镁合金微弧氧化陶瓷层形成及生长过程Research on formation and growth process of ceramic coatings on magnesium alloy by micro-arc oxidation
葛延峰,蒋百灵,王聪婕,龙燚
摘要(Abstract):
为了探讨通电时间对镁合金微弧氧化陶瓷层形成和生长过程的影响规律,利用高速相机记录微弧放电状态,采用扫描电子显微镜观察膜层表面形貌,借助电化学测试分析膜层表面阻值,根据电压变化曲线计算能量消耗。结果表明:随微弧氧化时间增加,镁合金表面微弧放电斑点由边缘逐渐扩展至整个表面,放电强度增大且数量增多;微弧氧化初期,样品表面有含氧元素的不规则颗粒生成,数量逐渐增多,直至起弧瞬间形成孔径小于0.2μm的放电微孔;随微弧氧化时间增加镁合金表面阻值增大,直至3.1×104Ω时出现明显微弧放电现象;镁合金微弧氧化各时间段所消耗能量逐渐升高,陶瓷层生长阶段能量消耗54.62 k J明显高于起弧阶段的7.98 k J。
关键词(KeyWords): 镁合金;微弧氧化;微观结构;放电状态;能量消耗
基金项目(Foundation): 国家自然科学基金(51071121、51271144)
作者(Author): 葛延峰,蒋百灵,王聪婕,龙燚
DOI: 10.13289/j.issn.1009-6264.2014.12.034
参考文献(References):
- [1]Gupta P,Tenhundfeld G,Daigle E O.Electrolytic plasma technology:Science and engineering-an overview[J].Surface and Coatings Technology,2007,201(21):8746-8760.
- [2]Xin Shi-Gang,Song Li-Xin,Zhao Rong-Gen.Properties of aluminum oxide coating on aluminum alloy produced by micro-arc oxidation[J].Surface and Coatings Technology,2005,199(2):184-188.
- [3]Jaspard-Mecuson,Czerwiec T,Henrion G,et al.Tailored aluminium oxide layers by bipolar current adjustment in the plasma electrolytic oxidation(PEO)process[J].Surface and Coatings Technology,2007,201(21):8677-8682.
- [4]Yerokhin A L,Snizhko L O,Gurevina L,et al.Discharge characterization in plasma electrolytic oxidation of aluminium[J].Journal of Applied Physics,2003,36:2110-2120.
- [5]蒋百灵,刘东杰.制约微弧氧化技术应用开发的几个科学问题[J].中国有色金属学报,2011,21(10):2402-2407.JIANG Bai-ling,LIU Dong-jie.Scientific aspects of restricting development and application of micro-arc oxidation technology[J].The Chinese Journal of Nonferrous Metals,2011,21(10):2402-2407.
- [6]葛延峰,蒋百灵,时惠英.电流脉冲宽度对铝合金微弧氧化过程的影响[J].材料热处理学报,2013,34(10):165-169.GE Yan-feng,JIANG Bai-ling,SHI Hui-ying.Effect of current pulse width on micro-arc oxidation process for aluminum alloys[J].Transactions of Materials and Heat Treatment,2013,34(10):165-169.
- [7]Nie X,Leyland A,Song H W,et al.Thickness effects on the mechanical properties of micro-arc discharge oxide coatings on aluminium alloys[J].Surface and Coatings Technology,1999,116-119(9):1055-1060.
- [8]Yerokhin A L,Shatrov T A,Samsonov V,et al.Oxide ceramic coatings on aluminium alloys produced by a pulsed bipolar plasma electrolytic oxidation process[J].Surface and Coatings Technology,2005,199:150-157.
- [9]蒋百灵,吴国建,张淑芬,等.镁合金微弧氧化陶瓷层生长过程及微观结构的研究[J].材料热处理学报,2002,23(1):5-7.JIANG Bai-ling,WU Guo-jian,ZHANG Shu-fen,et al.The research on micromechanism and growth procedure of ceramic coating formed by micro-arc oxidation on magnesium alloys[J].Transactions of Materials and Heat Treatment,2002,23(1):5-7.
- [10]Xue W B,Wang C,Li Y L,et al.Effect of microarc discharge surface treatment on the tensile properties of Al-Cu-Mg alloy[J].Materials Letters,2002,56:737-743.
- [11]龚巍巍,张乐,吴晓玲.镁合金等离子体微弧氧化过程控制的研究[J].材料热处理学报,2005,26(1):77-80.GONG Wei-wei,ZHANG Le,WU Xiao-ling.Controlling process of plasma microarc oxidation on magnesium alloy[J].Transactions of Materials and Heat Treatment,2005,26(1):77-80.
- [12]郝建民,田新宇,陈宏,等.镁合金微弧氧化黑色膜的制备工艺和结构[J].材料热处理学报,2011,32(7):164-168.HAO Jian-min,TIAN Xin-yu,CHEN Hong,et al.Preparation process and microstructure of black coatings on magnesium alloy by micro-arc oxidation[J].Transactions of Materials and Heat Treatment,2011,32(7):164-168.
- [13]郭锋,刘瑞霞,李鹏飞,等.电解液中的稀土对AZ91D镁合金微弧氧化陶瓷层的影响[J].材料热处理学报,2011,32(2):134-138.GUO Feng,LIU Rui-xia,LI Peng-fei,et al.Effect of rare earth elements in electrolyte on ceramic coating prepared by micro-arc oxidation on AZ91D magnesium alloy[J].Transactions of Materials and Heat Treatment,2011,32(2):134-138.
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