,Mi X J,et al.Effect of Ni/Si mass ratio and thermomechanical treatment on the microstructure and properties of Cu-Ni-Si Alloys[J].Materials (Basel),2019,12(13):2076.
[18] Wang W,Kang H J,Chen Z N,et al.Effects of Cr and Zr additions on microstructure and properties of Cu-Ni-Si alloys[J].Materials Science and Engineering A,2016,673:378-390.
[19] Wang C S,Fu H D,Jiang L,et al.A property-oriented design strategy for high performance copper alloys via machine learning[J].npj Computational Materials,2019,5(1):87-94.
[20] 山本佳紀,佐々木元,太田真,et al.Development of high strength copper alloy for lead frames HCL 305[J].Journal of the Japan Copper and Brass Research Association,1999,38:204-208.
[21] 曹祎程.铜镍硅合金的不连续相演变行为及强化机理研究[D].北京:北京有色金属研究总院,2022.CAO Yi-cheng.Study on discontinuous precipitate evolution behavior and strengthening mechanism of Cu-Ni Si alloy[D].Beijing:General Research Institute for Nonferrous Metals,2022.
[22] Lei Q,Li Z,Pan Z Y,et al.Dynamics of phase transformation of Cu-Ni-Si alloy with super-high strength and high conductivity during aging[J].Transactions of Nonferrous Metals Society of China,2010,20(6):1006-1011.
[23] Lei Q,Xiao Z,Hu W P,et al.Phase transformation behaviors and properties of a high strength Cu-Ni-Si alloy[J].Materials Science and Engineering A,2017,697:37-47.
[24] Han S Z,Choi E A,Lim S H,et al.Alloy design strategies to increase strength and its trade-offs together[J].Progress in Materials Science,2021,117:100720.
[25] Han S Z,Lim S H,Kim S H,et al.Increasing strength and conductivity of Cu alloy through abnormal plastic deformation of an intermetallic compound[J].Scientific Reports,2016,6:30907.
[26] Semboshi S,Sato S,Iwase A,et al.Discontinuous precipitates in age-hardening CuNiSi alloys[J].Materials Characterization,2016,115:39-45.
[27] Han S Z,Ahn J H,You Y S,et al.Discontinuous precipitation at the deformation band in copper alloy[J].Metals and Materials International,2018,24(1):23-27.
[28] Ahn J H,Han S Z,Choi E A,et al.Simple optimization for strength and conductivity of Cu-Ni-Si alloy with discontinuous precipitation[J].Materials Characterization,2022,184:111605.
[29] 李冬梅,韩敬宇,董闯.高硬导电 Cu-Ni-Si 系铜合金强化相成分设计[J].物理学报,2019,68(19):196102.LI Dong-Mei,HAN Jing-yu,DONG Chuang.Phase-composition design of high-hardness and high-electric-conductivity Cu-Ni-Si Alloy[J].Acta Physica Sinica,2019,68(19):196102.
[30] Soldi L,Laplace A,Roskosz M,et al.Phase diagram and thermodynamic model for the Cu-Si and the Cu-Fe-Si systems[J].Journal of Alloys and Compounds,2019,803:61-70.
[31] Lei C H,Yang H Y,Zhao F,et al.Effect of Co addition on hardness and electrical conductivity of Cu-Si alloys[J].Journal of Materials Science,2021,56(26):14821-14831.
[32] Zhao F,Lei C H,Yu J,et al.Effects of Co/Si atomic ratio on hardness and electrical conductivity of Cu-Co-Si alloys[J].Advanced Engineering Materials,2022,25(6):2201241.
[33] Li J,Huang G J,Mi X J,et al.Microstructure evolution and properties of a quaternary Cu-Ni-Co-Si alloy with high strength and conductivity[J].Materials Science and Engineering A,2019,766:138390.
