长时热暴露对Mar-M247合金组织演变及高温拉伸性能的影响Effect of long-term thermal exposure on microstructure evolution and high temperature tensile properties of Mar-M247 alloy
罗超,商玉洁,高振桓,王西涛,何金珊
摘要(Abstract):
研究了等轴Mar-M247高温合金在800℃热暴露长达24000 h过程中的组织演变规律和800℃的高温拉伸强度和塑性。结果表明:热暴露5000 h前,合金的枝晶干二次γ′相、三次γ′相尺寸显著增大,热暴露5000~240000 h时,枝晶干二次γ′相尺寸没有明显变化,枝晶干三次γ′相尺寸略微增长。随热暴露时间延长,枝晶干二次γ′相体积分数增大,三次γ′相体积分数下降。根据两种γ′相的尺寸分布(PSD),两种γ′相的粗化均符合跨界面扩散控制(Trans-interface diffusion-controlled, TIDC)粗化理论;晶界处MC型碳化物通过MC+γ→M_(23)C_6+γ′反应逐渐分解,在晶界处形成γ′相膜,包裹着MC型碳化物和M_(23)C_6型碳化物。高温拉伸实验结果表明,随热暴露时间的延长,合金的屈服强度和抗拉强度先减小后基本不变,伸长率和断面收缩率先增大后减小再增大,在热暴露5000 h后,屈服强度和抗拉强度分别减小了164和76 MPa,而在热暴露5000~24000 h时,屈服强度和抗拉强度分别稳定在750和950 MPa。
关键词(KeyWords): 镍基高温合金;等轴Mar-M247合金;热暴露;组织演变;拉伸性能
基金项目(Foundation): 国家自然科学基金(52201102);; 长寿命高温材料国家重点实验室项目(DEC8300X202310074);; 山东省高校青年创新科技支撑计划(2020KJA002)
作者(Author): 罗超,商玉洁,高振桓,王西涛,何金珊
DOI: 10.13289/j.issn.1009-6264.2023-0482
参考文献(References):
- [1] Bor H Y,Wei C N,Jeng R R,et al.Elucidating the effects of solution and double ageing treatment on the mechanical properties and toughness of MAR-M247 superalloy at high temperature[J].Materials Chemistry and Physics,2008,109(2/3):334-341.
- [2] Liu M,Sheng G,He H,et al.Microstructural evolution and mechanical properties of TLP bonded joints of Mar-M247 superalloys with Ni-Cr-Co-W-Ta-B interlayer[J].Journal of Materials Processing Technology,2017,246:245-251.
- [3] Zhang Y,Wang Q,Dong H G,et al.High-temperature structural stabilities of Ni-based single-crystal superalloys Ni-Co-Cr-Mo-W-Al-Ti-Ta with varying Co contents[J].Acta Metallurgica Sinica (English Letters),2018,31:127-133.
- [4] Li H T,Liang Y C,Zhong W L,et al.Tensile properties and deformation behavior of several cast Ni-based superalloys fabricated by different solidification ways[J].Acta Metallurgica Sinica (English Letters),2017,30:280-288.
- [5] Li X,Ou M,Wang M,et al.Microstructure evolution and stress rupture properties of K4750 alloys with various B contents during long-term aging[J].Journal of Materials Science & Technology,2021,73:108-115.
- [6] Zhong Z,Gu Y,Yuan Y.Microstructural stability and mechanical properties of a newly developed Ni-Fe-base superalloy[J].Materials Science and Engineering A,2015,622:101-107.
- [7] Stevens R A,Flewitt P E J.The effects of γ′ precipitate coarsening during isothermal aging and creep of the nickel-base superalloy IN-738[J].Materials Science and Engineering,1979,37(3):237-247.
- [8] Xiong X,Quan D,Dai P,et al.Tensile behavior of nickel-base single-crystal superalloy DD6[J].Materials Science and Engineering A,2015,636:608-612.
