田伟,胡梦楠,孙玥,毕莉明

• 1:上海理工大学理学院
• 2:上海理工大学科技处

摘要(Abstract)：

随着汽车轻量化、高容量化、低成本化的趋势,作为外壳材料的铝合金的性能研究成为了近年的热点,而稀土元素的化学活性很强,将其加入到合金中会起到净化熔体、细化晶粒、微合金化等积极作用。本文综述了国内外关于稀土在铝铜合金中的应用研究现状,通过对稀土在铝铜合金中的作用机理的阐述,从晶粒大小、析出物、相结构等多个方面,讨论了稀土对铝铜合金的显微组织、力学性能和耐腐蚀性能等方面产生的影响,提出了稀土在铝铜合金发展中需要注意的问题,为将稀土加入到2XXX系合金并改善综合性能的研究提供了参考。

关键词(KeyWords)： 稀土;铝合金;研究进展;力学性能

Abstract:

Keywords:

基金项目(Foundation): 国家重点实验室项目(2018GZKF03007);; 国家自然科学基金(10874118)

作者(Author): 田伟,胡梦楠,孙玥,毕莉明

DOI: 10.13289/j.issn.1009-6264.2018-0455

参考文献(References)：

• [1] Miller W S,Zhuang L,Bottema J,et al.Recent development in aluminium alloys for the automotive industry[J].Materials Science and Engineering A,2000,280(1):37-49.
• [2] Patil A,Patil V,Shin D W,et al.Issue and challenges facing rechargeable thin film lithium batteries[J].Materials Research Bulletin,2008,43(8/9):1913-1942.
• [3] 内田秀俊,长井康礼,伊藤智康.电池外壳用铝合金板及其制造方法:中国CN101358307A[P].2009-02-04.
• [4] Buller S,Thele M,De Doncker R W A A,et al.Impedance-based simulation models of supercapacitors and Li-ion batteries for power electronic applications[J].IEEE Transactions on Industry Applications,2005,41(3):742-747.
• [5] Burke A,Miller M.The power capability of ultracapacitors and lithium batteries for electric and hybrid vehicle applications[J].Journal of Power Sources,2011,196(1):514-522.
• [6] Wang S C,Starink M J,Gao N.Precipitation hardening in Al-Cu-Mg alloys revisited[J].Scripta Materialia,2006,54(2):287-291.
• [7] Zuiko I S,Gazizov M R,Kaibyshev R O.Effect of thermomechanical treatment on the microstructure,phase composition,and mechanical properties of Al-Cu-Mn-Mg-Zr alloy[J].The Physics of Metals and Metallography,2016,117(9):906-919.
• [8] Yin Z,Pan Q,Zhang Y,et al.Effect of minor Sc and Zr on the microstructure and mechanical properties of Al-Mg based alloys[J].Materials Science and Engineering A,2000,280(1):151-155.
• [9] Norman A F,Prangnell P B,McEwen R S.The solidification behaviour of dilute aluminium-scandium alloys[J].Acta Materialia,1998,46(16):5715-5732.
• [10] Mishra A K,Balasubramaniam R.Corrosion inhibition of aluminum alloy AA 2014 by rare earth chlorides[J].Corrosion Science,2007,49(3):1027-1044.
• [11] Nogita K,McDonald S D,Dahle A K.Eutectic modification of Al-Si alloys with rare earth metals[J].Materials Transactions,2004,45(2):323-326.
• [12] Chaubey A K,Mohapatra S,Jayasankar K,et al.Effect of cerium addition on microstructure and mechanical properties of Al-Zn-Mg-Cu alloy[J].Transactions of the Indian Institute of Metals,2009,62(6):539-543.
• [13] Wang W,Zhang X,Gao Z,et al.Influences of Ce addition on the microstructures and mechanical properties of 2519A aluminum alloy plate[J].Journal of alloys and Compounds,2010,491(1/2):366-371.
• [14] Ao X,Xing S,Yu B,et al.Effect of Ce addition on microstructures and mechanical properties of A380 aluminum alloy prepared by squeeze-casting[J].International Journal of Minerals,Metallurgy,and Materials,2018,25(5):553-564.
