2,982 | 149 | 70 |
下载次数 | 被引频次 | 阅读次数 |
综述了国内外高强镁合金的最新研发现状,分析了高强镁合金的强化机理,简单介绍了高强镁合金的新型制备技术及其在工业中的应用,探讨了高强镁合金强化中存在的问题,最后,展望了高性能镁合金的发展趋势。
Abstract:The research and development of latest high-strength magnesium alloys was reviewed.The microstructure,strengthening mechanism,preparation technology,industrial application as well as some key problems of high-strength magnesium alloy were illustrated.Finally,the future research direction of high-strength magnesium alloys is proposed.
[1]陈礼清,赵志江.从镁合金在汽车及通讯电子领域的应用看其发展趋势[J].世界有色金属,2004(7):12-20.CHEN Li-qing,ZHAO Zhi-jiang.Trend of development of magnesium alloy in automobile and electronic product[J].World Nonferrous Metals,2004(7):12-20.
[2]黄晓燕,周宏.镁合金的研究应用及最新进展[J].材料与冶金学报,2003,2(4):300-306.HUANG Xiao-yan,ZHOU Hong.Microstructure and high-temperature mechanical properties of Mg-6Al magnesium alloy containing yttrium[J].Journal of Materials and Metallurgy,2003,2(4):300-306.
[3]史文方,周昆.我国镁合金的开发应用现状及展望[J].汽车工艺与材料,2004(4):32-37.SHI Wen-fang,ZHOU Kun.The application and outlook of magnesium alloy development in China[J].Automobile Technology and Material,2004(4):32-37.
[4]唐全波,黄少东,伍太宾.镁合金在武器装备中的应用分析[J].兵器材料科学与工程,2007,30(2):69-71.TANG Quan-bo,HUANG Shao-dong,WU Tai-bin.Application analysis of magnesium alloys in weapon components[J].Ordnance Material Scienceand Engineering,2007,30(2):69-71.
[5]吉泽升.日本镁合金研究进展及新技术[J].中国有色金属学报,2004,14(12):1977-1984.JI Ze-sheng.Research process and new technology of magnesium alloy in Japan[J].The Chinese Journal of Nonferrous Metals,2004,14(12):1977-1984.
[6]刘静安,盛春磊.镁及镁合金的应用及市场发展前景[J].有色金属加工,2007,36(2):1-6.LIU Jing-an,SHENG Chun-lei.Application and Market prospect of magnesium and magnesium alloys[J].Nonferrous Metals Processing,2007,36(2):1-6.
[7]Eliezer D,Aghion E,Froes F H.Magnesium science,technology and applications[J].Advanced Performance Materials,1998(5):201-212.
[8]房灿峰,张兴国,于延浩,等.镁合金的性能、成形技术及其应用研究[J].金属热处理,2006,31(3):12-16.FANG Can-feng,ZHANG Xing-guo,YU Yan-hao,et al.Properties and forming technology of magnesium alloys and its application[J].Heat Treatmentof Metals,2006,31(3):12-16.
[9]于文斌,刘志义,程南璞,等.稀土变形镁合金的研究与开发[J].材料导报,2006,20(11):65-72.YU Wen-bin,LIU Zhi-yi,CHENG Nan-pu,et al.Research and development of wrought magnesium alloy containing rare earth elements[J].MaterialsReview,2006,20(11):65-72.
[10]彭光怀,张小联,邱承洲.稀土镁合金的研究进展[J].江西有色金属,2006,20(3):27-30.PENG Guang-huai,ZHANG Xiao-lian,QIU Cheng-zhou.The latest development of rare earth magnesium alloy research[J].Jiangxi NonferrousMetals,2006,20(3):27-30.
[11]李大全,王渠东,丁文江.稀土在变形镁合金中的应用[J].轻合金加工技术,2006,34(2):9-12.LI Da-quan,WANG Qu-dong,DING Wen-jiang.Application of rare earth metals in wrought magnesium alloy[J].Light Alloy Fabrication Technology,2006,34(2):9-12.
