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高熵合金由于其优异的性能逐渐成为了广大学者的研究热点,而热处理可以有效地消除铸态高熵合金内部的结构缺陷及残余应力从而有效地改善其性能。本文综述了国内外有关高熵合金热处理的研究现状,从析出物、相结构、显微组织等多个方面,讨论了热处理对高熵合金的力学性能、耐磨性能和耐腐蚀性能等方面的影响,提出了高熵合金在热处理过程中需要注意的问题,以期为高熵合金的研究提供参考。
Abstract:The high-entropy alloy has become a research focus of a large number of scholars because of its excellent performance, and the heat treatment can effectively eliminate the structural defects and residual stress in the as-cast high-entropy alloy so as to effectively improve its performance. The research status of heat treatment of high-entropy alloy at home and abroad is reviewed in this paper. The effects of heat treatment on the mechanical properties, wear-resisting property and corrosion resistance of high-entropy alloy are discussed from the aspects of the precipitation, the phase structure, the microstructure and so on, and the problems needing attention in the heat treatment process of high entropy alloys are put forward in order to provide reference for the research of high entropy alloys.
[1] 周航,杨少锋,杨亚楠,等.高熵合金的研究进展及发展趋势[J].热加工工艺,2018,47(18):5-9.ZHOU Hang,YANG Shao-feng,YANG Ya-nan,et al.Research progress and development trend of high entropy alloy[J].Hot Working Technology,2018,47(18):5-9.
[2] 朱海云,孙宏飞,李业超.多主元高熵合金的研究现状与发展[J].新材料产业,2008(9):67-70.ZHU Hai-yun,SUN Hong-fei,LI Ye-chao.Research progress and development of high-entropy alloys with multi-principal elements[J].Advanced Materials Industry,2008(9):67-70.
[3] Yang X,Zhang Y.Prediction of high-entropy stabilized solid-solution in multi-component alloys[J].Materials Chemistry and Physics,2012,132(2/3):233-238.
[4] 薛虎东.热处理和元素含量对高熵合金组织和性能的影响[D].沈阳:东北大学,2011.XUE Hu-dong.Influence on the microstructure and properties of the high-entropy alloys by heat treatment and elements[D].Shenyang:Northeastern University,2011.
[5] 李安敏,张喜燕,刘乐林,等.退火对AlCrFeCoNiCu高熵合金组织与性能的影响[J].机械工程材料,2012,36(7):14-16.LI An-min,ZHANG Xi-yan,LIU Le-lin,et al.Effect of annealing on microstructure and properties of AlCrFeCoNiCu high-entropy alloy[J].Materials for Mechanical Engineering,2012,36(7):14-16.
[6] 班煜峰,刘贵仲,董鑫涛,等.热处理对AlFeCrCoNiMo高熵合金微观组织与硬度的影响[J].锻压技术,2017,42(7):136-140.BAN Yu-feng,LIU Gui-zhong,DONG Xin-tao,et al.Influence of heat treatment on microstructure and hardness of high entropy alloy AlFeCrCoNiMo[J].Forging and Stamping Technology,2017,42(7):136-140.
[7] 吴桂芬,唐群华,柯跃前,等.淬火温度对Al0.5CoCrFeNiSi0.2高熵合金组织结构的影响[J].材料科学与工程学报,2012,30(3):422-427.WU Gui-fen,TANG Qun-hua,KE Yue-qian,et al.Effect of quenching temperature on the microstructure of high-entropy Al0.5CoCrFeNiSi0.2 alloy[J].Journal of Materials Science and Engineering,2012,30(3):422-427.
[8] 孙永哲,田笑,魏亚风,等.热处理对冷轧变形Al0.3CoCrFeNi高熵合金组织与力学性能的影响[J].材料热处理学报,2017,38(9):18-23.SUN Yong-zhe,TIAN Xiao,WEI Ya-feng,et al.Effect of heat treatment on microstructure and mechanical properties of Al0.3CoCrFeNi high entropy alloy with cold rolling[J].Transactions of Materials and Heat Treatment,2017,38(9):18-23.
