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2019, 03, v.40;No.225 12-19
稀土元素对铝铜合金性能影响的研究进展
基金项目(Foundation): 国家重点实验室项目(2018GZKF03007);; 国家自然科学基金(10874118)
邮箱(Email):
DOI: 10.13289/j.issn.1009-6264.2018-0455
摘要:

随着汽车轻量化、高容量化、低成本化的趋势,作为外壳材料的铝合金的性能研究成为了近年的热点,而稀土元素的化学活性很强,将其加入到合金中会起到净化熔体、细化晶粒、微合金化等积极作用。本文综述了国内外关于稀土在铝铜合金中的应用研究现状,通过对稀土在铝铜合金中的作用机理的阐述,从晶粒大小、析出物、相结构等多个方面,讨论了稀土对铝铜合金的显微组织、力学性能和耐腐蚀性能等方面产生的影响,提出了稀土在铝铜合金发展中需要注意的问题,为将稀土加入到2XXX系合金并改善综合性能的研究提供了参考。

Abstract:

With the trend of light weight, high capacity and low cost of automobiles, the research on the properties of aluminum alloys as shell materials has become popular in recent years. The chemical activity of rare earth elements is very strong, and its addition to the alloy plays a positive role in purifying melts, refining grains, and microalloying. The present research status of the application of rare earths in Al-Cu alloys at home and abroad is reviewed. Through the description of the action mechanism of rare earths in Al-Cu alloys, the effects of rare earth on microstructure, mechanical properties and corrosion resistance of Al-Cu alloy are discussed from the aspects of grain size, precipitates and phase structure. and some problems worthy of attention in the development of Al-Cu alloys are put forward. It provides a reference for the research of adding rare earth to 2 XXX series alloys and improving the comprehensive properties.

参考文献

[1] Miller W S,Zhuang L,Bottema J,et al.Recent development in aluminium alloys for the automotive industry[J].Materials Science and Engineering A,2000,280(1):37-49.

[2] Patil A,Patil V,Shin D W,et al.Issue and challenges facing rechargeable thin film lithium batteries[J].Materials Research Bulletin,2008,43(8/9):1913-1942.

[3] 内田秀俊,长井康礼,伊藤智康.电池外壳用铝合金板及其制造方法:中国CN101358307A[P].2009-02-04.

[4] Buller S,Thele M,De Doncker R W A A,et al.Impedance-based simulation models of supercapacitors and Li-ion batteries for power electronic applications[J].IEEE Transactions on Industry Applications,2005,41(3):742-747.

[5] Burke A,Miller M.The power capability of ultracapacitors and lithium batteries for electric and hybrid vehicle applications[J].Journal of Power Sources,2011,196(1):514-522.

[6] Wang S C,Starink M J,Gao N.Precipitation hardening in Al-Cu-Mg alloys revisited[J].Scripta Materialia,2006,54(2):287-291.

[7] Zuiko I S,Gazizov M R,Kaibyshev R O.Effect of thermomechanical treatment on the microstructure,phase composition,and mechanical properties of Al-Cu-Mn-Mg-Zr alloy[J].The Physics of Metals and Metallography,2016,117(9):906-919.

[8] Yin Z,Pan Q,Zhang Y,et al.Effect of minor Sc and Zr on the microstructure and mechanical properties of Al-Mg based alloys[J].Materials Science and Engineering A,2000,280(1):151-155.

[9] Norman A F,Prangnell P B,McEwen R S.The solidification behaviour of dilute aluminium-scandium alloys[J].Acta Materialia,1998,46(16):5715-5732.

[10] Mishra A K,Balasubramaniam R.Corrosion inhibition of aluminum alloy AA 2014 by rare earth chlorides[J].Corrosion Science,2007,49(3):1027-1044.

[11] Nogita K,McDonald S D,Dahle A K.Eutectic modification of Al-Si alloys with rare earth metals[J].Materials Transactions,2004,45(2):323-326.

[12] Chaubey A K,Mohapatra S,Jayasankar K,et al.Effect of cerium addition on microstructure and mechanical properties of Al-Zn-Mg-Cu alloy[J].Transactions of the Indian Institute of Metals,2009,62(6):539-543.

