热处理对Hf-基非晶合金力学性能的影响Effect of heat treatment on mechanical properties of Hf-based amorphous alloy
王燕涛,姜凤贤,王燕坡,战再吉,王文魁
摘要(Abstract):
采用铜模浇铸法制备Hf44.5Cu27Ni13.5Ti5Al10块体非晶合金,并对其进行等温退火处理。利用X射线衍射仪(XRD)和透射电镜(TEM)对非晶合金的晶化行为进行了分析,并通过MTS810实验机及场发射扫描电子显微镜(FESEM)研究了等温退火对合金力学性能的影响。结果表明,该非晶合金等温退火相转变进程为:非晶→非晶+Al16 Hf6Ni7→非晶+Al16 Hf6Ni7+CuTi2→CuHf2+CuTi2。合金断裂强度随退火温度的升高先增大后减小。743 K等温退火后,合金断裂强度达到最大值2400 MPa,弹性应变为3.0%。在Hf44.5Cu27Ni13.5Ti5Al10块体非晶合金压缩断口上观察到纳米级韧窝及周期性条纹结构。随着退火温度的升高,周期性条纹间距逐渐减小直至消失,断口形貌呈现为脆性解理断裂的河流状花样。
关键词(KeyWords): Hf-基非晶合金;等温退火;周期性条纹;力学性能
基金项目(Foundation): 国家重点基础研究发展计划(2010CB731600)
作者(Author): 王燕涛,姜凤贤,王燕坡,战再吉,王文魁
DOI: 10.13289/j.issn.1009-6264.2011.10.006
参考文献(References):
- [1]Inoue A,Shen B L,Koshiba H,et al.Cobalt-based bulk glassy alloy with ultrahigh strength and soft magnetic properties[J].Nature Mater,2003,2:661-663.
- [2]Morrison M L,Buchanan R A,Peker A,et al.Cyclic-anodic-polarization studies of a Zr41.2 Ti13.8 Ni10 Cu12.5 Be22.5 bulk metallic glass[J].Intermetallics,2004,12:1177-1181.
- [3]Conner R D,Dandiliker R B,Scruggs V,et al.Dynamic deformation behavior of tungsten-fiber/metallic-glass matrix composites[J].InternationalJournal of Impact Engineering,2000,24(5):435-44.
- [4]Kecskes L J,Edwards B T,et al.Hf-based bulk metallic glasses for kinetic energy penetrators[C]//24th Army Science Conference.Orlando,FL,2004.
- [5]Li C,Saida J,Matsuhita M,et al.Precipitation of an icosahedral quasicrystalline phase in Hf59 Ni8Cu20 Al10 Ti3 metallic glass[J].PhilosophicalMagazine Letters,2000,80(9):621-626.
- [6]Wang L,Li C,Inoue A.Formation of a single icosahedral quasicrystaline phase in Hf60 Ni15 Cu10 Ti15 metallic glass[J].Journal of Alloys andCompounds,2001,325:L7-L10.
- [7]Zhang L,Ma E,Xu Jian.Hf-based bulk metallic glasses with critical diameter on centimeter scale[J].Intermetallics,2008,16(4):584-586.
- [8]Zhang L,Shi L L,Xu Jian.Hf-Cu-Ni-Al bulk metallic glasses:Optimization of glass-forming ability and plasticity[J].Journal of Non-crystallineSolids,2009,355:1005-1007.
- [9]He G,Eckert J,Loser W,et al.Composition dependence of the microstructure and mechanical properties of nano/ultrafine-structured Ti-Cu-Ni-Sn-NbAlloys[J].Acta Materialia,2004,52(10):3035-3046.
- [10]邱胜宝,姚可夫,龚攀.晶化分数对Zr基块体非晶基复相材料力学性能的影响[J].中国科学,2010,40(6):711-716.QIU S B,YAO K F,GONG P.Effect of crystallization fraction on mechanical properties of Zr-based bulk metallic glasses composite materials[J].Science China,2010,40(6):711-716.
- [11]Jiang W H,Pinkerton F E,Atzmon M.Mechanical behavior of shear bands and the effect of their relaxation in a rolled amorphous Al-based alloy[J].Acta Materialia,2005,53(12):3469-3477
- [12]Xi X K,Zhao D Q,Pan M X,et al.Periodic corrugation on dynamic fracture surface in brittle bulk metallic glass[J].Applied Physics Letters,2006,89:181911.
- [13]Liang W Z,Mao X Y,Wu L Z,et al.Nanoscale ripples on the compressive fracture surface of a bulk metallic glass with microscale crystals[J].J MaterSci,2009,44:2016-2020.
- [14]Shen J,Liang W Z,Sun J F.Formation of nanowaves in compressive fracture of a less-brittle bulk metallic glass[J].Applied Physics Letters,2006,89:121908.
- [15]Nguyen H T,Robert N L.Observation of nanometer waves along fracture surface[J].Chemical Physics Letters,2004,391:385-388.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||