卢金山,彭长浩,邓莉萍,冯志军,李喜宝

• 1:南昌航空大学材料科学与工程学院

摘要(Abstract)：

以废玻璃、粉煤灰为主要原料,利用快速烧结-晶化法制备斜辉石-钙长石微晶玻璃。利用XRD和SEM研究了升温速率对微晶玻璃烧结-晶化行为和显微结构影响。结果表明,与10℃/min常规烧结相比,30℃/min以及烧结温度下直接置入烧结的烧结激活能显著降低,微晶玻璃体积密度更大、气孔孔径更小。快速升温时最佳烧结温度明显降低,且钙长石晶相出现择优取向生长,导致微晶玻璃抗弯强度增大,950℃下直接置入烧结的微晶玻璃抗弯强度达到最高值107 MPa。

关键词(KeyWords)： 废玻璃;粉煤灰;微晶玻璃;烧结-晶化行为;抗弯强度

Abstract:

Keywords:

基金项目(Foundation): 江西省教育厅科研项目(GJJ11497);; 江西省研究生创新基金(YC10A111)

作者(Author): 卢金山,彭长浩,邓莉萍,冯志军,李喜宝

DOI: 10.13289/j.issn.1009-6264.2013.01.002

参考文献(References)：

• [1]Rawlings R D,Wu J P,Boccaccinia A R.Glass-ceramics:Their production from wastes—A review[J].Journal of Mateials Science,2006,41(3):733-761.
• [2]梁晓娟,周永强,刘海涛.废玻璃在建筑微晶玻璃中的应用研究[J].中国陶瓷,2006,42(5):49-51.LIANG Xiao-juan,ZHOU Yong-qiang,LIU Hai-tao.Study on the application of waste glass to the building glass-ceramics[J],China Cermics,2006,42(5):49-51.
• [3]Pontikes Y,Esposito L,Tucci A,et al.Thermal behaviour of clays for traditional ceramics with soda-lime-silica waste glass admixture[J].Journalof the European Ceramic Society,2007,27(2-3):1657-1663.
• [4]杨超,阮玉忠,曾华瑞.CaF2对废碎建筑玻璃制微晶玻璃析晶的影响[J].陶瓷学报,2009,30(1):59-63.YANG Chao,RUAN Yu-zhong,ZENG Hua-rui.Effect of CaF2 on glass-ceramics prepared from abandoned architectural glass[J].Journal ofCeramics,2009,30(1):59-63.
• [5]Bernardo E,Scarinci G,Edme E,et al.Fast-sintered gehlenite glass-ceramics from plasma-vitrified municipal solid waste incinerator fly ashes[J].Journal of the American Ceramic Society,2009,92(2):528-530.
• [6]Bernardo E,Dattoli A,Bonomo E.Application of an industrial waste glass in“glass-ceramic stoneware”[J].International Journal of AppliedCeramic Technology,2011,8(5):1153-1162.
• [7]Yuruyen S,Toplan H O.The sintering kinetics of porcelain bodies made from waste glass[J].Ceramics International,2009,35(6):2427-2433.
• [8]Clark T J,Reed J S.Kinetic processes involved in the sintering and crystallization of glass powders[J].Journal of the American Ceramic Society,1986,69(11):837-846.
• [9]Ray A,Tiwari A N.Compaction and sintering behaviour of glass-alumina composites[J].Materials Chemistry and Physics,2001,67(1-3):220-225.
• [10]Karamanov A,Pelino M,Hreglich S.Sintered glass-ceramics from municipal solid waste-incinerator fly ashes—Part I:The influence of the heatingrate on the sinter-crystallization[J].Journal of the European Ceramic Society,2003,23(6):827-832.
• [11]Bernardo E,Castellan R,Hreglich S.Sintered glass-ceramics from mixtures of wastes[J].Ceramics International,2007,33(1):27-33.
• [12]Bernardo E,Esposito L,Rambaldi E,et al.Recycle of waste glass into“glass-ceramic stoneware”[J].Journal of the American Ceramic Society,2008,91(7):2156-2162.
• [13]Bernardo E,Scarinci G.Fast sinter-crystallization of glasses from mixtures of wastes[J].Advances in Applied Ceramics,2008,107(6):344-349..
• [14]Boccaccini A R.On the viscosity of glass composites containing rigid inclusions[J].Materials Letters,1998,34(3-6):285-289.
• [15]Bernardo E.Fast sinter-crystallization of a glass from waste materials[J].Journal of Non-Crystalline Solids,2008,354(29):3486-3490.
• [16]Bernardo E,Bonomo E,Dattoli A.Optimisation of sintered glass-ceramics from an industrial waste glass[J].Ceramics International,2010,36(5):1675-1680.
• [17]Gualtieri A F.Thermal behaviour of the raw materials forming porcelain stoneware mixtures by combined optical and in situ X-ray dilatometry[J].Journal of the American Ceramic Society,2007,80(4):1222-1231.
• [18]ISO 13006.Ceramic tiles—definitions,classification,characteristics and marking[S].International Organization for Standardization,Geneva,Switzerland,1998.

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