• [15] Xiao D H,Wang J N,Ding D Y,et al.Effect of rare earth Ce addition on the microstructure and mechanical properties of an Al-Cu-Mg-Ag alloy[J].Journal of Alloys and Compounds,2003,352(1/2):84-88.
• [16] Sawtell R R,Jensen C L.Mechanical properties and microstructures of Al-Mg-Sc alloys[J].Metallurgical Transactions A,1990,21(1):421-430.
• [17] Filatov Y A,Yelagin V I,Zakharov V V.New Al-Mg-Sc alloys[J].Materials Science and Engineering A,2000,280(1):97-101.
• [18] Jones M J,Humphreys F J.Interaction of recrystallization and precipitation:the effect of Al3Sc on the recrystallization behaviour of deformed aluminium[J].Acta Materialia,2003,51(8):2149-2159.
• [19] Davydov V G,Rostova T D,Zakharov V V,et al.Scientific principles of making an alloying addition of scandium to aluminium alloys[J].Materials Science and Engineering A,2000,280(1):30-36.
• [20] Marquis E A,Seidman D N.Nanoscale structural evolution of Al3Sc precipitates in Al3 (Sc) alloys[J].Acta Materialia,2001,49(11):1909-1919.
• [21] Fuller C B,Seidman D N.Temporal evolution of the nanostructure of Al3(Sc,Zr) alloys:Part II-coarsening of Al3(Sc1-xZrx) precipitates[J].Acta Materialia,2005,53(20):5415-5428.
• [22] Knipling K E,Karnesky R A,Lee C P,et al.Precipitation evolution in Al-0.1 Sc,Al-0.1 Zr and Al-0.1 Sc-0.1 Zr (at%) alloys during isochronal aging[J].Acta Materialia,2010,58(15):5184-5195.
• [23] Norman A F,Hyde K,Costello F,et al.Examination of the effect of Sc on 2000 and 7000 series aluminium alloy castings:for improvements in fusion welding[J].Materials Science and Engineering A,2003,354(1/2):188-198.
• [24] Starink M J,Gao N,Kamp N,et al.Relations between microstructure,precipitation,age-formability and damage tolerance of Al-Cu-Mg-Li (Mn,Zr,Sc) alloys for age forming[J].Materials Science and Engineering A,2006,418(1/2):241-249.
• [25] Colombo M,Gariboldi E,Morri A.Er addition to Al-Si-Mg-based casting alloy:Effects on microstructure,room and high temperature mechanical properties[J].Journal of Alloys and Compounds,2017,708:1234-1244.
• [26] 杨军军,聂祚仁,金头男,等.稀土元素铒对 Al-4Cu 合金组织与性能的影响[J].中国稀土学报,2002(z2):159-162.YANG Jun-jun,NIE Zuo-ren,JIN Tou-nan,et al.Effects of rare earth element Er on structure and properties of Al-4Cu alloy[J].Journal of the Chinese Rare Earth Society,2002(z2):159-162.
• [27] 李云涛,刘志义,夏卿坤,等.稀土铒对Al-Cu-Mg-Ag-Zr合金微观组织与时效行为的影响[J].材料热处理学报,2007,28(2):49-53.LI Yun-tao,LIU Zhi-yi,XIA Qing-kun,et al.Effect of trace addition of Er on microstructure and ageing behavior of Al-Cu-Mg-Ag-Zr alloy[J].Transactions of Materials and Heat Treatment,2007,28(2):49-53.
• [28] Shivkumar S,Wang L,Apelian D.Molten metal processing of advanced cast aluminum alloys[J].JOM,1991,43(1):26-32.
• [29] Lumley R N,Morton A J,Polmear I J.Enhanced creep performance in an Al-Cu-Mg-Ag alloy through underageing[J].Acta Materialia,2002,50(14):3597-3608.
• [30] Lathabai S,Lloyd P G.The effect of scandium on the microstructure,mechanical properties and weldability of a cast Al-Mg alloy[J].Acta Materialia,2002,50(17):4275-4292.
