周妍,王松林,张然

• 1:铜陵学院机械工程学院
• 2:铜陵学院信息管理与系统工程研究所

摘要(Abstract)：

采用NH4F-DMSO-甘油-H2O溶液体系的电化学阳极氧化法,经高温热处理后,在金属钛基板上制备了有序的Ti O2纳米管阵列薄膜。通过计时安培法、循环伏安曲线、光照开路电位谱和瞬态光电流谱技术对纳米管阵列电极的电致变色及光电化学特性进行了研究。结果表明,Ti O2纳米管为混晶组成,阵列薄膜具有大比表面积和高长径比。纳米管阵列电极具有稳定的阴极电致变色效应,快速的着色/褪色反应时间。与Ti O2纳米多孔膜电极相比,Ti O2纳米管阵列电极的光电流及光照开路电压都显著增加。

关键词(KeyWords)： Ti O2;纳米管阵列;阳极氧化;电致变色;光电化学

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(21171131);; 安徽省教育厅高校自然科学研究项目(KJ2010B233,KJ2010B234)

作者(Author): 周妍,王松林,张然

DOI: 10.13289/j.issn.1009-6264.2015.04.001

参考文献(References)：

• [1]Mor G K,Shankar K,Paulose M,et al.Use of highly-ordered Ti O2nanotube arrays in dye-sensitized solar cells[J].Nano Letters,2006,6(2):215-218.
• [2]Berger S,Ghicov A,Nah Y,et al.Transparent Ti O2nanotube electrodes via thin layer anodization:fabrication and use in electrochromic devices[J].Langmuir,2009,25(9):4841-4844.
• [3]Chen X,Mao S S.Titanium dioxide nanomaterials:synthesis,properties,modifications and applications[J].Chemical Reviews,2007,107(7):2891-2959.
• [4]Mohamed A,Rohani S.Modified Ti O2nanotube arrays(TNTAs):progressive strategies towards visible light responsive photoanode,a review[J].Energy Environmental Science,2011(4):1065-1086.
• [5]Yan J F,Zhou F.Ti O2nanotubes:Structure optimization for solar cells[J],Journal of Materials Chemistry,2011,21(26):9406-9418.
• [6]Zhang H,Quan X,Chen S,et al.“Mulberry-like”Cd Se nanoclusters anchored on Ti O2nanotube arrays:a novel architecture with remarkable photoelectrochemical performance[J].Chemistry of Materials,2009,21(14):3090-3095.
• [7]Wang D,Hu T C,Hu L T,et al.Micro-structured Ti O2nanotube arrays for improved photoelectrocatalysis and mechanical stability[J].Advanced Functional Materials,2009,19(12):1930-1938.
• [8]Wang D,Liu Y,Yu B,et al.Ti O2nanotubes with tunable morphology,diameter and length:synthesis and photoelectrocatalytic performance[J].Chemistry of Materials,2009,21(7):1198-1206.
• [9]Wolcott A,Smith W A,Kuykendall T R,et al.Photoelectrochemical water splitting using dense and aligned Ti O2nanorod arrays[J].Small,2009(5):104-111.
• [10]Gong D,Grimes C A,Varghese O K,et al.Titanium oxide nanotube arrays prepared by anodic oxidation[J].Journal of Materials Research,2001,16(12):3331-3334.
• [11]Sreekantan S,Lockman Z,Hazan R,et al.Influence of electrolyte p H on Ti O2nanotube formation by Ti anodization[J].Journal of Alloys and Compounds,2009,485(1):478-483.
• [12]Lockman Z,Sreekantan S,Ismail S,et al.Influence of anodisation voltage on the dimension of titania nanotubes[J].Journal of Alloys and Compounds,2010,503(2):359-364.
• [13]Macak J M,Tsuchiya H,Schmuki P.High-aspect-ratio Ti O2nanotubes by anodization of titanium[J].Angewandte Chemie International Edition,2005,44(14):2100-2102.
• [14]Cai Q,Paulose M,Varghese O K,et al.The effect of electrolyte composition on the fabrication of self-organized titanium oxide nanotube arrays by anodic oxidation[J].Journal of Materials Research,2005,20(1):230-236.
• [15]Wang J,Lin Z Q.Freestanding Ti O2nanotube arrays with ultrahigh aspect ratio via electrochemical anodization[J].Chemistry of Materials,2008,20(4):1257-1261.
• [16]Yoriya S,Grimes C A.Self-assembled anodic Ti O2nanotube arrays:electrolyte properties and their effect on resulting morphologies[J].Journal of Materials Chemistry,2011,21(1):102-108.
• [17]Song Y Y,Gao Z D,Wang J H,et al.Multistage colouring electrochromic device based on Ti O2nanotube arrays modified with WO3nanoparticles[J].Advanced Functional Materials,2011,21(10):1941-1946.
• [18]Shankar K,Mor G K,Grimes C A,et al.Highly-ordered Ti O2nanotube arrays up to 220μm in length:Use in water photoelectrolysis and dyesensitized solar cells[J].Nanotechnology,2007(18):065707-065718.
• [19]Varghese O K,Paulose M,Grimes C A.Long vertically aligned titania nanotubes on transparent conducting oxide for highly efficient solar cells[J].Nature Nanotechnology,2009(4):592-597.
• [20]Macak J M,Tsuchiya H,Schmuki P.Smooth anodic Ti O2nanotubes[J].Angewandte Chemie International Edition,2005,44(45):7463-7465.
• [21]Ghicov A,Albu S,Hahn R,et al.Ti O2nanotubes in dye-sensitized solar cells:critical factors for the conversion efficiency[J].Chemistry-An Asian Journal,2009,4(4):520-525.
• [22]Aldabergenova S B,Ghicov A,Albu S,et al.Smooth titania nanotubes:self-organization and stabilization of anatase phase[J].Journal of NonCrystalline Solids,2008,354(19):2190-2194.
• [23]Li D,Haneda H,Hishita S,et al.N-F-codoped Ti O2photocatalysts synthesis by spray pyrolysis and surface characterization[J].Chemistry of Materials,2005,17(10),2588-2595.
• [24]Ohashi N,Hishita S,Kolodiazhnyi T,et al.Origin of visible-light-driven photocatalysis:a comparative study on N/F-doped and N-F-codoped Ti O2powders by means of experimental characterizations and theoretical calculations[J].Journal of Non-Crystalline Solids,2005,178(11):3293-3302.
• [25]Yu J G,Yu J,Ho W K,et al.Effects of F-doping on the photocatalytic activity and microstructures of nanocrystalline Ti O2powers[J].Chemistry of Materials,2002,14(9):3808-3816.
• [26]Lindstroem H,Soedergren S,Solbrand A,et al.Li+ion insertion in Ti O2(anatase).2.Voltammetry on nanoporous films[J].Journal of Chemical Physics B,1997,101(39):7717-7722.
• [27]Hu H,Xiao W J,Yuan J,et al.Preparations of Ti O2film coated on foam nickel substrate by sol-gel processes and its photocatalytic activity for degradation of acetaldehyde[J].Journal of Environmental Sciences,2007,19(1):80-85.

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