[12]王荣滨.稀土在镁合金中的作用与应用研究[J].有色金属加工,2007,36(1):27-29.WANG Rong-bin.Roles of RE in magnesium alloys and application of RE magnesium alloys[J].Nonferrous Metals Processing,2007,36(1):27-29.
[13]Chino Y,Lee J S,Nakaura Y.Mechanical properties of Mg-Al-Ca alloy recycled by solid-stale recycling[J].Material Transctions,2005,46(12):2592-2595.
[14]Wook K Y.Microstructure and mechanical properties of rapidly solidified Mg-Al-Zn-MM alloys[J].Journal of Material Science and Technology,2008,24(1):89-92.
[15]陈振华.镁合金[M].北京.化学工业出版社,2004:29.
[16]夏鹏举,蒋百灵,张菊梅,等.Mg-Al系镁合金离异共晶β相的研究[J].特种铸造及有色合金,2007,27(5):360-363.XIA Peng-ju,JIANG Bai-ling,ZHANG Ju-mei,et al.Divorced eutecticβphase in Mg-Al series magnesium alloy[J].Special Casting and NonferrousAlloys,2007,27(5):360-363.
[17]Nami B,Shabestari S G,Razavi H,et al.Effect of Ca,RE element and semi-solid processing on the microstructure and creep properties of AZ91 alloy[J].Materials Science and Engineering A,2011,528:1261-1267.
[18]Esgandari B A,Mehrjoo H,Nami B.The effect of Ca and RE elements on the precipitation kinetics of Mg17 Al12 phase during artificial aging ofmagnesium alloy AZ91[J].Materials Science and Engineering A,2011,528:5018-5024.
[19]Candan S,Unal M,Koc E,et al.Effect of titanium addition on mechanical and corrosion behaviours of AZ91 magnesium alloy[J].Journal of Alloysand Compounds,2011,509:1958-1963.
[20]Luo A,Pekguleryuz M Z.Review cast magnesium alloys for elevated temperature applications[J].Journal of Materials Science,1994,29:5259-5271.
[21]刘子利,丁文江,袁广银.镁铝基耐热铸造镁合金的进展[J].机械工程材料,2001,25(11):1-4.LIU Zi-li,DING Wen-jiang,YUAN Guang-yin.Survey of the Mg-Al based elevated temperature magnesium casting alloys[J].Mechanical EngineeringMaterials,2001,25(11):1-4.
[22]Ma G R,Li X L,Wang X.Modification of Mg2Si morphology in Mg-9%Al-0.7%Si alloy by the SIMA process[J].Materials Characterization,2011,62:360-366.
[23]杨明波,潘复生,白亮,等.合金元素对Mg-Al-Si系镁合金中Mg2Si相形貌影响的研究进展[J].热加工工艺,2007,36(14):71-74.YANG Ming-bo,PAN Fu-sheng,BAI Liang,et al.Development of effects of alloy elements on morpohoty of Mg2Si phase in Mg-Al-Si based magnesiumalloys[J].Hot Working Technology,2007,36(14):71-74.
[24]宫宁宁,张兴国,郝海,等.钙对Mg-6Al变形镁合金显微组织和拉伸性能的影响[J].机械工程材料,2008,32(9):20-23.GONG Ning-ning,ZHANG Xing-guo,HAO Hai,et al.Effect of calcium on microstructure and tensile properties of Mg-6Al wrought magnesium alloy[J].Materials for Mechanical Engineering,2008,32(9):20-23.
[25]Ninomiya R,Ojiro T,Kubopta K.Improved heat Resistance of Mg-Al alloys by the Ca addition[J].Acta Metallurgica et Materialia,1995,43(2):669-674.
[26]Pekguleryuz M O,Kaya A A.Creep resistant magnesium alloys for powetrain application[J].Advanced Engineering Materials,2002,5(12):74-93.
