魏敬鹏,高巍,程赵辉,要玉宏,金耀华,陈建,杨巍

• 1:西安工业大学材料与化工学院

摘要(Abstract)：

在电解液中加入不同浓度的焦磷酸铜对TC4进行微弧氧化处理,对微弧氧化层进行了粗糙度和显微硬度测试,通过扫描电镜(SEM)、X射线衍射仪(XRD)及摩擦磨损测试分析了焦磷酸铜浓度对微弧氧化层微观结构及磨损性能的影响。结果表明:加入2 g/L焦磷酸铜后,微弧氧化层表面孔隙增大,数量增多,但随焦磷酸铜浓度的继续增加,微弧氧化层表面孔隙减小,数量减少。随着电解液中焦磷酸铜浓度的增加,微弧氧化层的厚度增加,硬度减小,摩擦系数曲线波动减小,其中电解液中加入2 g/L焦磷酸铜时微弧氧化层的摩擦系数最小,微弧氧化层的摩痕宽度随着电解液中焦磷酸铜浓度的增加而减小,焦磷酸铜浓度为8 g/L时,由于铜元素的润滑作用,微弧氧化层的磨痕最轻微,磨痕宽度最窄。

关键词(KeyWords)： 钛合金;微弧氧化;焦磷酸铜;硬度;摩擦性能

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金面上项目(52071252)