[34] 常君,王明飞,接金川,等.Ni/Co质量比对Cu-Ni-Co-Si合金组织和性能的影响[J].中国有色金属学报,2023,33(10):3215-3228.CHANG Jun,WANG Ming-fei,JIE Jin-chuan,et al.Effects of Ni/Co mass ratio on microstructure and properties of Cu-Ni-Co-Si alloy[J].The Chinese Journal of Nonferrous Metals,2023,33(10):3215-3228.
[35] 肖翔鹏.新型高性能Cu-Ni-Co-Si合金制备及组织性能的研究[D].北京:北京有色金属研究总院,2013.XIAO Xiang-peng.Research on fabrication,microstructure and properties of Cu-Ni-Co-Si alloy with high performance[D].Beijing:General Research Institute for Nonferrous Metals,2013.
[36] Zhang H T,Fu H D,Zhu S C,et al.Machine learning assisted composition effective design for precipitation strengthened copper alloys[J].Acta Materialia,2021,215:117118.
[37] Lu L,Shen Y F,Chen X H,et al.Ultrahigh strength and high electrical conductivity in copper[J].Science,2004,304(5669):422-426.
[38] 李亚萍.新型高强高导Cu-Mg-Ca合金的制备与组织性能[D].长沙:中南大学,2017.LI Ya-ping.Microstructure and properties of a novel Cu-Mg-Ca alloy with high strength and high electrical conductivity[D].Changsha:Central South University,2017.
[39] 李冬梅.高强导电Cu-Ni-Si合金的成分与性能关联研究[D].大连:大连理工大学,2019.LI Dong-mei.Correlation between compositions and properties of high strength and conductive Cu-Ni-Si alloys[D].Dalian:Dalian University of Technology,2019.
[40] 周孟,饶劢攀,刘勇,等.Zr含量对Cu-Ni-Si-Co-Zr合金热变形行为的影响[J].材料热处理学报,2022,43(11):180-189.ZHOU Meng,RAO Mai-pan,LIU Yong,et al.Effect of Zr content on hot deformation behavior of Cu-Ni-Si-Co-Zr alloy[J].Transactions of Materials and Heat Treatment,2022,43(11):180-189.
[41] Wei H,Chen Y L,Zhao Y N,et al.Correlation mechanism of grain orientation/microstructure and mechanical properties of Cu-Ni-Si-Co alloy[J].Materials Science and Engineering A,2021,814:141239.
[42] Monzen R,Watanabe C.Microstructure and mechanical properties of Cu-Ni-Si alloys[J].Materials Science and Engineering A,2008,483-484:117-119.
[43] 王俊峰,贾淑果,陈少华,等.时效对热轧态Cu-Ni-Si-Mg合金组织和性能的影响[J].材料热处理学报,2013,34(S2):70-73.WANG Jun-feng,JIA Shu-guo,CHEN Shao-hua,et al.Effects of aging on microstructure and properties of hot-rolled Cu-Ni-Si-Mg alloy[J].Transactions of Materials and Heat Treatment,2013,34(S2):70-73.
[44] Kim H G,Lee T W,Kim S M,et al.Effects of Ti addition and heat treatments on mechanical and electrical properties of Cu-Ni-Si alloys[J].Metals and Materials International,2013,19(1):61-65.
[45] Lee E,Euh K,Han S Z,et al.Tensile and electrical properties of direct aged Cu-Ni-Si-x%Ti alloys[J].Metals and Materials International,2013,19(2):183-188.
[46] Lei Q,Li Z,Dai C,et al.Effect of aluminum on microstructure and property of Cu-Ni-Si alloys[J].Materials Science and Engineering A,2013,572:65-74.
[47] Lei Q,Li S Y,Zhu J L,et al.Microstructural evolution,phase transition,and physics properties of a high strength Cu-Ni-Si-Al alloy[J].Materials Characterization,2019,147:315-323.
[48] Cheng J Y,Tang B B,Yu F X,et al.Evaluation of nanoscaled precipitates in a Cu-Ni-Si-Cr alloy during aging[J].Journal of Alloys and Compounds,2014,614:189-195.
