不同Ti含量Cu-Cr-Ti合金的析出动力学Precipitation kinetics of Cu-Cr-Ti alloys with different Ti contents
刘健,龚清华,吴凡,陈辉明,谢伟滨,汪航,杨斌
摘要(Abstract):
采用真空熔炼方法制备了Cu-0.42Cr、Cu-0.50Cr-0.06Ti和Cu-0.52Cr-0.40Ti合金,并对合金进行了“热轧—固溶—时效”处理。研究了在450、550和650℃下时效不同时间对不同Ti含量的Cu-Cr-Ti合金导电率的影响,并分析了合金在时效过程中析出相的析出动力学。结果表明:Cu-0.42Cr合金导电率在时效2 h后趋于平稳,加入Ti元素后,合金则在时效8 h后导电率趋于平稳,表明析出相在此时已完全析出;Ti元素对合金导电率的影响较大,在450℃时效8 h后,Cu-0.42Cr合金的导电率为97%IACS,而Cu-0.50Cr-0.06Ti和Cu-0.52Cr-0.40Ti合金分别为80.2%IACS和34.1%IACS。根据马基申-富列明格规律和Avrami经验方程计算得到Cu-0.42Cr、Cu-0.50Cr-0.06Ti和Cu-0.52Cr-0.40Ti合金在不同时效温度的析出动力学方程和导电率方程,并通过透射电镜(TEM)统计在完全析出时的析出相体积分数,与通过析出动力学方程计算出的析出相体积分数进行了对比,计算值与统计值相符合。
关键词(KeyWords): Cu-Cr-Ti合金;时效处理;导电率;析出动力学
基金项目(Foundation): 江西省青年井冈学者计划;; 江西省科技创新高端人才(青年)项目;; 江西理工大学高层次人才科研启动项目
作者(Author): 刘健,龚清华,吴凡,陈辉明,谢伟滨,汪航,杨斌
DOI: 10.13289/j.issn.1009-6264.2023-0156
参考文献(References):
- [1] Juan H S,Qi M D,Ping L,et al.Research on aging precipitation in a Cu-Cr-Zr-Mg alloy[J].Materials Science and Engineering A,2005,392:422-426.
- [2] Zhang S,Li R,Kang H,et al.A high strength and high electrical conductivity Cu-Cr-Zr alloy fabricated by cryorolling and intermediate aging treatment[J].Materials Science and Engineering A,2016,680(5):108-114.
- [3] Zhang Y,Volinsky A A,Hai T T,et al.Aging behavior and precipitates analysis of the Cu-Cr-Zr-Ce alloy[J].Materials Science and Engineering A,2016,650:248-253.
- [4] Dobatkin S V,Gubicza J,Shangina D V,et al.High strength and good electrical conductivity in Cu-Cr alloys processed by severe plastic deformation[J].Materials Letters,2015,153:5-9.
- [5] Zhang Y,Volinsky A A,Hai T T,et al.Effects of Ce addition on high temperature deformation behavior of Cu-Cr-Zr alloys[J].Journal of Materials Engineering & Performance,2015,24(10):1-6.
- [6] Islamgaliev R K,Nesterov K M,Bourgon J,et al.Nanostructured Cu-Cr alloy with high strength and electrical conductivity[J].Journal of Applied Physics,2014,115(19):194301.
- [7] Liu Q,Zhang X,Ge Y,et al.Effect of processing and heat treatment on behavior of Cu-Cr-Zr alloys to railway contract wire[J].Metallurgical and Materials Transactions A,2006,37(11):3233-3238.
- [8] 袁大伟,龚留奎,陈辉明,等.Cu-Cr-Ag合金的组织与性能[J].金属热处理,2018,43(2):127-133.YUAN Da-wei,GONG Liu-kui,CHEN Hui-ming,et al.Microstructures and properties of Cu-Cr-Ag alloy[J].Heat Treatment of Metals,2018,43(2):127-133.
- [9] Mao Q Z,Wang L,Nie J F,et al.Enhancing strength and electrical conductivity of Cu-Cr composite wire by two-stage rotary swaging and aging treatments[J].Composites Part B:Engineering,2022,231:109567.
- [10] 王松,刘满门,陈永泰,等.合金化元素Zr、Y、Mo对Cu-Cr合金组织与性能的影响[J].电工材料,2013(4):3-6.WANG Song,LIU Man-men,CHEN Yong-tai,et al.Effects of alloying elements Zr,Y and Mo on microstructure and properties of Cu-Cr alloy[J].Electric Engineering Materials,2013(4):3-6.