[9] 唐群华,赵亚光,蔡建宾,等.时效处理对Al0.5CoCrFeNi高熵合金微观组织和力学性能的影响[J].有色金属(冶炼部分),2011(4):47-50.TANG Qun-hua,ZHAO Ya-guang,CAI Jian-bin,et al.Effect of aging treatment on microstructures and mechanical properties of Al0.5CoCrFeNi high-entropy alloy[J].Nonferrous Metals(Extractive Metallurgy),2011(4):47-50.
[10] 谢志敏,饶湖常,王海燕,等.热处理对FeCoCrNiMnC0.1高熵合金组织结构与力学性能的影响[J].热加工工艺,2017,46(4):226-230.XIE Zhi-min,RAO Hu-chang,WANG Hai-yan,et al.Effects of heat treatment on microstructure and mechanical properties of FeCoCrNiMnC0.1 high-entropy alloy[J].Hot Working Technology,2017,46(4):226-230.
[11] 张冲,陈国进,戴品强.时效对激光熔覆FeCoCrNiB0.5高熵合金激光涂层组织和硬度的影响[J].金属热处理,2015,40(9):146-151.ZHANG Chong,CHEN Guo-jin,DAI Pin-qiang.Effects of aging on microstructure and hardness of FeCoCrNiB0.5 high-entropy alloy coating prepared by laser cladding[J].Heat Treatment of Metals,2015,40(9):146-151.
[12] 黄元盛,温立哲.退火处理对Al3CoCrCu1/2FeMoNiTi高熵合金激光涂层组织和性能的影响[J].表面技术,2016,45(7):162-166.HUANG Yuan-sheng,WEN Li-zhe.Effect of annealing on the microstructure and property of Al3CoCrCu1/2FeMoNiTi high-entropy alloy laser coating[J].Surface Technology,2016,45(7):162-166.
[13] 吴兴财,张伟强,秦力,等.退火处理对AlCoCrFeNi高熵合金组织结构及性能的影响[J].热加工工艺,2015,44(8):220-222.WU Xing-cai,ZHANG Wei-qiang,QIN Li,et al.Effects of annealing treatment on microstructure and mechanical properties of AlCoCrFeNi high-entropy alloy[J].Hot Working Technology,2015,44(8):220-222.
[14] 刘亮,张越,赵作福,等.热处理对CoCrFeNiMo高熵合金组织与硬度的影响[J].金属热处理,2016,41(8):29-32.LIU Liang,ZHANG Yue,ZHAO Zuo-fu,et al.Effect of heat treatment on microstructure and hardness of CoCrFeNiMo high entropy alloy[J].Heat Treatment of Metals,2016,41(8):29-32.
[15] 伍冠中,聂金凤,赵永好.热处理对高压扭转FeNi2CoMo0.2V0.5高熵合金微观组织演变及力学性能的影响[J].热加工工艺,2019,48(14):159-162.WU Guan-zhong,NIE Jin-feng,ZHAO Yong-hao.Effects of heat treatment on microstructure evolution and mechanical properties of hpt deformed FeNi2CoMo0.2V0.5 high-entropy alloy by high pressure torsion[J].Hot Working Technology,2019,48(14):159-162.
[16] Lu Y,Gao X,Jiang L,et al.Directly cast bulk eutectic and near-eutectic high entropy alloys with balanced strength and ductility in a wide temperature range[J].Acta Materialia,2017,124:143-150.
[17] 李田野,姚小飞,吕煜坤,等.热处理对CoCrFeMnNi-5%Mo高熵合金组织及性能的影响[J].西安工业大学学报,2019,39(1):80-85.LI Tian-ye,YAO Xiao-fei,Lü Yu-kun,et al.Effect of heat treatment on microstructure and properties of CoCrFeMnNi-5%Mo high entropy alloy[J].Journal of Xi'an Technological University,2019,39(1):80-85.