- [9] Jiang X W,Wang D,Xie G,et al.The effect of long-term thermal exposure on the microstructure and stress rupture property of a directionally solidified Ni-based superalloy[J].Metallurgical and Materials Transactions A,2014,45:6016-6026.
- [10] Jeong H W,Seo S M,Choi B G,et al.Effect of long-term thermal exposures on microstructures and mechanical properties of directionally solidified CM247LC alloy[J].Metals and Materials International,2013,19:917-925.
- [11] 杨胜杰,周佳金,张文吉,等.热处理对MAR-M247焊件微区组织和力学性能的影响[J].成都大学学报(自然科学版),2022,41(4):393-400.YANG Sheng-jie,ZHOU Jia-jin,ZHANG Wen-ji,et al.Effect of heat treatment on microstructure and mechanical properties of MAR-M247 weldment[J].Journal of Chengdu University (Natural Science Edition),2022,41(4):393-400.
- [12] Bor H Y,Chao C G,Ma C Y.The influence of magnesium on carbide characteristics and creep behavior of the Mar-M247 superalloy[J].Scripta Materialia,1997,38(2):329-335.
- [13] Nathal M V,Maier R D,Ebert L J.The influence of cobalt on the microstructure of the nickel-base superalloy MAR-M247[J].Metallurgical Transactions A,1982,13:1775-1783.
- [14] Li L,Gong X,Wang C,et al.Correlation between phase stability and tensile properties of the Ni-based superalloy MAR-M247[J].Acta Metallurgica Sinica (English Letters),2021,34:872-884.
- [15] Ducki J K,Rodak K,Wojtynek L.Precipitation and growth of intermatallic phases in an Fe-Ni superalloy during prolonged ageing[J].Solid State Phenomena,2016,4090:246-246.
- [16] Lifshitz I M,Slyozov V V.The kinetics of precipitation from supersaturated solid solutions[J].Journal of Physics and Chemistry of Solids,1961,19:35-50.
- [17] 张雷雷,陈晶阳,汤鑫,等.K439B等轴晶铸造高温合金800 ℃长期时效组织与性能演变[J].金属学报,2023,59(9):1253-1264.ZHANG Lei-lei,CHEN Jing-yang,TANG Xin,et al.Evolution of microstructures and mechanical properties of K439B equiaxed superalloy during long-term aging at 800 ℃[J].Acta Metallurgica Sinica,2023,59(9):1253-1264.
- [18] Ardell A,Ozolins V.Trans-interface diffusion-controlled coarsening[J].Nature Materials,2005,4:309-316.
- [19] Zhang J,Liu L,Huang T,et al.Coarsening kinetics of γ′ precipitates in a re-containing Ni-based single crystal superalloy during long-term aging[J].Journal of Materials Science & Technology,2021,62:1-10.
- [20] Qin X Z,Guo J T,Yuan C,et al.Effects of long-term thermal exposure on the microstructure and properties of a cast Ni-base superalloy[J].Metallurgical and Materials Transactions A,2007,38:3014-3022.
- [21] Wang J,Zhou L,Qin X,et al.Primary MC decomposition and its effects on the rupture behaviors in hot-corrosion resistant Ni-based superalloy K444[J].Materials Science and Engineering A,2012,553:14-21.
- [22] Qin X,Guo J,Yuan C,et al.Thermal stability of primary carbides and carbonitrides in two cast Ni-base superalloys[J].Materials Letters,2008,62(15):2275-2278.
- [23] Garosshen T J,McCarthy G P.Low temperature carbide precipitation in a nickel base superalloy[J].Metallurgical Transactions A,1985,16:1213-1223.
- [24] Wang C,Guo Y A,Guo J,et al.Microstructural changes and their effect on tensile properties of a Ni-Fe based alloy during long-term thermal exposure[J].Materials Science and Engineering A,2016,670:178-187.
- [25] Horikawa K,Kuramoto S,Kanno M.Intergranular fracture caused by trace impurities in an Al-5.5 mol% Mg alloy[J].Acta Materialia,2001,49(19):3981-3989.
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