免加热直轧工艺钢筋在模拟混凝土孔隙液中的耐腐蚀性能Corrosion resistance of steel bars prepared by non-heating direct rolling process in simulated concrete pore solution
夏子祥,黄贞益,邓爱军,敬和民,刘洋
摘要(Abstract):
采用电化学测试和浸泡实验等方法,研究了免加热直轧(DROF)钢筋和传统加热炉轧制(THR)钢筋在模拟混凝土孔隙液中的耐腐蚀性能。结果表明:与THR钢筋相比,DROF钢筋的组织晶粒度细化,在不同浓度Cl~-溶液中,DROF钢筋都具有更低的自腐蚀电流密度、更高的自腐蚀电位和更高的阻抗值,耐腐蚀性能更好;腐蚀质量损失实验表明,DROF钢筋基体表面腐蚀坑较小,且拥有较低的腐蚀速率和较少的点蚀坑。试样表面的腐蚀产物主要成分为Fe_3O_4、Fe_2O_3、α-FeOOH、γ-FeOOH。
关键词(KeyWords): 电化学腐蚀;耐腐蚀性;腐蚀速率
基金项目(Foundation): 安徽省高等学校自然科学研究项目(KJ2019ZD07);; 安徽省高校研究生科学研究项目(YJS20210329)
作者(Author): 夏子祥,黄贞益,邓爱军,敬和民,刘洋
DOI: 10.13289/j.issn.1009-6264.2024-0025
参考文献(References):
- [1] Nouroozi M,Mirzadeh H,Zamani M.Effect of microstructural refinement and intercritical annealing time on mechanical properties of high-formability dual phase steel[J].Materials Science and Engineering A,2018,736:22-26.
- [2] 冯磊,鲍思前,张永青,等.控轧控冷工艺对含铌HRB400E钢筋组织和性能的影响[J].材料热处理学报,2023,44(9):150-160.FENG Lei,BAO Si-qian,ZHANG Yong-qing,et al.Effect of controlled rolling and controlled cooling process on microstructure and properties of niobium-containing HRB400E steel bar[J].Transactions of Materials and Heat Treatment,2023,44(9):150-160.
- [3] 吕明,薛魁,习晓峰,等.铸坯头尾温差模拟及直接轧制棒材力学性能分析[J].中国冶金,2024,34(2):61-68.Lü Ming,XUE Kui,XI Xiao-feng,et al.Simulation of temperature difference between head and tail of casting strand and analysis on mechanical properties of direct rolling bar steel[J].China Metallurgy,2024,34(2):61-68.
- [4] Ralston K D,Birbilis N.Effect of grain size on corrosion:A review[J].Corrosion,2010,66(7):75005.
- [5] Ralston K D,Birbilis N,Davies C H J.Revealing the relationship between grain size and corrosion rate of metals[J].Scripta Materialia,2010,63(12):1201-1204.
- [6] 汪兵,刘清友,贾书君,等.晶粒尺寸对普碳钢耐工业环境下大气腐蚀性能的影响[J].中国腐蚀与防护学报,2007(4):193-196.WANG Bing,LIU Qing-you,JIA Shu-jun,et al.Effect of grain size on the atmospheric corrosion resistance of carbon steel in industrial environment[J].Journal of Chinese Society for Corrosion and Protection,2007(4):193-196.
- [7] Chen Y T,Zhang K G.Influence of grain size on corrosion resistance of a HSLA steel[J].Advanced Materials Research,2012,557:143-146.
- [8] Soleimani M,Mirzadeh H,Dehghanian C.Unraveling the effect of martensite volume fraction on the mechanical and corrosion properties of low-carbon dual-phase steel[J].Steel Research International,2020,91(2):1900327.
- [9] Li Y,Wang F,Liu G.Grain size effect on the electrochemical corrosion behavior of surface nanocrystallized low-carbon steel[J].Corrosion,2004,60(10):891-896.
- [10] Soleimani M,Mirzadeh H,Dehghanian C.Processing route effects on the mechanical and corrosion properties of dual phase steel[J].Metals and Materials International,2020,26:882-890.
