添加WS2/(Ni-P)包覆的激光制备高温自润滑耐磨复合涂层High temperature self-lubricating wear-resistant NiCr-Cr3C2/30% WS2(Ni-P) composite coating fabricated by laser cladding
郑晨,刘秀波,杨茂盛,王明娣,石世宏,傅戈雁,齐龙浩
摘要(Abstract):
为抑制WS2在激光熔覆过程中的分解,增加其与金属基体的相容性,采用化学镀的方法,在WS2粉末颗粒表面包覆一层微米级Ni-P合金,对比研究了添加包覆粉末和未包覆粉末所制备的高温自润滑耐磨复合涂层的微观组织和室温、300℃和600℃下的摩擦学性能。NiCr-Cr3C2/30%WS2(Ni-P)涂层组织主要为初生树枝状Cr7C3、共晶γ-(Fe,Ni)/Cr7C3和CrS,以及少量弥散分布的WS2;对涂层进行摩擦学实验表明,添加包覆粉末所制备的涂层摩擦学性能更佳,室温和300℃时,NiCr-Cr3C2/30%WS2(Ni-P)涂层有较低的摩擦系数,且室温、300℃和600℃时,NiCr-Cr3C2/30%WS2(Ni-P)涂层磨损率都低于NiCr-Cr3C2/30%WS2涂层。
关键词(KeyWords): 激光熔覆;化学镀Ni-P;固体润滑;摩擦学性能
基金项目(Foundation): 江苏省自然科学基金(BK2009134,BK2010267);; 苏州市科技计划项目(SYG201233,SG201273,SH201022,SYG201036);; 国家自然科学基金(51205266,11172191)
作者(Author): 郑晨,刘秀波,杨茂盛,王明娣,石世宏,傅戈雁,齐龙浩
DOI: 10.13289/j.issn.1009-6264.2013.06.028
参考文献(References):
- [1]俞友军,周键松.激光熔覆NiCr/Cr3C2-Ag-BaF2/CaF2金属基高温自润滑耐磨覆层的组织结构及摩擦学性能[J].中国表面工程,2010,23(3):64-73.YU You-jun,ZHOU Jian-song.Preparation and tribological properies of NiCr/Cr3C2-Ag-BaF2/CaF2 high temperature self-lubricating wear-resistantcoating[J].China Surface Engineering,2010,23(3):64-73.
- [2]张光钧,吴培桂,许佳宁.激光熔覆的应用基础研究进展[J].金属热处理,2011,36(1):5-13.ZHANG Guang-jun,WU Pei-gui,XU Jia-ning.Development of basic research for application of laser cladding technology[J].Heat Treatment ofMetals,2011,36(1):5-13.
- [3]Zhong M,Liu W.Laser surface cladding:the state of the art and challenges[J].Mechanical Engineering Science,2009,224:1041-1060.
- [4]陈哲源,徐江,刘文今,等.激光熔覆MoS2/TiC/Ni减摩耐磨复合涂层组织及磨损性能的研究[J].材料热处理学报,2007,28:253-258.CHEN Zhe-yuan,XU Jiang,LIU Wen-jin,et al.Study on microstructure and wear behaviors of MoS2/TiC/Ni composite wear-resistant coating by lasercladding[J].Transactions of Materials and Heat Treatment,2007,28:253-258.
- [5]XIONG Dang-sheng.Lubrication behavior of Ni-Cr-based alloys containing MoS2 at high temperature[J].Wear,2001,251:1094-1099.
- [6]章小峰,王爱华,张祥林.激光熔覆Ni45-CaF2-WS2自润滑涂层组织与性能[J].中国有色金属学报,2008,18(2):215-220.ZHANG Xiao-feng,WANG Ai-hua,ZHANG Xiang-lin.Microstructure and tribological properties of laser cladding Ni45-CaF2-WS2 self-lubricatingcoating[J].The Chinese Journal of Nonferrous Metals,2008,18(2):215-220.
- [7]LIU Xiu-bo,SHI Shi-hong,GUO Jian,et al.Microstructure and wear behavior ofγ/Al4C3/TiC/CaF2 composite coating onγ-TiAl intermetallic alloyprepared by Nd:YAG laser cladding[J].Applied Surface Science,2009,255:5662-5668.
- [8]章小峰,王爱华.激光熔覆Ni基纳米Ni包h-BN/CaF2涂层组织性能[J].华中科技大学学报:自然科学版,2009,37(1):9-13.ZHANG Xiao-feng,WANG Ai-hua.Microstructure and properties of laser cladding nano-Ni-encapsulated h-BN/CaF2 composite coating[J].JHuazhong Univ of Sci&Tech:Natural Science Edition,2009,37(1):9-13.
- [9]李溪滨,刘如铁,龚雪龙.添加Ni包覆MoS2的Ni-Cr高温固体自润滑材料的研究[J].稀有金属材料与工程,2003,32(10):783-786.LI Xi-bin,LIU Ru-tie,GONG Xue-long.Study of Ni-Cr high temperature solid self-lubricating materials added with Ni coated MoS2 powder[J].RareMetal Materials and Engineering,2003,32(10):783-786.
- [10]黄传兵,杜令忠,张伟刚.NiCr/Cr3C2-BaF2.CaF2高温自润滑耐磨涂层的制备与摩擦磨损性能[J].摩擦学学报,2009,29(1):68-74.HUANG Chuan-bing,DU Ling-zhong,ZHANG Wei-gang.Preparation and tribological properties of NiCr/Cr3C2-BaF2.CaF2 high temperature self-lubricating wear-resistant coating[J].Tribology,2009,29(1):68-74.
- [11]常国威,王建中.金属凝固过程中的晶体生长与控制[M].北京:冶金工业出版社,2002.
- [12]毛卫民.金属材料成形与加工[M].北京:清华大学出版社,2008.
- [13]HE Xiang-Ming,LIU Xiu-Bo.Elevated temperature dry sliding wear behavior of nickel-based composite coating on austenitic stainless steel depositedby a novel central hollow laser cladding[J].Applied Surface Science,2011,258:535-541.
- [14]Liu Y,Wang H M.Elevated temperature wear behaviors of Co-Mo-Si ternary metal silicide alloy[J].Scripta Materialia,2005,52:1235-1240.
- [15]HUANG Kai-jin,YAN Li,WANG Cun-shan.Wear and corrosion properties of laser cladded Cu47Ti43Zr18Ni8/SiC amorphous composite coatings onAZ91D magnesium alloy[J].The Chinese Journal of Nonferrous Metals,2010,20(7):1351-1355.
- [16]Wang A H,Zhang X L,Zhang X F.Ni-based alloy/submicron WS2 self-lubricating composite coating synthesized by ND:YAG laser cladding[J].Materials Science and Engineering,2008,475:312-318.
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