激光熔覆制备Fe-Mo-Ni-Si-B非晶纳米晶复合涂层的性能Properties of Fe-Mo-Ni-Si-B amorphous nanocrystalline composite coating fabricated by laser cladding
付琴,胡树兵
摘要(Abstract):
利用激光熔覆技术在45钢上制备Fe-Mo-Ni-Si-B涂层,并进行激光重熔处理。借助光学光学显微镜、环境扫描电子显微镜、X射线衍射仪对涂层的组织结构进行研究,并利用维氏硬度计、磨损试验机、电化学工作站等设备分析了重熔前后涂层的显微硬度、摩擦磨损及耐腐蚀性能。结果表明:利用激光熔覆技术能够在45钢上获得冶金结合良好的Fe-Mo-Ni-Si-B非晶纳米晶复合涂层。熔覆层由晶体相和非晶相混合组成,主要的晶体相包括Fe Si、Fe2B、Fe Ni、Fe3Mo及Fe单质。经过重熔处理后,熔覆层组织细化,晶粒更为细小,非晶相比例提高。熔覆层的硬度可达到1007 HV0.1,而重熔层硬度略提高到1076 HV0.1,与基体相比,都提高了5~6倍;与基体相比,熔覆层的耐磨性和耐蚀性得以提高,其中重熔层更是表现出优异的耐磨性和耐蚀性。
关键词(KeyWords): 激光熔覆;激光重熔;显微组织;耐磨性;耐蚀性
基金项目(Foundation): 国家自然科学基金(51375005);; 国家973项目(2014CB046704);; 2010年省部产学研合作重大项目(2010A090200047)
作者(Author): 付琴,胡树兵
DOI: 10.13289/j.issn.1009-6264.2015.11.035
参考文献(References):
- [1]Riveiro A,Mejias A,Pardo J,et al.Laser cladding of aluminum on AISI 304 stainless steel with high-power diode lasers[J].Surface and Coatings Technology,2014,253:214-220.
- [2]D'Amato C,Betts John C.Laser surface alloying of an A356 aluminum alloy using nickel and Ni-Ti-C:A corrosion study[J].Surface and Coatings Technology,2014,244:194-202.
- [3]高亚丽,王存山,刘红宾,等.AZ91HP镁合金真空激光熔凝晶粒细化[J].材料热处理学报,2006,27(1):92-95.GAO Ya-li,WANG Cun-shan,LIU Hong-bin,et al.Grain refinement of AZ91HP magnesium alloy treated by vacuum laser melting[J].Transactions of Materials and Heat Treatment,2006,27(1):92-95
- [4]张坚,邱斌,赵龙志,等.激光熔覆技术研究进展[J].热加工工艺,2011,40(18):116-119.ZHANG Jian,QIU Bin,ZHAO Long-zhi,et al.Latest developments of laser cladding technology[J].Hot Working Technology,2011,40(18):116-119.
- [5]Zeng C,Liao W H.Study of laser cladding thermal damage:A quantified micro hardness method[J].Surface and Coatings Technology,2013,236:309-314.
- [6]臧辰峰,刘常升,张小彬,等.轧辊表面激光处理技术的研究进展[J].材料导报,2010,24(3):6-10.ZANG Chen-feng,LIU Chang-sheng,ZHANG Xiao-bin,et al.Research progress of laser modification techniques used on roller surface[J].Materials Review,2010,24(3):6-10.
- [7]丁阳喜,柴柱.K1000型钢轨焊机推瘤刀激光熔覆修复研究[J].中国铁道科学,2012,33(2):71-75.DING Yang-xi,CHAI Zhu.Research on repairing the knob removing tool used for K1000 rail welding by laser cladding[J].China Railway Science,2012,33(2):71-75.
- [8]Inoue A,Shen B L.Super-high strength of over 4000 MPa for Fe-based bulk glassy alloys in[(Fe1-xCox)0.75B0.2Si0.05]96Nb4 system[J].Acta Materialia,2004,52(14):4093-4099.
- [9]He J H,Wang W.Annealing temperature effect on microstructure,magnetic and microwave properties of Fe-based amorphous alloy powders[J].Journal of Magnetism and Magnetic Materials,2012,324(18):2902-2906.
- [10]Pang S J,Zhang T.Bulk glassy Fe-Cr-Mo-C-B alloys with high corrosion resistance[J].Corrosion Science,2002,44(8):1847-1856.
- [11]Katakam S,Kumar V.Laser assisted Fe-based bulk amorphous coating:Thermal effects and corrosion[J].Journal of Alloys and Compounds,2014,604:266-272.
- [12]ZHANG P L,LU Y L.Effect of Nb addition on Fe-Ni-B-Si amorphous and crystalline composite coatings by laser processing[J].Surface and Coatings Technology,2013,236:84-90.
- [13]武晓雷,洪友士.激光熔覆铁基大厚度非晶合金表层的研究[J].材料热处理学报,2001,22(1):51-54.WU Xiao-lei,HONG You-shi.Thick amorphous coating of Fe-based alloy by laser cladding[J].Trans Mater Heat Treat,2001,22(1):51-54.
- [14]刘喜军,常铁军.材料近代分析方法[M].哈尔滨:哈尔滨工业大学出版社,2005.
- [15]王吉会.材料力学性能[M].天津:天津大学出版社,2006.
- [16]YANG Y,WU H.Improving the wear resistance of AZ91D magnesium alloys by laser cladding with Al-Si powders[J].Materials Letters,2009,63(1):19-21.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||