- [11] Peng H C,Xie W B,Chen H M,et al.Effect of micro-alloying element Ti on mechanical properties of Cu-Cr alloy[J].Journal of Alloys and Compounds,2021,852(1):157004.
- [12] Kuang G,Miao K S,Li X W,et al.In-situ observation of microstructure and orientation evolution of the Cu-Cr-Zr-Hf alloys[J].Materials Science and Engineering A,2023,865:144642.
- [13] Gong Q H,Liu J,Wu,F,et al.Precipitation behavior and strengthening effects of the Cu-0.42Cr-0.16Co alloy during aging treatment[J].Journal of Alloys and Compounds,2023,936:168269.
- [14] Sun X L,Jie J C,Wang P F,et al.Effects of Co and Si additions and cryogenic rolling on structure and properties of Cu-Cr alloys[J].Materials Science and Engineering A,2019,740:165-173.
- [15] Guo X L,Zhu X,Qiu W T,et al.Microstructure and properties of Cu-Cr-Nb alloy with high strength,high electrical conductivity and good softening resistance performance at elevated temperature[J].Materials Science and Engineering A,2019,749:281-290.
- [16] 袁继慧.Cu-Cr-Ti-Si 合金加工软化行为研究[D].赣州:江西理工大学,2020.YUAN Ji-hui.Study on work softening behavior of Cu-Cr-Ti-Si alloy[D].Ganzhou:Jiangxi University of Science and Technology,2020.
- [17] 李勇,李焕,赵亚茹,等.Cu-0.3Cr-0.05Ti 合金时效析出动力学[J].材料热处理学报,2016,37(5):226-230.LI Yong,LI Huan,ZHAO Ya-ru,et al.Kinetics of precipitation in Cu-0.3Cr-0.5Ti alloy[J].Transactions of Materials and Heat Treatment,2016,37(5):226-230.
- [18] Wang H,Gong L K,Liao J F,et al.Retaining meta-stable fcc-Cr phase by restraining nucleation of equilibrium bcc-Cr phase in CuCrZrTi alloys during ageing[J].Journal of Alloys and Compounds,2018,749:140-145.
- [19] 郑碰菊,李勇,张建波,等.Cu-0.33Cr-0.05Ti合金时效相变动力学[J].材料研究与应用,2015,9(2):91-95.ZHENG Peng-ju,LI Yong,ZHANG Jian-bo,et al.Kinetics of phase transformation of aged Cu-0.33Cr-0.5Ti alloy[J].Materials Research and Application,2015,9(2):91-95.
- [20] Xu K,Liu J D,Xu W,et al.Numerical simulation of precipitation kinetics in multicomponent alloys[J].Journal of Materials Science & Technology,2022,128:98-106.
- [21] Liu J,Gong Q H.Strengthening caused by precipitates with different morphologies in Cu-Cr-Ti alloys:The role of dislocation bending angle[J].Materials Science and Engineering A,2022,840:142927.
- [22] 柳瑞清,谢伟滨,黄国杰,等.Cu-3.0Ni-0.75Si合金时效析出动力学分析[J].材料科学与工艺,2015,23(3):124-128.LIU Rui-qing,XIE Wei-bin,HUANG Guo-jie,et al.Study on dynamics of aging precipitation of Cu-3.0Ni-0.75Si alloy[J].Materials Science and Technology,2015,23(3):124-128.
- [23] 李勇,易丹青.Cu-0.1Ag-0.1Fe合金的相变动力学[J].材料热处理学报,2010,31(5):49-52.LI Yong,YI Dan-qing.Dynamics of phase transformation in Cu-Fe-Ag alloy[J].Transactions of Materials and Heat Treatment,2010,31(5):49-52.
- [24] 张彦敏,王海艳,罗钧,等.直流电流下Cu-0.33Cr-0.06Zr合金的时效动力学[J].特种铸造及有色合金,2014,34(11):1123-1126.ZHANG Yan-min,WANG Hai-yan,LUO Jun,et al.Aging kinetics of Cu-0.33Cr-0.06Zr alloy under DC (Direct current)[J].Special Casting & Nonferrous Alloys,2014,34(11):1123-1126.
- [25] 温盛发,周海涛,刘克明,等.Cu-1.0Cr-0.2Zr合金的时效析出研究[J].热加工工艺,2010,39(12):113-116.WEN Sheng-fa,ZHOU Hai-tao,LIU Ke-ming,et al.Study on microstructure and properties of aging Cu-1.0Cr-0.2Zr alloy[J].Hot Working Technology,2010,39(12):113-116.
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