[13] Wang W,Zhang X,Gao Z,et al.Influences of Ce addition on the microstructures and mechanical properties of 2519A aluminum alloy plate[J].Journal of alloys and Compounds,2010,491(1/2):366-371.

[14] Ao X,Xing S,Yu B,et al.Effect of Ce addition on microstructures and mechanical properties of A380 aluminum alloy prepared by squeeze-casting[J].International Journal of Minerals,Metallurgy,and Materials,2018,25(5):553-564.

[15] Xiao D H,Wang J N,Ding D Y,et al.Effect of rare earth Ce addition on the microstructure and mechanical properties of an Al-Cu-Mg-Ag alloy[J].Journal of Alloys and Compounds,2003,352(1/2):84-88.

[16] Sawtell R R,Jensen C L.Mechanical properties and microstructures of Al-Mg-Sc alloys[J].Metallurgical Transactions A,1990,21(1):421-430.

[17] Filatov Y A,Yelagin V I,Zakharov V V.New Al-Mg-Sc alloys[J].Materials Science and Engineering A,2000,280(1):97-101.

[18] Jones M J,Humphreys F J.Interaction of recrystallization and precipitation:the effect of Al3Sc on the recrystallization behaviour of deformed aluminium[J].Acta Materialia,2003,51(8):2149-2159.

[19] Davydov V G,Rostova T D,Zakharov V V,et al.Scientific principles of making an alloying addition of scandium to aluminium alloys[J].Materials Science and Engineering A,2000,280(1):30-36.

[20] Marquis E A,Seidman D N.Nanoscale structural evolution of Al3Sc precipitates in Al3 (Sc) alloys[J].Acta Materialia,2001,49(11):1909-1919.

[21] Fuller C B,Seidman D N.Temporal evolution of the nanostructure of Al3(Sc,Zr) alloys:Part II-coarsening of Al3(Sc1-xZrx) precipitates[J].Acta Materialia,2005,53(20):5415-5428.

[22] Knipling K E,Karnesky R A,Lee C P,et al.Precipitation evolution in Al-0.1 Sc,Al-0.1 Zr and Al-0.1 Sc-0.1 Zr (at%) alloys during isochronal aging[J].Acta Materialia,2010,58(15):5184-5195.

[23] Norman A F,Hyde K,Costello F,et al.Examination of the effect of Sc on 2000 and 7000 series aluminium alloy castings:for improvements in fusion welding[J].Materials Science and Engineering A,2003,354(1/2):188-198.

[24] Starink M J,Gao N,Kamp N,et al.Relations between microstructure,precipitation,age-formability and damage tolerance of Al-Cu-Mg-Li (Mn,Zr,Sc) alloys for age forming[J].Materials Science and Engineering A,2006,418(1/2):241-249.

[25] Colombo M,Gariboldi E,Morri A.Er addition to Al-Si-Mg-based casting alloy:Effects on microstructure,room and high temperature mechanical properties[J].Journal of Alloys and Compounds,2017,708:1234-1244.

[26] 杨军军,聂祚仁,金头男,等.稀土元素铒对 Al-4Cu 合金组织与性能的影响[J].中国稀土学报,2002(z2):159-162.YANG Jun-jun,NIE Zuo-ren,JIN Tou-nan,et al.Effects of rare earth element Er on structure and properties of Al-4Cu alloy[J].Journal of the Chinese Rare Earth Society,2002(z2):159-162.

[27] 李云涛,刘志义,夏卿坤,等.稀土铒对Al-Cu-Mg-Ag-Zr合金微观组织与时效行为的影响[J].材料热处理学报,2007,28(2):49-53.LI Yun-tao,LIU Zhi-yi,XIA Qing-kun,et al.Effect of trace addition of Er on microstructure and ageing behavior of Al-Cu-Mg-Ag-Zr alloy[J].Transactions of Materials and Heat Treatment,2007,28(2):49-53.

[28] Shivkumar S,Wang L,Apelian D.Molten metal processing of advanced cast aluminum alloys[J].JOM,1991,43(1):26-32.

[29] Lumley R N,Morton A J,Polmear I J.Enhanced creep performance in an Al-Cu-Mg-Ag alloy through underageing[J].Acta Materialia,2002,50(14):3597-3608.

[30] Lathabai S,Lloyd P G.The effect of scandium on the microstructure,mechanical properties and weldability of a cast Al-Mg alloy[J].Acta Materialia,2002,50(17):4275-4292.