[18] 王康康,王荣峰,吴瑞瑞,等.高熵合金的研究进展[J].中国重型装备,2017(3):49-51+54.WANG Kang-kang,WANG Rong-feng,WU Rui-rui,et al.Research development of high-entropy alloy[J].China Heavy Equipment,2017(3):49-51+54.
[19] 梁秀兵,陈永雄,张志彬,等.热处理对FeCrNiCoCu高熵合金涂层的影响[J].装甲兵工程学院学报,2013,27(4):96-99.LIANG Xiu-bing,CHEN Yong-xiong,ZHANG Zhi-bin,et al.Effect of heat treatment on FeCrNiCoCu high-entropy alloy coating[J].Journal of Academy of Armored Force Engineering,2013,27(4):96-99.
[20] 许世红,邱建平,常国华,等.机械合金化和热处理对高熵合金MgTiVCrNi微观组织演化和相结构的影响[J].甘肃高师学报,2015,20(2):44-49.XU Shi-hong,QIU Jian-ping,CHANG Guo-hua,et al.Effect of mechanical alloying and treatment on the microstructure evolution and phase structure of the entropy alloys MgTiVCrNi[J].Journal of Gansu Normal Colleges,2015,20(2):44-49.
[21] 刘贵仲,李伟,罗晓艳,等.AlFeCuCoNiCrTix高熵合金的退火组织及硬度变化[J].材料导报,2009,23(12):51-54.LIU Gui-zhong,LI Wei,LUO Xiao-yan,et al.Study on behaviors of annealed microstructure and hardness development in AlFeCuCoNiCrTix high-entropy alloys[J].Materials Review,2009,23(12):51-54.
[22] 黄祖凤,张冲,唐群华,等.退火对激光熔覆FeCoCrNiB高熵合金涂层组织结构与硬度的影响[J].表面技术,2013,42(1):9-13.HUANG Zu-feng,ZHANG Chong,TANG Qun-hua,et al.Effects of annealing on the microstructure and hardness of laser cladding FeCoCrNiB high-entropy alloy Coating[J].Surface Technology,2013,42(1):9-13.
[23] Munitz A,Salhov S,Hayun S,et al.Heat treatment impacts the micro-structure and mechanical properties of AlCoCrFeNi high entropy alloy[J].Journal of Alloys and Compounds,2016,683:221-230.
[24] He F,Wang Z J,Niu S Z,et al.Strengthening the CoCrFeNiNb0.25 high entropy alloy by FCC precipitate[J].Journal of Alloys and Compounds,2016,667:S0925838816301542.
[25] Niu S,Kou H,Guo T,et al.Strengthening of nanoprecipitations in an annealed Al0.5CoCrFeNi high entropy alloy[J].Materials Science and Engineering A,2016,671:82-86.
[26] 王水华,张勇.多种工艺对COCrFeNiCu高熵合金组织及拉伸性能的影响[C]//2011中国材料研讨会论文摘要集,2011.
[27] 赵春凤,吴波,杨上金,等.热处理工艺对AlCoCrFeNiTi0.5高熵合金的显微组织和硬度的影响[J].广西大学学报(自然科学版),2014,39(2):407-416.ZHAO Chun-feng,WU Bo,YANG Shang-jin,et al.Effect of heat treatment on microstructure and hardness of AlCoCrFeNiTi0.5 high entropy alloy[J].Journal of Guangxi University(Natural Science Edition),2014,39(2):407-416.
[28] 翁子清,董刚,张群莉,等.退火对激光熔覆FeCrNiCoMn高熵合金涂层组织与性能的影响[J].中国激光,2014,41(3):65-70.WENG Zi-qing,DONG Gang,ZHANG Qun-li,et al.Effects of annealing on microstructure and properties of FeCrNiCoMn high-entropy alloy coating prepared by laser cladding[J].Chinese Journal of Lasers,2014,41(3):65-70.