- [11] Soleimani M,Mirzadeh H,Dehghanian C.Effect of grain size on the corrosion resistance of low carbon steel[J].Materials Research Express,2020,7(1):016522.
- [12] Wang P,Zhao J,Ma L,et al.Effect of grain ultra-refinement on microstructure,tensile property,and corrosion behavior of low alloy steel[J].Materials Characterization,2021,179:111385.
- [13] Wang P,Cheng X,Zhang Z,et al.Roles of grain refinement in the rust formation and corrosion resistance of weathering steels[J].Corrosion Science,2023,224:111561.
- [14] 张明,杨善武,迟丽丽,等.高钛钢在盐雾环境中的腐蚀行为[J].机械工程材料,2010,34(11):18-22.ZHANG Ming,YANG Shan-wu,CHI Li-li,et al.Corrosion behavior of high titanium steel exposed in salt fog environment[J].Materials for Mechanical Engineering,2010,34(11):18-22.
- [15] 董超芳,肖葵,徐琳,等.含氯离子大气环境中 7A04 铝合金腐蚀及电化学行为研究(英文)[J].稀有金属材料与工程,2011,40(S2):275-279.DONG Chao-fang,XIAO Kui,XU Lin,et al.Characterization of 7A04 aluminum alloy corrosion under atmosphere with chloride ions using electrochemical techniques[J].Rare Metal Materials and Engineering,2011,40(S2):275-279.
- [16] Zhang X,Pehkonen S O,Kocherginsky N,et al.Copper corrosion in mildly alkaline water with the disinfectant monochloramine[J].Corrosion Science,2002,44(11):2507-2528.
- [17] Wei J,Dong J H,Ke W.Corrosion resistant performance of a chemical quenched steel bars in concrete[J].Construction and Building Materials,2011,25(3):1243-1247.
- [18] Mansfeld F.Electrochemical impedance spectroscopy (EIS) as a new tool for investigating methods of corrosion protection[J].Electrochimica Acta,1990,35(10):1533-1544.
- [19] 朱其麟.氯离子侵蚀下泡沫混凝土中钢筋锈蚀特性研究[D].马鞍山:安徽工业大学,2021.ZHU Qi-lin.Study on corrosion characteristics of steel bar in foam concrete under chloride ion erosion[D].Ma’anshan:Anhui University of Technology,2021.
- [20] Cheng X Q,Tian Y W,Li X G,et al.Corrosion behavior of nickel-containing weathering steel in simulated marine atmospheric environment[J].Materials and Corrosion,2014,65(10):1033-1037.
- [21] Zhao Y,Ren H,Dai H,et al.Composition and expansion coefficient of rust based on X-ray diffraction and thermal analysis[J].Corrosion Science,2011,53(5):1646-1658.
- [22] 邹妍,王佳,郑莹莹.锈层下碳钢的腐蚀电化学行为特征[J].物理化学学报,2010,26(9):2361-2368.ZOU Yan,WANG Jia,ZHENG Ying-ying.Electrochemical corrosion behaviors of rusted carbon steel[J].Acta Physico-Chimica Sinica,2010,26(9):2361-2368.
- [23] Hao L,Zhang S,Dong J,et al.Rusting evolution of MnCuP weathering steel submitted to simulated industrial atmospheric corrosion[J].Metallurgical and Materials Transactions,2012,43(5):1724-1730.
- [24] Murase Y,Masuda H,Katayama H.Corrosion resistance of finer/coarser pearlitic structures of carbon steel[J].Journal of the Electrochemical Society,2021,168(4):041501.
- [25] Katiyar P K,Behera P K,Misra S,et al.Comparative corrosion behavior of five different microstructures of steel bars steels in simulated concrete pore solution with and without chloride addition[J].Journal of Materials Engineering and Performance,2019,28(10):6275-6286.
- [26] Katiyar P K,Misra S,Mondal K.Effect of different cooling rates on the corrosion behavior of high-carbon pearlitic steel[J].Journal of Materials Engineering and Performance,2018,27(4):1753-1762.
- [27] Gollapudi S.Grain size distribution effects on the corrosion behaviour of materials[J].Corrosion Science,2012,62(1):90-94.
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