[31] Xiao D H,Huang B.Effect of Yb addition on precipitation and microstructure of Al-Cu-Mg-Ag alloys[J].Transactions of Nonferrous Metals Society of China,2007,17(6):1181-1185.

[32] 张新明,王文韬,刘波,等.Nd对2519铝合金组织与耐热性能的影响[J].中国有色金属学报,2009,19(1):15-20.ZHANG Xin-ming,WANG Wen-tao,LIU Bo,et al.Effect of Nd addition on microstructures and heat resisting properties of 2519 aluminum alloy[J].The Chinese Journal of Nonferrous Metals,2009,19(1):15-20.

[33] Gazizov M,Teleshov V,Zakharov V,et al.Solidification behaviour and the effects of homogenisation on the structure of an Al-Cu-Mg-Ag-Sc alloy[J].Journal of Alloys and Compounds,2011,509(39):9497-9507.

[34] 张娜,李杨.锂离子动力电池铝外壳的腐蚀[J].腐蚀与防护,2015,36(4):351-365.ZHANG Na,LI Yang.Corrosion of aluminum casing of lithium-ion power battery[J].Corrosion and Protection,2015,36(4):351-365.

[35] Gupta R K,Deschamps A,Cavanaugh M K,et al.Relating the early evolution of microstructure with the electrochemical response and mechanical performance of a Cu-rich and Cu-lean 7xxx aluminum alloy[J].Journal of the Electrochemical Society,2012,159(11):492-502.

[36] Ringer S P,Hono K.Microstructural evolution and age hardening in aluminium alloys:atom probe field-ion microscopy and transmission electron microscopy studies[J].Materials Characterization,2000,44(1/2):101-131.

[37] Ralston K D,Birbilis N,Cavanaugh M K,et al.Role of nanostructure in pitting of Al-Cu-Mg alloys[J].Electrochimica Acta,2010,55(27):7834-7842.

[38] Dabalà M,Armelao L,Buchberger A,et al.Cerium-based conversion layers on aluminum alloys[J].Applied Surface Science,2001,172(3/4):312-322.

[39] 郑玉林,暨波,叶凌英,等.稀土镱对2519A铝合金抗晶间腐蚀性能的影响[J].中南大学学报:自然科学版,2013,44(12):4806-4810.ZHEN Yu-lin,JI Bo,YE Ling-ying,et al.Influence of Yb addiotion on intergranular corrosion resistance of aluminum alloy 2519A[J].Journal of Central South University (Science and Technology),2013,44(12):4806-4810.

[40] Ho D,Brack N,Scully J,et al.Cerium dibutylphosphate as a corrosion inhibitor for AA2024-T3 aluminum alloys[J].Journal of the Electrochemical Society,2006,153(9):392-401.

[41] Markley T A,Forsyth M,Hughes A E.Corrosion protection of AA2024-T3 using rare earth diphenyl phosphates[J].Electrochimica Acta,2007,52(12):4024-4031.

[42] Yasakau K A,Zheludkevich M L,Lamaka S V,et al.Mechanism of corrosion inhibition of AA2024 by rare-earth compounds[J].The Journal of Physical Chemistry B,2006,110(11):5515-5528.

[43] Catubig R,Hughes A E,Cole I S,et al.The use of cerium and praseodymium mercaptoacetate as thiol-containing inhibitors for AA2024-T3[J].Corrosion Science,2014,81:45-53.

[44] Hinton B R W,Arnott D R,Ryan N E.Cerium conversion coatings for the corrosion protection of aluminum[C]//Materials Forum.1986,9(3):162-173.

[45] Hughes A E,Taylor R J,Hinton B R W,et al.XPS and SEM characterization of hydrated cerium oxide conversion coatings[J].Surface and Interface Analysis,1995,23(7/8):540-550.

基本信息:

DOI:10.13289/j.issn.1009-6264.2018-0455

中图分类号:TG146.21

引用信息:

[1]田伟,胡梦楠,孙玥,等.稀土元素对铝铜合金性能影响的研究进展[J],2019,40(03):12-19.DOI:10.13289/j.issn.1009-6264.2018-0455.

基金信息:

国家重点实验室项目(2018GZKF03007);; 国家自然科学基金(10874118)

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