• [31] Xiao D H,Huang B.Effect of Yb addition on precipitation and microstructure of Al-Cu-Mg-Ag alloys[J].Transactions of Nonferrous Metals Society of China,2007,17(6):1181-1185.
• [32] 张新明,王文韬,刘波,等.Nd对2519铝合金组织与耐热性能的影响[J].中国有色金属学报,2009,19(1):15-20.ZHANG Xin-ming,WANG Wen-tao,LIU Bo,et al.Effect of Nd addition on microstructures and heat resisting properties of 2519 aluminum alloy[J].The Chinese Journal of Nonferrous Metals,2009,19(1):15-20.
• [33] Gazizov M,Teleshov V,Zakharov V,et al.Solidification behaviour and the effects of homogenisation on the structure of an Al-Cu-Mg-Ag-Sc alloy[J].Journal of Alloys and Compounds,2011,509(39):9497-9507.
• [34] 张娜,李杨.锂离子动力电池铝外壳的腐蚀[J].腐蚀与防护,2015,36(4):351-365.ZHANG Na,LI Yang.Corrosion of aluminum casing of lithium-ion power battery[J].Corrosion and Protection,2015,36(4):351-365.
• [35] Gupta R K,Deschamps A,Cavanaugh M K,et al.Relating the early evolution of microstructure with the electrochemical response and mechanical performance of a Cu-rich and Cu-lean 7xxx aluminum alloy[J].Journal of the Electrochemical Society,2012,159(11):492-502.
• [36] Ringer S P,Hono K.Microstructural evolution and age hardening in aluminium alloys:atom probe field-ion microscopy and transmission electron microscopy studies[J].Materials Characterization,2000,44(1/2):101-131.
• [37] Ralston K D,Birbilis N,Cavanaugh M K,et al.Role of nanostructure in pitting of Al-Cu-Mg alloys[J].Electrochimica Acta,2010,55(27):7834-7842.
• [38] Dabalà M,Armelao L,Buchberger A,et al.Cerium-based conversion layers on aluminum alloys[J].Applied Surface Science,2001,172(3/4):312-322.
• [39] 郑玉林,暨波,叶凌英,等.稀土镱对2519A铝合金抗晶间腐蚀性能的影响[J].中南大学学报:自然科学版,2013,44(12):4806-4810.ZHEN Yu-lin,JI Bo,YE Ling-ying,et al.Influence of Yb addiotion on intergranular corrosion resistance of aluminum alloy 2519A[J].Journal of Central South University (Science and Technology),2013,44(12):4806-4810.
• [40] Ho D,Brack N,Scully J,et al.Cerium dibutylphosphate as a corrosion inhibitor for AA2024-T3 aluminum alloys[J].Journal of the Electrochemical Society,2006,153(9):392-401.
• [41] Markley T A,Forsyth M,Hughes A E.Corrosion protection of AA2024-T3 using rare earth diphenyl phosphates[J].Electrochimica Acta,2007,52(12):4024-4031.
• [42] Yasakau K A,Zheludkevich M L,Lamaka S V,et al.Mechanism of corrosion inhibition of AA2024 by rare-earth compounds[J].The Journal of Physical Chemistry B,2006,110(11):5515-5528.
• [43] Catubig R,Hughes A E,Cole I S,et al.The use of cerium and praseodymium mercaptoacetate as thiol-containing inhibitors for AA2024-T3[J].Corrosion Science,2014,81:45-53.
• [44] Hinton B R W,Arnott D R,Ryan N E.Cerium conversion coatings for the corrosion protection of aluminum[C]//Materials Forum.1986,9(3):162-173.
• [45] Hughes A E,Taylor R J,Hinton B R W,et al.XPS and SEM characterization of hydrated cerium oxide conversion coatings[J].Surface and Interface Analysis,1995,23(7/8):540-550.

文章评论(Comment)：