[29] Qiao J W,Wang Y F,Wang R Q,et al.Tailoring microstructures and mechanical properties of AlCoCrFeNiTi0.3 high-entropy alloys by heat treatment[C]//中国材料大会2012第21分会场:非晶合金与高熵合金论文集,中国山西太原,2012:64-70.
[30] 农智升,张波,朱景川.退火对CrCuFeMnTi高熵合金组织结构和力学性能的影响[J].稀有金属材料与工程,2018,47(9):2827-2832.NONG Zhi-sheng,ZHANG Bo,ZHU Jing-chuan.Effect of annealing on microstructures and mechanical properties of CrCuFeMnTi high entropy alloy[J].Rare Metal Materials and Engineering,2018,47(9):2827-2832.
[31] Zhang C,Wu G F,Dai P Q.Phase transformation and aging behavior of Al0.5CoCrFeNiSi0.2 high-entropy alloy[J].Journal of Materials Engineering and Performance,2015,24(5):1918-1925.
[32] 初雅杰,李晓泉,李建,等.退火温度对激光熔覆AlFeCrCoNiTi高熵合金涂层组织与性能的影响[J].材料热处理学报,2018,39(6):91-95.CHU Ya-jie,LI Xiao-quan,LI Jian,et al.Effects of annealing temperature on microstructure and properties of AlFeCrCoNiTi high-entropy alloy coating prepared by laser cladding[J].Transactions of Materials and Heat Treatment,2018,39(6):91-95.
[33] 张海波,李超.热处理对Fe40Cr30Ni20Al5Ti5高熵合金微观组织及性能的影响[J].热加工工艺,2019,48(6):229-231.ZHANG Hai-bo,LI Chao.Effects of heat treatment on microstructure and properties of Fe40Cr30Ni20Al5Ti5 high entropy alloy[J].Hot Working Technology,2019,48(6):229-231.
[34] 张越,刘亮,商剑.退火温度对CoCrFeNiAl高熵合金组织与性能的影响[J].金属热处理,2017,42(9):36-39.ZHANG Yue,LIU Liang,SHANG Jian.Effect of annealing temperature on microstructure and properties of CoCrFeNiAl high entropy alloy[J].Heat Treatment of Metals,2017,42(9):36-39.
[35] 唐群华,蔡建宾,吴桂芬,等.热处理对Al0.5CoCrFeNiB0.2高熵合金组织结构及力学性能的影响[J].铸造,2011,60(1):24-27.TANG Qun-hua,CAI Jian-bin,WU Gui-fen,et al.Effects of heat treatment on microstructure and mechanical properties of Al0.5CoCrFeNiB0.2 high-entropy alloy[J].Foundry,2011,60(1):24-27.
[36] Li J,Hui J,Lu Y P,et al.Mechanical properties improvement of AlCrFeNi2Ti0.5 high entropy alloy through annealing design and its relationship with its particle-reinforced microstructures[J].Journal of Materials Science and Technology,2015,31(4):397-402.
[37] Nong Z S,Zhu J C,Yang X W,et al.Effects of annealing on microstructure,mechanical and electrical properties of AlCrCuFeMnTi high entropy alloy[J].Journal of Wuhan University of Technology(Materials Science Edition),2013,28(6):1196-1200.
[38] Zhang M N,Zhou X L,Zhu W Z,et al.Influence of annealing on microstructure and mechanical properties of refractory CoCrMoNbTi0.4 high-entropy alloy[J].Metallurgical and Materials Transactions A,2018,49(4):1313-1327.
[39] Zhang H,Tang H,He Y Z,et al.Effect of heat treatment on borides precipitation and mechanical properties of CoCrFeNiAl1.8Cu0.7B0.3Si0.1 high-entropy alloy prepared by arc-melting and laser-cladding[J].JOM-Journal of the Minerals,69(11):2078-2083.