[49] Wu Y K,Li Y,Lu J Y,et al.Correlations between microstructures and properties of Cu-Ni-Si-Cr alloy[J].Materials Science and Engineering A,2018,731:403-412.
[50] Watanabe C,Nishijima F,Monzen R,et al.Mechanical properties of Cu-4.0wt%Ni-0.95wt%Si alloys with and without P and Cr addition[J].Materials Science Forum,2007,561-565:2321-2324.
[51] 李钊.微量Sn对Cu-3Ni-0.75Si合金组织与性能影响研究[D].赣州:江西理工大学,2020.LI Zhao.Effect of trace Sn on mierostructure and properties of Cu-3Ni-0.75Si alloy[D].Ganzhou:Jiangxi University of Science and Technology,2020.
[52] Liao W N,Yang H Q,Yi C,et al.Effect and mechanism of cold rolling and aging process on microstructure and properties of columnar grain C70250 copper alloy[J].Materials Science and Engineering A,2022,833:142577.
[53] Liao W N,Liu X F,Yang Y H.Relationship and mechanism between double cold rolling-aging process,microstructure and properties of Cu-Ni-Si alloy prepared by two-phase zone continuous casting[J].Materials Science and Engineering A,2020,797:140148.
[54] Wang C S,Fu H D,Zhang H T,et al.Simultaneous enhancement of mechanical and electrical properties of Cu-Ni-Si alloys via thermo-mechanical process[J].Materials Science and Engineering A,2022,838:142815.
[55] Zhao Z L,Xiao Z,Li Z,et al.Microstructure and properties of a Cu-Ni-Si-Co-Cr alloy with high strength and high conductivity[J].Materials Science and Engineering A,2019,759:396-403.
[56] Qin L X,Zhou T,Jiang X Y,et al.Microstructure and properties of Cu-Ni-Co-Si-Cr-Mg alloy by multistage thermomechanical treatment[J].Transactions of Nonferrous Metals Society of China,2023,33(12):3739-3755.
[57] 黄海鹏.形变热处理对Cu-Ni-Si系合金组织与性能的影响[D].福州:福州大学,2021.HUANG Hai-peng.Effects of thermomechanical treatment processing on microstructure and properties of Cu-Ni-Si alloy[D].Fuzhou:Fuzhou University,2021.
[58] 单运启,张彦敏,张朝民,等.形变热处理对Cu-Ni-Si合金组织性能的影响[J].材料热处理学报,2024,45(1):95-102.SHAN Yun-qi,ZHANG Yan-min,ZHANG Chao-min,et al.Effect of thermomechanical treatment on microstructure and properties of Cu-Ni-Si alloy[J].Transactions of Materials and Heat Treatment,2024,45(1):95-102.
[59] Li S,Li Z,Xiao Z,et al.Microstructure and property of Cu-2.7Ti-0.15Mg-0.1Ce-0.1Zr alloy treated with a combined aging process[J].Materials Science and Engineering A,2016,650:345-353.
[60] Liu P,Kang B X,Cao X G,et al.Strengthening mechanisms in a rapidly solidified and aged Cu-Cr alloy[J].Journal of Materials Science,2000,35:1691-1694.
[61] Humphreys F J,Hirsch P B.The deformation of single crystals of copper and copper-zinc alloys containing alumina particles.ii.microstructure and dislocation-particle interactions[J].Proceedings of the Royal Society of London Series A,Mathematical and Physical Sciences,1970,318(1532):73-92.
[62] 张龙.Cu-Ni-Si合金回归工艺研究[D].长沙:中南大学,2014.ZHANG Long.Regression technique research of Cu-Ni-Si alloy[D].Changsha:Central South University,2014.
[63] Du Y B,Zhou Y J,Song K X,et al.Influence of trace silicon addition on the strengthening precipitates,mechanical properties and stress relaxation resistance of Cu-Cr alloy[J].Journal of Alloys and Compounds,2023,948:169619.
