Cr12Mo1V1模具钢碳化物分断细化热处理技术Heat treatment technology of carbide breaking and refining of Cr12Mo1V1 die steel
迟宏宵,刘继浩,殷军伟,周健,马党参
摘要(Abstract):
改善高耐磨型Cr12Mo1V1冷作模具钢中碳化物的形态和颗粒尺寸对提高其力学性能尤为重要。采用光学显微镜(OM)、扫描电镜(SEM)、Image-proplus 6.0分析和激光共聚焦显微镜等研究了Cr12Mo1V1钢在高温加热过程中碳化物的溶解、尺寸及形貌特征变化行为。结果表明:在高温加热过程中,Cr12Mo1V1冷作模具钢的碳化物将发生溶解及形状的改变。随着加热温度升高,大颗粒碳化物含量比例逐渐减少,小颗粒碳化物比例逐渐增多,碳化物产生细化。当加热温度足够高时,大颗粒共晶碳化物的形貌会发生明显变化;在1200℃加热时,大颗粒共晶碳化物分断、碎化成尺寸相对较小的颗粒状,随保温时间增加效果更明显。热力学分析表明:碳化物的溶解和形貌特征变化是表面能降低驱动的自发过程;动力学分析表明:由于碳化物表面不同曲率半径处浓度差的存在,合金元素将由曲率半径较小处(如细颈、尖角处)向曲率半径较大处(如平直界面处)扩散,使碳化物发生断开和球化的自发过程。
关键词(KeyWords): 冷作模具钢;碳化物;碳化物细化;热处理技术
基金项目(Foundation): 国家重点研发计划项目(2020YFB0311000)
作者(Author): 迟宏宵,刘继浩,殷军伟,周健,马党参
DOI: 10.13289/j.issn.1009-6264.2022-0324
参考文献(References):
- [1] 徐进,姜先畲,陈再枝,等.模具钢[M].北京:冶金工业出版社,1998.
- [2] 陈再枝,蓝德年,马党参.模具钢手册[M].北京:冶金工业出版社,2020.
- [3] 陈再良,陈蕴博,佟晓辉,等.典型冷作模具钢性能与失效关系的探讨[J].金属热处理,2006,31(2):87-93.CHEN Zai-liang,CHEN Yun-bo,TONG Xiao-hui,et al.Mechanical properties and failure types for cold-working die steels[J].Heat Treatment of Metals,2006,31(2):87-93.
- [4] 冯晓曾,王家瑛,何世禹.提高模具寿命指南[M].北京:机械工业出版社,1998.
- [5] 迟宏宵.Cr8型冷作模具钢高性能化研究[D].昆明:昆明理工大学,2011.CHI Hong-xiao.Study on high performance of Cr8 cold working die steel[D].Kunming:Kunming University of Technology,2011.
- [6] Roberts G A,Cary R A.Tool Steels (4th Edition)[M].New York:American Society for Metals,1980.
- [7] Scandian C,Luz T S,Pardal J M,et al.Failure analysis of guides made of high-strength AISI D2 tool steel[J].Journal of Failure Analysis and Prevention,2015,15(6):789-793.
- [8] 方钟惠.逐步进入我国模具钢市场的D2钢[J].特殊钢,1993(5):41-43.FANG Zhong-hui.D2 steel gradually entering China’s die steel market[J].Special Steel,1993(5):41-43.
- [9] 尹熙武.D2钢的耐磨机理探讨[J].特钢技术,1999(1):1-11.YIN Xi-wu.Discussion on wear resistance mechanism of D2 steel[J].Special Steel Technology,1999(1):1-11.
- [10] Payson P.The Metallurgy of Tool Steels[M].New York:John Wiley & Sons’ Incorporation,1962.
- [11] Bombac D,Fazarinc M,Podder A S,et al.Study of carbide evolution during thermo-mechanical processing of AISI D2 tool steel[J].Journal of Materials Engineering and Performance,2013,22(3):742-747.
- [12] Kuo K.Carbides in chromium,molybdenum and tungsten steels[J].Journal of Iron and Steel Research International,1953,173:363-375.
