铝合金中半共格析出相的研究进展Research progress on semi-coherent precipitates in aluminum alloys
高志国,陈泽智
摘要(Abstract):
对铝合金中具有工程应用价值的半共格析出相进行了综述,重点关注了典型热处理铝合金中的半共格相,包括2xxx系铝合金的θ′相、S′相和Ω相,6xxx系铝合金的β′相和Q′相,7xxx系铝合金的η′相。介绍了铝合金中这些半共格析出相的晶体结构、点阵参数、惯析面、晶体学关系等,以及它们对铝合金的强化效应。此外,还介绍了3xxx系铝合金中的α-Al(Mn, Fe)Si部分共格弥散相,虽然共格关系存在争议,但该相具有较高的热稳定性,有利于提高铝合金的高温强度。本文旨在为建立铝合金半共格强化相与力学性能之间的关系提供支持,为研发新一代铝合金提供参考。
关键词(KeyWords): 铝合金;半共格相;晶体结构;强化
基金项目(Foundation): 福建省工业引导性项目(2022H0054)
作者(Author): 高志国,陈泽智
DOI: 10.13289/j.issn.1009-6264.2024-0269
参考文献(References):
- [1] 高志国,徐武锋.Al-xCu 合金中θ′析出相稳定性的研究进展[J].材料热处理学报,2023,44(6):11-19.GAO Zhi-guo,XU Wu-feng.Research progress on stability of θ′ precipitates in Al-xCu alloys[J].Transactions of Materials and Heat Treatment,2023,44(6):11-19.
- [2] Chen S W,Huang C C.Solidification curves of Al-Cu,Al-Mg and Al-Cu-Mg alloys[J].Acta Materialia,1996,44(5):1955-1965.
- [3] Kim K.Thermodynamics and kinetics of aluminum alloys[D].Evanston:Northwestern University,2017.
- [4] Bourgeois L,Medhekar N V,Smith A E,et al.Efficient atomic-scale kinetics through a complex heterophase interface[J].Physical Review Letters,2013,111(4):046102.
- [5] Poplawsky J D,Milligan B K,Allard L F,et al.The synergistic role of Mn and Zr/Ti in producing θ′/L12 co-precipitates in Al-Cu alloys[J].Acta Materialia,2020,194:577-586.
- [6] Shyam A,Roy S,Shin D,et al.Elevated temperature microstructural stability in cast AlCuMnZr alloys through solute segregation[J].Materials Science and Engineering A,2019,765(2):138279.
- [7] Chen X,Marioara C D,Andersen S J,et al.Precipitation processes and structural evolutions of various GPB zones and two types of S phases in a cold-rolled Al-Mg-Cu alloy[J].Materials and Design,2021,199:109425.
- [8] 吕可欣.2xxx系铝合金主要强化相的微观结构研究[D].上海:上海交通大学,2019.Lü Ke-xin.Study on microstructure of main strengthening phases of 2xxx aluminum alloy[D].Shanghai:Shanghai Jiao Tong University,2019.
- [9] 范才河,范语楠,胡泽艺,等.快速冷冲对喷射成形 Al-Cu-Mg 合金长片状 S′ 相的演变规律[J].中国有色金属学报,2020,30(7):1544-1551.FAN Cai-he,FAN Yu-nan,HU Ze-yi,et al.Effect of rapid cold stamping on evolution of long strip S′ phase in spray-formed Al-Cu-Mg alloy[J].The Chinese Journal of Nonferrous Metals,2020,30(7):1544-1551.
- [10] Hu Z Y,Fan C H,Shen T,et al.Effect of aging treatment on evolution of S′ phase in rapid cold punched Al-Cu-Mg alloy[J].Transactions of Nonferrous Metals Society of China,2021,31(7):1930-1938.
- [11] 宋旼,肖代红,黄伯云.Al-Cu-Mg-Ag合金中半共格Ω析出相与位错的交互作用[J].北京工业大学学报,2008,34(10):1093-1097.SONG Min,XIAO Dai-hong,HUANG Bo-yun.Interaction between semi-coherent Ω precipitates and dislocations in Al-Cu-Mg-Ag Alloy[J].Journal of Beijing University of Technology,2008,34(10):1093-1097.
- [12] Ringer S P,Hono K,Polmear I J,et al.Nucleation of precipitates in aged Al-Cu-Mg-(Ag) alloys with high Cu:Mg ratios[J].Acta Materialia,1996,44(5):1883-1898.
- [13] Knowles K M,Stobbs W M.The structure of {111} age-hardening precipitates in Al-Cu-Mg-Ag alloys[J].Acta Crystallographica Section B,1988,44(3):207-227.
- [14] Tai C L,Chen M C,Chung T F,et al.The nano-structural characterization of Ω and S phases in Al-5.1Cu-1.0Mg-(0.4Ag) AA2024 aluminum alloys[J].Materials Science and Engineering A,2023,881:145361.
- [15] 刘志义,李云涛,刘延斌,等.A1-Cu-Mg-Ag 合金析出相的研究进展[J].中国有色金属学报,2007,17(12):1905-1915.LIU Zhi-yi,LI Yun-tao,LIU Yan-bin,et al.Development of Al-Cu-Mg-Ag alloys[J].The Chinese Journal of Nonferrous Metals,2007,17(12):1905-1915.
- [16] Ringer S P,Yeung W,Muddle B C,et al.Precipitate stability in Al-Cu-Mg-Ag alloys aged at high temperatures[J].Acta Metallurgica et Materialia,1994,42(5):1715-1725.
- [17] Liu K,Chen X G.Development of Al-Mn-Mg 3004 alloy for applications at elevated temperature via dispersoid strengthening[J].Materials and Design,2015,84:340-350.