[27]Wang Q D,Chen W H,Zeng X Q.Effects of Ca addition on the microstructure and mechanical properties of AZ91 magnesium ally[J].Journal ofMaterial Science,2001,36:3035-3040
[28]Xu S W,Kamado S,Uchida F,et al.High-strength extruded Mg-Al-Ca-Mn alloy[J].Scripta Materialia,2011,65:269-272.
[29]Zhang J,Ma Q,Pan F S.Effects of trace Er addition on the microstructure and mechanical properties of Mg-Zn-Zr alloy[J].Materials and Design,2010,31:4043-4049.
[30]Bai Y,Fang C F,Hao H.Effects of yttrium on microstructure and mechanical properties of Mg-Zn-Cu-Zr alloys[J].Transactions of Nonferrous MetalsSociety of China,2010,20(2):357-360.
[31]Oh-ishi K,Mendis C L,Homma T.Bimodally grained microstructure development during hot extrusion of Mg-2.4 Zn-0.1 Ag-0.1 Ca-0.16 Zr(at.%)alloys[J].Acta Materialia,2009,57(18):5593-5604.
[32]Zhang J,Zhang X F,Li W G.Partition of Er among the constituent phases and the yield phenomenon in a semi-continuously cast Mg-Zn-Zr alloy[J].Scripta Materialia,2010,63(4):367-370.
[33]Zhou T,Chen D,Chen Z H.Microstructures and properties of rapidly solidified Mg-Zn-Ca alloys[J].Transactions of Nonferrous Metals Society ofChina,2008,18(1):101-106.
[34]孙明,吴国华,戴吉春.Zr在镁合金中晶粒细化行为研究进展[J].铸造,2010,59(3):255-259.SUN Ming,WU Guo-hua,DAI Ji-chun.Current research status of grain refinement effect of Zr on magnesium alloy[J].Foundry,2010,59(3):255-259.
[35]陈增,张密林,吕艳卓.锆在镁及镁合金中的作用[J].铸造技术,2007,28(6):820-822.CHEN Zeng,ZHANG Mi-lin,LYan-zhuo.Role of zirconium in magnesium and magnesium alloys[J].Foundry Technology,2007,28(6):820-822.
[36]陈敬区,刘江文.Mg-Zn系合金G.P.区和时效强化的研究进展[J].材料导报,2008,22:342-345.CHEN Jing-qu,LIU Jiang-wen.Research and development of G.P.zones and aging strengthening of Mg-Zn alloys[J].Materials Review,2008,22:342-345.
[37]李萧,刘江文,罗承萍.铸造ZC62镁合金的时效行为[J].金属学报,2006,42(7):733-738.LI Xiao,LIU Jiang-wen,LUO Cheng-ping.Precipitation behavior of cast ZC62 magnesium alloy[J].Acta Metallurgica Sinica,2006,42(7):733-738.
[38]李爱文,刘江文,伍翠兰.Cu含量对铸造Mg-3Zn-xCu-0.6Zr镁合金时效析出行为的影响[J].中国有色金属学报,2010,20(8):1487-1494.LI Ai-wen,LIU Jiang-wen,WU Cui-lan.Effects of Cu addition on aging precipitation behavior of cast Mg-3Zn-xCu-0.6Zr magnesium alloys[J].TheChinese Journal of Nonferrous Metals,2010,20(8):1487-1494.
[39]Zhang D F,Shi G L,Dai Q W,et al.Microstructures and mechanical properties of high strength Mg-Zn-Mn alloy[J].Transactions of Nonferrous MetalsSociety of China,2008,18(Supplement 1):59-63.
[40]Zhang D F,Shi G L,Zhao X B.Microstructure evolution and mechanical properties of Mg-x%Zn-1%Mn(x=4,5,6,7,8,9)wrought magnesiumalloys[J].Transactions of Nonferrous Metals Society of China,2011,21(1):15-25.
[41]戴庆伟,张丁非,袁炜.新型Mg-Zn-Mn变形镁合金的挤压特性与组织性能研究[J].材料工程,2008,299(4):38-42.DAI Qing-wei,ZHANG Ding-fei,YUAN Wei.Researches on extrusion,microstructure and mechanical properties of new Mg-Zn-Mn alloy[J].Journalof Materials Engineering,2008,299(4):38-42.