[40] 温鑫,金国,庞学佳,等.热处理对真空热压烧结NiCrCoTiV高熵合金组织结构及耐腐蚀性能的影响[J].材料导报,2017,31(12):79-83.WEN Xin,JIN Guo,PANG Xue-jia,et al.Effect of heat treatment on microstructure and corrosion resistance of NiCrCoTiV high-entropy alloy prepared by vacuum hot-pressing sintering[J].Materials Review,2017,31(12):79-83.
[41] 蒋淑英,林志峰,许红明.铸态和退火态Al0.5CoCrFeNiTi0.5高熵合金的组织与性能[J].中国有色金属学报,2019,29(2):326-333.JIANG Shu-ying,LIN Zhi-feng,XU Hong-ming.Microstructure and properties of as-cast and annealed Al0.5CoCrFeNiTi0.5 high-entropy alloys[J].The Chinese Journal of Nonferrous Metals,2019,29(2):326-333.
[42] 谢红波,刘贵仲,郭景杰,等.回火工艺对AlFeCrCoCu高熵合金组织及耐蚀性能的影响研究[J].稀有金属与硬质合金,2015,43(4):51-56.XIE Hong-bo,LIU Gui-zhong,GUO Jing-jie,et al.Research on effects of tempering process on microstructure and corrosion resistance of AlFeCrCoCu high-entropy alloy[J].Rare Metals and Cemented Carbides,2015,43(4):51-56.
[43] Lin C M,Hsien-Lung Tsai,Hui-Yun Bor.Effect of aging treatment on microstructure and properties of high-entropy Cu0.5CoCrFeNi alloy[J].Intermetallics,2010,18(6):1244-1250.
[44] 马国峰,傅鸿博,牛建平,等.热处理对FeCoNiAlCrCu0.5 高熵合金显微组织及摩擦性能的影响[J].沈阳大学学报(自然科学版),2015,27(5):345-349.MA Guo-feng,FU Hong-bo,NIU Jian-ping,et al.Effect of annealing on microstructure and friction and wear properties of FeCoNiAlCrCu0.5 high entropy alloys[J].Journal of Shenyang University(Natural Science),2015,27(5):345-349.
[45] 田彦文,任俊业,黄千里,等.退火温度对包套挤压FeCoCrNiMo0.1 高熵合金组织与摩擦性能的影响[J].粉末冶金材料科学与工程,2018,23(5):482-487.TIAN Yan-wen,REN Jun-ye,HUANG Qian-li,et al.Effects of annealing temperature on the microstructure and friction properties of FeCoCrNiMo0.1 high-entropy alloy fabricated by canned extruding[J].Materials Science and Engineering of Powder Metallurgy,2018,23(5):482-487.
[46] 尚晓娟,刘其斌,郭亚雄,等.退火对激光熔覆MoFeCrTiWAlNb高熔点高熵合金涂层组织与性能的影响[J].材料热处理学报,2017,38(11):101-107.SHANG Xiao-juan,LIU Qi-bin,GUO Ya-xiong,et al.Effect of annealing on microstructure and properties of laser cladding MoFeCrTiWAlNb high-melting-point high-entropy alloy coating[J].Transactions of Materials and Heat Treatment,2017,38(11):101-107.
[47] Lin D Y,Zhang N N,He B,et al.Influence of laser re-melting and vacuum heat treatment on plasma-sprayed FeCoCrNiAl alloy coatings[J].Journal of Iron and Steel Research,International,2017,24(12):1199-1205.
基本信息:
DOI:10.13289/j.issn.1009-6264.2019-0525
中图分类号:TG156;TG139
引用信息:
[1]李承泽,尤俊华,白鹤山等.高熵合金的热处理综述[J],2020,41(05):1-12.DOI:10.13289/j.issn.1009-6264.2019-0525.
基金信息:
国家自然科学基金(51401130);; 辽宁省高等学校创新人才支持计划(LCR2018016)