作者(Author): 魏敬鹏,高巍,程赵辉,要玉宏,金耀华,陈建,杨巍

DOI: 10.13289/j.issn.1009-6264.2020-0361

参考文献(References)：

• [1] 杨佩，康聪，李维.TC4钛合金工艺进展[J].湖南有色金属，2020,36(1):45-47.YANG Pei,KANG Cong,LI Wei.Progress in technology of TC4 titanium alloy[J].Hunan Nonferrous Metals,2020,36(1):45-47.
• [2] Yang W,Gao Y,Guo P,et al.Adhesion,biological corrosion resistance and biotribological properties of carbon films deposited on MAO coated Ti substrates[J].Journal of the Mechanical Behavior of Biomedical Materials,2019(101):103448.
• [3] 江洪，陈亚杨.钛合金在舰船上的研究及应用进展[J].新材料产业，2018(12):11-14.JIANG Hong,CHEN Ya-yang.Research and application progress of titanium alloy on ship[J].New Materials Industry,2018(12):11-14.
• [4] 孙静，齐元甲，刘辉，等.海洋环境下钛及钛合金的腐蚀磨损研究进展[J].材料保护，2020,53(1):151-156.SUN Jing,QI Yuan-jia,LIU Hui,et al.Research progress on tribo-corrosion of titanium and titanium alloys in seawater environment[J].Materials Protection,2020,53(1):151-156.
• [5] 任超，罗军明，陈宇海，等.喷丸对TC4合金微弧氧化涂层磨损和腐蚀行为的影响[J].材料导报，2020(18):1-15.REN Chao,LUO Jun-ming,CHEN Yu-hai,et al.Effect of shot peening on wear and corrosion behavior of micro-arc oxidation coating of TC4 alloy[J].Materials Reports,2020(18):1-15.
• [6] 潘晓龙，刘啸锋，王少鹏.TC4钛合金表面磁控溅射TiAlN涂层的组织与性能[J].钛工业进展，2013,30(5):31-34.PAN Xiao-long,LIU Xiao-feng,WANG Shao-peng.Microstructure and properties of TiAlN coating prepared by magnetron sputtering on titanium alloy[J].Titanium Industry Progress,2013,30(5):31-34.
• [7] 孙荣禄，牛伟，雷贻文，等.钛合金TC4激光熔覆NiCrBSi + Ni/MoS2涂层组织和摩擦磨损性能[J].材料热处理学报，2014,35(6):157-162.SUN Rong-lu,NIU Wei,LEI Yi-wen,et al.Microstructure and tribological properties of laser clad NiCrBSi + Ni/MoS2 coating on TC4 titanium alloy[J].Transactions of Materials and Heat Treatment,2014,35(6):157-162.
• [8] 王军军，何浩然，黄伟九，等.Cr基过渡层对钛合金表面类金刚石薄膜摩擦学性能的影响[J].中国表面工程，2018,31(3):61-67.WANG Jun-jun,HE Hao-ran,HUANG Wei-jiu,et al.Effects of Cr-based interlayers on tribological property of diamond-like carbon films on titanium alloy[J].China Surface Engineering,2018,31(3):61-67.
• [9] 武上焜，杨巍，高羽，等.6061铝合金表面新型黄色微弧氧化陶瓷层的制备与表征[J].表面技术，2019,48(7):142-149.WU Shang-kun,YANG Wei,GAO Yu,et al.Preparation and characterization of new yellow ceramic coating by micro arc oxidation on 6061 aluminum alloy[J].Surface Technology,2019,48(7):142-149.
• [10] Cheng Z H,Yang W,Xu D P,et al.Improvement of high temperature oxidation resistance of micro arc oxidation coated AlTiNbMo0.5Ta0.5Zr high entropy alloy[J].Materials Letters,2019,262:127192.
• [11] Wang S Q,Xie F Q,Wu X,et al.Cathodic plasma electrolytic deposition of ZrO2/YSZ doped Al2O3 ceramic coating on TiAl alloy[J].Ceramics International,2019,45(15):18899-18907.
• [12] Lian Y,Dai X,Zhang J.Characterization of micro-arc oxidation coatings on Ti6Al4V with addition of SiC particle[J].Materials Research Express,2020,7(1):016438.
• [13] Krishna L R,Madhavi Y,Sahithi T,et al.Influence of prior shot peening variables on the fatigue life of micro arc oxidation coated 6061-T6 Al alloy[J].International Journal of Fatigue,2017,106(1):165-174.
• [14] Aliofkhazraei M,Rouhaghdam A S,Shahrabi T.Abrasive wear behaviour of Si3N4/TiO2 nanocomposite coatings fabricated by plasma electrolytic oxidation[J].Surface and Coatings Technology,2010,205(7):S41-S46.
• [15] 郝建民，王超，陈宏.Ti-6Al-4V表面ZrO2/TiO2微弧氧化复合陶瓷层的生长特性[J].材料热处理学报，2015,36(3):165-170.HAO Jian-min,WANG Chao,CHEN Hong.Growth characteristics of ZrO2/TiO2 composite ceramic coatings prepared by micro-arc oxidation on Ti-6Al-4V[J].Transactions of Materials and Heat Treatment,2015,36(3):165-170.
• [16] Yang W,Wu S K,Xu D P,et al.Preparation and performance of alumina ceramic coating doped with aluminum nitride by micro arc oxidation[J].Ceramics International,2020,46(10):17112-17116.
• [17] Wang S Q,Xie F Q,Wu X,et al.Microstructure and high temperature oxidation behavior of the Al2O3 CPED coating on TiAl alloy[J].Journal of Alloys and Compounds,2020,828:154271.
• [18] 边蕴静.船舶防污涂料最新发展[J].中国涂料，2015,30(8):9-12.BIAN Yun-jing.Latest development of marine antifouling coatings[J].China Coatings,2015,30(8):9-12.
• [19] 王佳兴，张剑锋，赵文杰，等.氧化亚铜纳米颗粒的制备及其释放速率测定[J].中国表面工程，2015,28(2):138-143.WANG Jia-xing,ZHANG Jian-feng,ZHAO Wen-jie,et al.Preparation of Cu2O nanoparticles and their release rate determination[J].China Surface Engineering,2015,28(2):138-143.
• [20] 黄利保，郝建民，张斌英，等.2A12铝合金在两种体系中微弧氧化膜层的磨损性能研究[J].表面技术，2020,49(5):185-190.HUANG Li-bao,HAO Jian-min,ZHANG Bin-ying,et al.Wear properties of microarc oxidation coating of 2A12 aluminum alloy in two systems[J].Surface Technology,2020,49(5):185-190.
• [21] 齐玉明，彭振军，刘百幸，等.钛合金表面高硬度微弧氧化膜的制备和耐磨性研究[J].表面技术，2019,48(7):81-88.QI Yu-ming,PENG Zhen-jun,LIU Bai-xing,et al.Fabrication and wear resistance of hard micro arc oxidation coatings on Ti alloys[J].Surface Technology,2019,48(7):81-88.

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