[42]石国梁,张丁非,戴庆伟.Mg-6Zn-1Mn镁合金中MgZn相析出的热力学计算[J].稀有金属材料与工程,2009,38(11):1940-1944.SHI Guo-liang,ZHANG Ding-fei,DAI Qing-wei.Thermodynamic Calculation of the precipitation reaction of MgZn phase in Mg-6Zn-1Mn magnesiumalloy[J].Rare Metal Materials and Engineering,2009,38(11):1940-1944.
[43]张丁非,方霖,段红玲.Mg-6wt%Zn-1wt%Mn镁合金均匀化处理研究[J].热加工工艺,2011,40(2):148-152.ZHANG Ding-fei,FANG Lin,DUAN Hong-lin.Study on homogenization treatment for Mg-6wt%Zn-1wt%Mn magnesium alloy[J].Hot WorkingTechnology,2011,40(2):148-152.
[44]张丁非,齐福刚,赵霞兵,等.Mg-Zn系高强度镁合金的研究进展[J].重庆大学学报,2010,33(11):53-61.ZHANG Ding-fei,QI Fu-gang,ZHAO Xia-bin,et al.Research progresses of high strength Mg-Zn series alloys[J].Journal of Chongqing University,2010,33(11):53-61.
[45]张丁非,赵霞兵,石国梁.Zn含量及热处理对Mg-Zn-Mn变形镁合金显微组织和力学性能的影响[J].稀有金属材料与工程,2011,40(3):418-423.ZHANG Ding-fei,ZHAO Xiao-bin,SHI Guo-liang.Effect of Zn content and heat treatment on microstructures and mechanical properties of Mg-Zn-Mnwrought magnesium alloys[J].Rare Metal Materials and Engineering,2011,40(3):418-423.
[46]Sasaki T T,Ju J D,Hono K.Heat-treatable Mg-Sn-Zn wrought alloy[J].Scripta Materialiia,2009,61:80-83.
[47]Harosh S,Miller L,Levi G.Microstructure and properties of Mg-5.6%Sn-4.4%Zn-2.1%Al alloy[J].Journal of Materials Science,2007,42:9983-9989.
[48]Sasaki T T,Yamamoto K,Honma T,et al.A high-strength Mg-Sn-Zn-Al alloy extruded at low temperature[J].Scripta Materialia,2008,59:1111-1114.
[49]Tang W N,Park S S,You B S.Effect of the Zn content on the microstructure and mechanical properties of indirect-extruded Mg-5Sn-xZn alloys[J].Materials and Design,2011,32:3537-3543.
[50]梁艳,黄晓锋,王韬,等.高强镁合金的研究状况及发展趋势[J].中国铸造装备与技术,2009,1:8-12.LIANG Yan,HUANG Xiao-feng,WANG Tao,et al.The situation and development trend of high-strength magnesium alloy research[J].China FoundryMachinery and Technology,2009,1:8-12.
[51]Xu S W,Oh-ishi K,Kamado S.High-strength extruded Mg-Al-Ca-Mn alloy[J].Sripta Materialia,2011,65(3):269-272.
[52]Dong T S,Bai P C,Hou X H.Microstructure and mechanical properties of spray deposited Mg-12.55Al-3.33Zn-0.58Ca-1.0Nd alloy[J].Rare MetalMaterial and Engineering,2011,40(4):689-692.
[53]Xu S W,Zheng M Y,Kamado S,et al.Dynamic microstructural changes during hot extrusion and mechanical properties of a Mg-5.0Zn-0.9Y-0.16Zr(wt%)alloy[J].Materials Science and Engineering A,2011,528:4055-40667.
[54]谷松伟,郝海,张爱民.Gd对铸态AZ31合金组织和性能的影响[J].特种铸造及有色合金,2011,31(5):472-476.Gu Song-wei,Hao Hai,Zhang Ai-min.Effects of Gd microstructure and properties of as-cast AZ31 magnesium alloy[J].Special Casting andNonferrous Alloys,2011,31(5):472-476.