- [18] Li Y J,Muggerud A M F,Olsen A,et al.Precipitation of partially coherent α-Al(Mn,Fe)Si dispersoids and their strengthening effect in AA 3003 alloy[J].Acta Materialia,2012,60(3):1004-1014.
- [19] Song R,Kumai S.Solidi?cation structure and secondary particles in vertical-type high-speed twin-roll cast 3003 aluminum alloy strip[J].Materials Transactions,2019,60(2):322-329.
- [20] 侯哲,徐志远.箔材用3003铝合金的热处理和性能[J].上海金属,2020,42(2):50-56.HOU Zhe,XU Zhi-yuan.Heat treatment and properties of 3003 aluminum alloy for Foil[J].Shanghai Metals,2020,42(2):50-56.
- [21] Qian F,Jin S,Wan D,et al.Synergistic effects of Cd,Si and Cr additions on precipitation strengthening and thermal stability of dispersoids in AA3003 alloy[J].Materials Science and Engineering A,2022,832:142422.
- [22] Li Z,Zhang Z,Chen X G.Effect of magnesium on dispersoid strengthening of Al-Mn-Mg-Si (3xxx) alloys[J].Transactions of Nonferrous Metals Society of China,2016,26(11):2793-2799.
- [23] Zandbergen H W,Andersen S J,Jansen J.Structure determination of Mg5Si6 particles in Al by dynamic electron diffraction studies[J].Science,1997,277(5330):1221-1225.
- [24] 王志伟,汪明朴,王正安,等.在线挤压淬火对地铁列车用6005A合金力学性能及微观组织的影响[J].中国有色金属学报,2001,11(4):603-606.WANG Zhi-wei,WANG Ming-pu,WANG Zheng-an,et al.Effects of on-line extrusion quenching technique on mechanical properties and microscopic structure of 6005A alloys employed in underground railway trains[J].The Chinese Journal of Nonferrous Metals,2001,11(4):603-606.
- [25] 杨文超.Al-Mg-Si-Cu系6005A合金的时效硬化行为及析出相的微观结构表征[D].长沙:中南大学,2011.YANG Wen-chao.Age-hardening behavior and microstructural characterization of precipitates in Al-Mg-Si-Cu:6005A alloy[D].Changsha:Central South University,2011.
- [26] 杨文超,汪明朴,盛晓菲,等.轨道交通车辆用6005A合金板材时效析出及硬化行为研究[J].金属学报,2010,46(12):1481-1487.YANG Wen-chao,WANG Ming-pu,SHENG Xiao-fei,et al.Study of the aging precipitation and hardening behavior of 6005A alloy sheet for rail traffic vehicle[J].Acta Metallurgica Sinica,2010,46(12):1481-1487.
- [27] 黄创高,黄礼琳,袁龙乐,等.Al-Mg-Si合金β′析出相的界面原子键络对性能的影响[J].中国有色金属学报,2013,23(3):610-615.HUANG Chuang-gao,HUANG Li-lin,YUAN Long-le,et al.Effect of atomic bonding of interface of β′ phase on property of Al-Mg-Si alloy[J].The Chinese Journal of Nonferrous Metals,2013,23(3):610-615.
- [28] 任建平,宋仁国,陈小明,等.7xxx系铝合金热处理工艺的研究现状及进展[J].热加工工艺,2009,38(6):119-124.REN Jian-ping,SONG Ren-guo,CHEN Xiao-ming,et al.Development and states of heat-treatment process for 7xxx series aluminum alloys[J].Hot Working Technology,2009,38(6):119-124.
- [29] 李春梅,陈志谦,程南璞,等.7055 超高强、超高韧铝合金力学性能分析[J].金属热处理,2008,33(1):100-104.LI Chun-mei,CHEN Zhi-qian,CHENG Nan-pu,et al.Mechanical properties of 7055 ultrahigh-strength and ultrahigh-ductility aluminum alloy[J].Heat Treatment of Metals,2008,33(1):100-104.
- [30] 曾渝,尹志民,潘青林,等.超高强铝合金的研究现状及发展趋势[J].中南工业大学学报,2002,33(6):592-596.ZENG Yu,YIN Zhi-min,PAN Qin-lin,et al.Present research and developing trends of ultra high strength aluminum alloys[J].Journal of Central South University of Technology,2002,33(6):592-596.
- [31] Li X Z,Hansen V,Gj?nnes J,et al.HREM study and structure modeling of the η′ phase,the hardening precipitates in commercial Al-Zn-Mg alloys[J].Acta Materialia,1999,47(9):2651-2659.
- [32] Ferragut R,Somoza A,Tolley A.Microstructural evolution of 7012 alloy during the early stages of artificial ageing[J].Acta Materialia,1999,47(17):4355-4364.
- [33] Wolverton C.Crystal structure and stability of complex precipitate phases in Al-Cu-Mg-(Si) and Al-Zn-Mg alloys[J].Acta Materialia,2001,49(16):3129-3142.
- [34] Zou Y,Wu X D,Tang S B,et al.Tailoring phase fractions of T′ and η′ phases in dual-phase strengthened Al-Zn-Mg-Cu alloy via ageing treatment[J].Transactions of Nonferrous Metals Society of China,2022,32(10):3182-3196.
- [35] 晁代义,孙有政,刘晓滕,等.Zn/Mg比及时效温度对Al-Zn-Mg-Cu系合金析出行为的影响[J].材料导报,2019,33(S2):398-401.CHAO Dai-yi,SUN You-zheng,LIU Xiao-teng,et al.Effect of Zn/Mg ratio and aging temperature on precipitation behavior of Al-Zn-Mg-Cu aluminum alloy[J].Materials Reports,2019,33(S2):398-401.
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