[64] Fox A.Stress relaxation in bending of copper beryllium alloy strip[J].Journal of Testing and Evaluation,1980,8(3):119-126.
[65] 潘素平.Ti-55511合金疲劳和应力松弛过程中的组织演变和性能衰减[D].长沙:中南大学,2022.PAN Su-ping.Microstructure evolution and mechanical property decay in Ti-55511 alloy during fatigue and stress relaxation[D].Changsha:Central South University,2022.
[66] 肖翔鹏,柳瑞清,陈辉明,等.Co对CuNiSi合金应力松弛行为的影响[J].材料导报,2015,29(10):148-151.XIAO Xiang-peng,LIU Rui-qing,CHEN Hui-ming,et al.Effects of Co on the stress relaxation behavior of CuNiSi alloy[J].Materials Review,2015,29(10):148-151.
[67] Xiao X P,Xu H,Huang J F,et al.Stress relaxation properties and microscopic deformation structure in bending of the C7025 and C7035 alloy[J].Crystals,2018,8(8):324-333.
[68] Lin H R,Shao H F,Zhang Z J,et al.Stress relaxation behaviors and mechanical properties of precipitation strengthening copper alloys[J].Journal of Alloys and Compounds,2021,861:158537.
[69] 刘峰,米绪军,马吉苗,等.低浓度Cu-Ni-Si合金的组织与性能[J].中国有色金属学报,2019,29(2):286-294.LIU Feng,Ml Xu-jun,MA Ji-miao,et al.Microstructure and properties of low concentration of Cu-Ni-Si alloy[J].The Chinese Journal of Nonferrous Metals,2019,29(2):286-294.
[70] Shan Y Q,Zhang Y M,Zhang C M,et al.Study on the microstructure and mechanism of stress relaxation behavior of Cu-Ni-Si alloy by two-stage rolling deformation[J].Materials Science and Engineering A,2024:146946.
[71] 杨耀鹏,张彦敏,王要利,等.时效处理对Cu-Ni-Si合金应力松弛行为影响研究[J].特种铸造及有色合金,2023,43(9):1230-1234.YANG Yao-peng,ZHANG Yan-min,WANG Yao-li,et al.Effects of aging process on stress relaxation behavior of Cu-Ni-Si alloy[J].Special Casting & Nonferrous Alloys,2023,43(9):1230-1234.
[72] Fox A.Stress Relaxation Testing[M].West Conshohocken:ASTM International,1979.
[73] 李江.新型高强高弹铜镍硅系合金制备及其微观组织性能的研究[D].北京:北京科技大学,2020.LI Jiang.Study on preparation,microstructure and properties of the new Cu-Ni-Si alloys with high strength and high elasticity[D].Beijing:University of Science and Technology Beijing,2020.
[74] 曹延峰.Cu-0.23Cr-0.08Ag合金连续挤压工艺优化与应力松弛行为研究[J].赣州:江西理工大学,2020.CAO Yan-feng.Continuous extrusion process simulation and stress relaxation optimization of Cu-0.23Cr-0.08Ag alloy[D].Ganzhou:Jiangxi University of Science and Technology,2020.
[75] Butt M Z,Khiliji M S.On the strength and stress-relaxation response of fine-grain Cu-42.2at.%Zn-0.6at.%Pb alloy polycrystals[J].Journal of Alloys and Compounds,2009,479(1/2):252-256.
基本信息:
DOI:10.13289/j.issn.1009-6264.2024-0343
中图分类号:TG146.11
引用信息:
[1]冯江,张彦敏,周延军等.高性能Cu-Ni-Si系合金成分设计与性能研究进展[J].材料热处理学报,2025,46(05):1-14.DOI:10.13289/j.issn.1009-6264.2024-0343.
基金信息:
河南省科技攻关项目(242102231023); 国家自然科学基金(52373313,52173297); 河南省科技重大专项(221100210300); 河南省科学院研发项目(220910009)