[55]Wang J L,Wang L D,Wu Y M.Effects of samarium on microstructures and tensile properties of Mg-5Al-0.3Mn alloy[J].Materials Science andEngineering A,2011,528:4115-4119.
[56]Zheng L,Liu C,Wan Y C,et al.Microstructures and mechanical properties of Mg-10Gd-6Y-2Zn-0.6Zr(wt%)alloy[J].Journal of Alloys andCompounds,2011,509:8832-8839.
[57]Li X,Liu C,Samman T A.Microstructure and mechanical properties of Mg-2Gd-3Y-0.6Zr alloy upon conventional and hydrostatic extrusion[J].Materials Letters,2011,65:1726-1729.
[58]Han X Z,Xu W C,Shan D B.Effect of precipitates on microstructures and properties of forged Mg-10Gd-2Y-0.5Zn-0.3Zr alloy during ageing process[J].Journal of Alloys and Compounds,2001,509:8625-8631.
[59]Li K J,Li Q A.Microstructure and superior mechanical properties of cast Mg-12Gd-2Y-0.5Sm-0.5Sb-0.5Zr alloy[J].Materials Science andEngineering A,2011,528:5453-5457.
[60]Homma T,Kunito N,Kamado S.Fabrication of extraordinary high-strength magnesium alloy by hot extrusion[J].Scripta Materialia,2009,61:644-647.
[61]Klements W,Willens R H,Duwez P.Non-crystalline structure in solidified gold-silicon alloys[J].Nature,1960,187:869-870.
[62]Calka A,Madhave M,Polk D E,et al.A transition-metal-free amorphous alloy:Mg.70Zn.30[J].Scripta Materialia,1977,11:65-70.
[63]Inoue A,Ohtera K,Kita K.Mg-Ce-Ni alloy with high strength and good ductility[J].Jpn J Appl Phys,1988,27:2248-2251.
[64]Inoue A,Kato A,Zhang T,et al.Ultrahigh mechanical strength of Al88Y2Ni10-xMx(M=Mn,Fe,or Co)amorphous alloys containing nanoscale fcc Alparticles[J].Mater Trans JIM,1991,32:599-608.
[65]Kang H G,Park E S,Kim W T,et al.Fabrication of bulk Mg-Cu-Ag-Y glassy alloy by squeeze casting[J].Mater Trans JIM,2000,41:846-849.
[66]Ma H,Shi L L,Xu J.Discovering inch-diameter metallic glasses in three-dimensional composition space[J].Appl Phys Lett,2005,87:181915.
[67]Lu L,Thong K K,Gupta M.Mg-based composite reinforced by Mg2Si[J].Composites Science and Technology,2003,63:627-632.
[68]Youssef M,Wang Y B,Liao X Z,et al.High hardness in a nanocrystalline Mg97Y2Zn1 alloy[J].Materials Science and Engineering A,2011,528:7494-7499.
[69]Guo S F,Liu L,Li N.Fe-based bulk metallic glass matrix composite with large plasticity[J].Scripta Materialia,2010,62:329-332.
[70]Hui X,Dong W,Chen G L.Formation,microstructure and properties of long-period order structure reinforced Mg-based bulk metallic glass composites[J].Acta Materialia,2007,55:907-920.
基本信息:
DOI:10.13289/j.issn.1009-6264.2012.06.007
中图分类号:TG146.22
引用信息:
[1]张丁非,张红菊,兰伟等.高强镁合金的研究进展[J].材料热处理学报,2012,33(06):1-8.DOI:10.13289/j.issn.1009-6264.2012.06.007.
基金信息:
国家“973”重大基础研究项目(2007CB613700);; 国家“十二五”科技支撑计划项目(2011BAE22B01-3);; 中央高校基本科研业务费(CDJXS11132228);; 科技部国际合作项目(2010DFR50010,2008DFR50040);; 重庆市科委项目(CSTC,2010AA4048)