Ti-Si-Al-N纳米复合膜的组织与性能Microstructure and properties of Ti-Si-Al-N nano-composite films
李学梅,尤建飞,董松涛,汪蕾,许俊华
摘要(Abstract):
采用磁控反应溅射法制备了一系列Al含量不同的Ti-Si-Al-N纳米复合薄膜,采用X射线衍射仪、扫描电子显微镜及配套能量色散谱仪研究了Al含量对薄膜组织结构、硬度及高温抗氧化性的影响。结果表明:Ti-Si-Al-N薄膜点阵常数随Al含量的增加呈下降趋势;Al含量增加到6.48at%时出现h-AlN相,此时薄膜具有最高的硬度,约33GPa;薄膜的抗氧化温度提高到约900℃,但Al含量较高易导致薄膜晶粒在高温下长大。
关键词(KeyWords): Ti-Si-Al-N复合膜;显微硬度;高温抗氧化性;磁控反应溅射法
基金项目(Foundation): 国家自然科学基金资助项目(50574044)
作者(Author): 李学梅,尤建飞,董松涛,汪蕾,许俊华
参考文献(References):
- [1]Munz W D.Titanium aluminum nitride films:a new alternative to TiN coatings[J].J Vac Sci Technol A,1986,4(6):2717-2725.
- [2]Oliver W C,Pharr G M.An improved technique for determining hardness and elastic modulus using load and displacement sensing indentat ion experiments[J].J Mater Res,1992,7(6):1564-1583.
- [3]Shum P W,Zhou Z F,Li K Y,et al.Structural and mechanical properties of titanium-aluminium-nitride films deposited by reactive close-field unbalancedmagnetron sputtering[J].Mater Sci Eng B,2003,100(2):199-203.
- [4]Vaz F,Rebouta L,Goudeau P,et al.Characterization of Ti1-xSixNynanocomposite films[J].Surf Coat Technol,2000,133-134:307-313.
- [5]Diserens M,Patscheider J,Levy F.Improving the properties of titanium nitride by incorporation of silicon[J].Surf Coat Technol,1998,108-109:241-246.
- [6]Veprek S.The search for novel,superhard materials[J].J Vac Sci Technol A,1999,17:2401.
- [7]Veprek S,Reiprich S.A concept for the design of novel superhard coatings[J].Thin Solid Films,1995,268(1-2):64-71.
- [8]Ning Jiang,Shen Y G,Zhang H J,et al.Superhard nanocomposite Ti-Al-Si-N films deposited by reactive unbalanced magnetron sputtering[J].MaterialsScience and Engineering B,2006,135(1):1-9.
- [9]Rafaja Poklad A,Klemm V,Schreiber G,et al.Microstructure and hardness of nanocrystalline Ti1-x-yAlxSiyN thin films[J].Materials Science andEngineering A,2007,462(1-2):279-282.
- [10]Vennemann A,Stock H R,Kohlscheen J,et al.Oxidation resistance of titanium-aluminium-silicon nitride coatings[J].Surf Coat Technol,2003,174-175:408-415.
- [11]Jeong Suk Kim,Gyeng Joong Kim,Myung Chang Kang,et al.Cutting performance of Ti-Al-Si-N-coated tool by a hybrid-coating system for high-hardenedmaterials[J].Surf Coat Technol,2005,193(1-3):249-254.
- [12]In-Wook Park,Sung Ryong Choi,et al.Effects of Si addition on the microstructural evolution and hardness of Ti-Al-Si-N films prepared by the hybrid systemof arc ion plating and sputtering techniques[J].J Vac Sci Technol A,2003,21(4):895-899.
- [13]In-Wook Park,Dong Shik Kang,et al.Microstructure,mechanical properties,and tribological behaviors of Cr-Al-N,Cr-Si-N,Cr-Al-Si-N coating by ahybrid coating system[J].Surface&Coatings Technology,2007,201(9-11):5223-5227.
- [14]Carvalho S,Ribeiro E,et al.Microstructure,mechanical properties and cutting performance of superhard(Ti,Si,Al)N nanocomposite films grown by d.c.reactive magnetron sputtering[J].Surf Coat Technol,2004,177-178:459-468.
- [15]农尚斌,喻利花,许俊华.Ti-Si-N复合膜的微结构及性能研究[J].表面技术,2008,37(2):45-49.NONG Sang-bin,YU Li-hua,XU Jun-hua.Microstructure and properties of Ti-Si-N Nano-composites deposited by magnetron sputtering[J].SurfaceTechnology,2008,37(2):45-49.
- [16]Barshilia Harish C,Deepthi B,Rajam K S.Deposition and characterization of TiAlN/Si3N4superhard nanocomposite coatings prepared by reactive directcurrent unbalanced magnetron sputtering[J].Vacuum,2006,81(4):479-488.
- [17]In-Wook Park,Sung Ryong Choi,Ju Hyung Suh,et al.Deposition and mechanical evaluation of superhard Ti-Al-Si-N nanocomposite films by a hybridcoating system[J].Thin Solid Films,2004,447-448:443-448.
- [18]Kim S H,Kim J K,Kim K H.Influence of deposition conditions on the microstructure and mechanical properties of Ti-Si-N films by DC reactive magnetronsputtering[J].Thin Solid Films 2002,420-421:360-365.
- [19]Hall E O.The deformation and ageing of mild steel:Ⅲdiscussion of results[J].Proc Phys Soc Lond Sect B,1951,64(9):747-753.
- [20]Petch N J.The cleavage strength of polycrystals[J].J Iron Steel Inst,1953,174(1):25-28.
- [21]孔明,赵文济,乌晓燕,等.TiN/Si3N4纳米晶复合膜的微结构和强化机制[J].无机材料学报,2007,22(3):033-038.KONG Ming,ZHAO Wen-ji,WU Xiao-yan,et al.Microstructure and mechanical properties of TiN/Si3N4nanocomposite films[J].Journal of InorganicMaterials,2007,22(3):33-38.
- [22]Oliveira I C,Grigorov K G,Maciel H S,et al.High textured AlN thin films grown by RF magnetron sputtering;composition,structure,morphology andhardness[J].Vacuum,2004,75(4):331-338.
- [23]汝强,胡社军,黄拿灿,等.钛合金表面电弧离子镀TiAlN涂层的抗高温氧化性能研究[J].材料保护,2007,40(1):28-31.RU Qiang,HU She-jun,HUANG Na-can,et al.Resistance to high-temperature oxidation of arc ion plated TiAlN coating on heat-resisting titanium alloy[J].Materials Protection,2007,40(1):28-31.
- [24]Vaz F,Rebouta L,Andritschky M,et al.Oxidation resistance of(Ti,Al,Si)N coating in air[J].Sur Coat Technol,1998,98(1-3):912-917.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||