Ag对Al-5.3Cu-0.8Mg合金铸态组织与时效硬化行为的影响Effects of Ag on age-hardening behavior and as-cast structure of Al-5.3Cu-0.8Mg alloy
屈华,刘伟东,刘海平
摘要(Abstract):
采用金相显微分析技术、布氏硬度、XRD分析、室温与高温拉伸性能测试等方法,研究了Ag对Al-5.3Cu-0.8Mg合金铸态组织与时效硬化行为的影响。研究表明:Ag对合金铸态组织有细化作用,随着Ag含量的增加,枝晶得到细化;Ag添加缩短了合金的峰时效时间,其原因在于Ag原子提高了合金析出相的形核速率,进而加速了析出相的形成;随着Ag含量的增加,合金的硬度先增加后降低,含0.8%Ag的合金峰时效硬度最大;适量的Ag可以促进合金中Ω相的形成,过量的Ag将会抑制Ω相的形成;随着Ag含量的增加,合金的强度和热稳定性先升高后降低,当Ag含量为0.8%时,其强度和热稳定性均达到峰值;Ag提高合金强度与热稳定性的原因在于析出了热稳定性和强化作用比θ'、S'相更强的Ω相。
关键词(KeyWords): Al-Cu-Mg-Ag合金;Ag添加;铸态组织;时效硬化;热稳定性
基金项目(Foundation): 辽宁省教育厅科学研究项目(L2015234)
作者(Author): 屈华,刘伟东,刘海平
DOI: 10.13289/j.issn.1009-6264.2015.12.012
参考文献(References):
- [1]刘志义,李云涛,刘延斌,等.Al-Cu-Mg-Ag合金析出相的研究进展[J].中国有色金属学报,2007,17(12):1905-1915.LIU Zhi-yi,LI Yun-tao,LIU Yan-bin,et al.Development of Al-Cu-Mg-Ag alloys[J].The Chinese Journal of Nonferrous Metals,2007,17(12):1905-1915.
- [2]Cordovilla C G,Louis E.Characterization of the microstructure of a commerical Al-Cu alloy(2011)by differential scanning calorimetry(DSC)[J].J Material Science,1984,19:279-290.
- [3]Mondolfo L F.Aluminum alloys:Structure and Properties[M].London:Butterwordths,1976:497-504.
- [4]Iau J,Kulak M.A new paradigm in the design of aluminium alloys for aerospace applications[J].Materials Science Forum,2000,331/337:127-140.
- [5]肖代红,王健农,陈世朴,等.微量Ag对Al-5.3Cu-0.8Mg合金组织和耐热性能的影响[J].机械工程材料,2003,27(1):38-40.XIAO Dai-hong,WANG Jian-nong,CHEN Shi-pu,et al.Effect of small amount of Ag on the microstructure and mechanical properties of an Al-5.3Cu-0.8Mg alloy[J].Materials for Mechanical Engineering,2003,27(1):38-40.
- [6]雷文平,沈健,毛柏平.A1-5.2Cu-0.4Mg-1.02Ag合金的时效析出行为研究[J].金属学报,2009,45(5):579-584.LEI Wen-ping,SHEN Jian,MAO Bai-ping.Study on aging precipation behavior of A1-5.2Cu-0.4Mg-1.02Ag alloy[J].Acta Metallurgica Sinica,2009,45(5):579-584.
- [7]宋艳芳,潘清林,曹素芳,等.Ag含量对Al-Cu-Mg合金组织与性能的影响[J].航空材料学报,2013,33(1):8-14.SONG Yan-fang,PAN Qing-lin,CAO Su-fang,et al.Effects of Ag content on microstructure and mechanical properties of Al-Cu-Mg-Ag alloy[J].Journal of Aeronautical Materials,2007,17(12):1905-1915.
- [8]Lumley R N,Polmear I J.The effect of long term creep exposure on the microstructure and properties of an underaged Al-Cu-Mg-Ag alloy[J].Scripta Materialia,2004,50(9):1227-1231.
- [9]Ringer S P,Yeung W,Muddle B C,et al.Precipitate stability in Al-Cu-Mg-Ag alloys aged at high temperature[J].Acta Metallurgica et Materialia,1994,42(5):1715-1725.
- [10]Muddle B C,Polmear I J.The precipitation phase in an Al-Cu-Mg-Ag alloys[J].Acta Metallurgica et Materialia,1989,37(3):777-789.
- [11]Chang Y C,Howe J M.Composition and stability of phase in an Al-Cu-Mg-Ag alloy[J].Metallurgical Transactions,1993,A24:1461-1470.
- [12]蔡金伶,易丹青,王宏伟,等.Ag对Al-Cu-Mg合金Ω相析出行为的影响[J].中国有色金属学报,2011,21(7):1504-1512.CAI Jin-ling,YI Dan-qing,WANG Hong-wei,et al.Effect of Ag on precipitation behavior ofΩphase in Al-Cu-Mg alloy[J].The Chinese Journal of Nonferrous Metals,2011,21(7):1504-1512.
- [13]刘伟东,屈华.Al-Cu-Mg-Ag合金析出相价电子结构与竞争析出的关系[J].稀有金属材料与工程,2013,42(S2):574-577LIU Wei-dong,QU Hua.Relationship between the valence electron structures and the competition precipitation of Al-Cu-Mg-Ag alloys[J].Rare Metal Materials and Engineering,2013,42(S2):574-577.
- [14]申晓璐.Al-Cu-Mg-(Ag)合金时效析出行为的EET理论研究[D].锦州:辽宁工业大学,2009.
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