超重力燃烧熔渗钨铜合金绝热温度计算及其显微组织Adiabatic temperature calculation and microstructure of W-Cu alloy fabricated by combustion synthesis infiltration technique under ultra-gravity field
孙祥鸣,宋月鹏,高东升,李江涛,陈义祥,郭世斌
摘要(Abstract):
根据燃烧合成体系绝热温度的热力学基本理论,通过计算机编程,对CuO/Al铝热剂体系的绝热温度进行了数值计算。结果表明,在考虑产物Cu的汽化焓情况下,体系绝热温度为2846 K(Cu的沸点温度),同时还有52.9 at%的Cu产物以气相形式存在,而该体系中钨粉添加量超过30 mass%时,绝热温度低于1800 K而不能自蔓延燃烧。采用超重力燃烧熔渗方法制备出组织致密,钨颗粒体积分数呈梯度分布(沿超重力方向70%~80 at%)的钨铜合金。进一步检测结果表明,该方法与传统烧结方法制备的钨铜合金其相结构及显微组织形貌相同,并对其成型机制进行了初步分析讨论。
关键词(KeyWords): 钨铜合金;超重力燃烧熔渗;绝热温度;显微组织;计算机数值计算
基金项目(Foundation): 国家自然科学基金(51001111);; ITPA人才项目(2010GB106003);; 国家“十二五”科技支撑计划项目(2011BAD12B02);; 山东省研究生教育创新计划(SDYY11079)
作者(Author): 孙祥鸣,宋月鹏,高东升,李江涛,陈义祥,郭世斌
DOI: 10.13289/j.issn.1009-6264.2013.06.007
参考文献(References):
- [1]黄友庭,汤德平,陈文哲.CuW80铜钨合金疲劳损伤过程的研究[J].材料热处理学报,2007,28(4):30-33.HUANG You-ting,TANG De-ping,CHEN Wen-zhe.Study on fatigue damage of CuW80 alloy[J].Transactions of Materials and Heat Treatment,2007,28(4):30-33.
- [2]WANG Xian-hui,LIANG Shu-hua,WANG Bo,et al.Investigation on microstructure and properties of WCu alloy fabricated by infiltrating CuLa masteralloy into W skeleton[J].Advanced Science Letters,2011,4(3):1012-1016.
- [3]陈文革,沈宏芳,丁秉均,等.W-Cu合金深冷处理及其组织性能研究[J].材料热处理学报,2004,25(6):44-47.CHENWen-ge,SHEN Hong-fang,DING Bing-jun,et al.Influence of cryogenic treatment on microstructure and properties of W-Cu alloys[J].Transactions of Materials and Heat Treatment,2004,25(6):44-47.
- [4]蔡辉,王亚平,宋晓平,等.铜基封装材料的研究进展[J].材料导报,2009,23(8):24-28.CAI Hui,WANG Ya-ping,SONG Xiao-ping,et al.Research progress in copper matrix composites for electronic packaging[J].Materials Review,2009,23(8):24-28.
- [5]徐凯.钨铜复合材料的现状与发展[J].中国钨业,2010,25(3):30-34..XU Kai.Current status and development of W-Cu composite materials[J].China Tungsten Industry,2010,25(3):30-34.
- [6]Jrg F,Lffler,William L,Johnson.Crystallization of Mg-Al and Al-based metallic liquids under ultra-high gravity[J].Intermetallics,2002(10):1167-1175.
- [7]Unuvar C,Fredrick D M,Anselmi-Tamburini U,et al.Gravity effects on reactive settling in the Al-W system in SHS[J].Intermetallics,2007(15):294-304.
- [8]PEI Jun,LI Jiang-tao,LIU Guang-Hua,et al.Fabrication of bulk Al2O3 by combustion synthesis melt-casting under ultra-high gravity[J].Journal ofAlloys and Compounds,2009,476:854-858.
- [9]殷声.燃烧合成[M].北京:冶金工业出版社,2004.
- [10]叶大伦.实用无机物热力学数据手册[M].北京:冶金出版社,1981.
- [11]宋月鹏.超重力铝热燃烧合成陶瓷材料绝热温度计算及过程仿真[C].北京:中国科学院理化技术研究所,2009.
- [12]纪文文,宋月鹏,杨筠,等.基于物质热力学数据库自蔓延反应体系绝热温度的计算及验证[J].硅酸盐通报,2009,28(6):897-902.JI Wen-wen,SONG Yue-peng,YANG Yun.Calculation andverification of adiabatic temperature of self-propagating reaction system based on thedatabase of materials thermodynamics[J].Bulletin of the Chinese Ceramic Society,2009,28(6):897-902.
- [13]LI Lai-jun,BI Qin-ling,YANG Jun,et al.Fabrication of bulk Al2O3 dispersed ultrafine-grained Cu matrix composite by self-propagating high-temperature synthesis casting route[J].Materials Letters,2008,62:2458-2460.
- [14]鲁学年.CuO/Al反应自生Al2O3增强铝基复合材料研究[D].甘肃工业大学,1999.
- [15]杨柳,宋月鹏.CuO/Al铝热剂体系绝热温度的计算机数值计算与分析研究[J].热加工工艺,2010,39(24):110-114.YANG Liu,SONG Yue-peng.Adiabatic temperature calculation and verification of CuO-Al aluminothermic system by computer simulation[J].HotWorking Technology,2010,39(24):110-114.
- [16]宋月鹏,李江涛,裴军,等.超重力燃烧合成大尺寸织构铁基金属材料[J].热加工工艺,2008,37(16):4-6.SONG Yue-peng,LI Jiang-tao,Pei Jun,et al.Preparation of large-scale textural microstructure Fe-based metallic composite by centrifugal-SHS method[J].Hot Working Technology,2008,37(16):4-6.
- [17]Wang L L,Munir Z A,Maximov Y M.Review thermite reactions:their utilization in the synthesis and processing of materials[J].Journal of MaterialsScience,1993,28:3693-3708.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||