- [13] 尹熙武.D2钢热加工工艺参数等对碳化物均匀性影响的研究报告[J].特钢技术,1996(3):47-62.YIN Xi-wu.Research report on the influence of D2 steel hot working process parameters on carbide uniformity[J].Special Steel Technology,1996(3):47-62.
- [14] 关慧欢,徐继东,刘燕燕,等.Cr12MoV钢拉深模失效分析及工艺改进[J].金属加工(热加工),2021(1):63-65.GUAN Hui-huan,XU Ji-dong,LIU Yan-yan,et al.Failure analysis and process improvement of Cr12MoV steel drawing die[J].Machinist Metal Forming,2021(1):63-65.
- [15] 林希峰,袁泽喜,李念.不同淬火工艺对D2钢组织与性能的影响[J].金属热处理,2015,40(4):117-120.LIN Xi-feng,YUAN Ze-xi,LI Nian.Influence of different quenching processes on microstructure and properties of D2 steel[J].Heat Treatment of Metals,2015,40(4):117-120.
- [16] Tang Z W,Li J S,Hu R,et al.Effects of solution heat treatment on carbide of Ni-Cr-W superalloy[J].Rare Metal Materials and Engineering,2010,39(7):1157-1161.
- [17] 郭海滨,左秀荣,张新理,等.奥氏体化温度对奥氏体晶粒度及第二相固溶的影响[J].钢铁研究学报,2016,28(2):63-68.GUO Hai-bin,ZUO Xiu-rong,ZHANG Xin-li,et al.Effect of austenitizing temperature on size of austenite grain and solid solution of second phase particles[J].Journal of Iron and Steel Research,2016,28(2):63-68.
- [18] Qian M.In-situ observations of the dissolution of carbides in an Fe-Cr-C alloy[J].Scripta Materialia,1999,41(12):1301-1303.
- [19] 刘健波,张学宾,宋克兴,等.固溶-高温回火对D2钢组织性能的影响[J].材料热处理报,2018,39(4):107-112.LIU Jian-bo,ZHANG Xue-bin,SONG Ke-xing,et al.Influence of solid solution and high temperature tempering on microstructure and properties of D2 steel[J].Transactions of Materials and Heat Treatment,2018,39(4):107-112.
- [20] 刘继浩,迟宏宵,曹建春,等.Cr12Mo1V1钢组织的高温转变行为[J].钢铁研究学报,2019,31(5):500-506.LIU Ji-hao,CHI Hong-xiao,CAO Jian-chun,et al.High temperature phase transition behavior of Cr12Mo1V1 steel[J].Journal of Iron and Steel Research,2019,31(5):500-506.
- [21] 崔向红,王树奇,吴宏,等.变质莱氏体钢中共晶碳化物的热处理粒化[J].吉林工业大学学报(工学版),2002(1):42-44.CUI Xiang-hong,WANG Shu-qi,WU Hong,et al.Granulation of eutectic carbide through heat-treatment in modified ledeburite steel[J].Journal of Jilin University (Engineering and Technology Edition),2002,32(1):42-46.
- [22] 马前,柳百成,王兆昌.Fe-C合金高温保温过程中碳化物表面形貌连续变化的研究[J].钢铁,1994(5):45-49.MA Qian,LIU Bai-cheng,WANG Zhao-chang.Study of the continuous morphological changes of carbide during high temperature holding of Fe-C alloys[J].Iron and Steel,1994(5):45-49.
- [23] Zhou X F,Fang F,Jiang J Q,et al.Refining carbide dimensions in AISI M2 high speed steel by increasing solidification rates and spheroidising heat treatment[J].Materials Science and Technology,2014,30(1):116-122.
- [24] Di H S,Zhang X M,Wang G D,et al.Spheroidizing kinetics of eutectic carbide in the twin roll-casting of M2 high-speed steel[J].Journal of Materials Processing Technology,2005,166(3):359-363.
- [25] 李彦军,姜启川,赵宇光,等.变质M2高速钢中共晶碳化物加热团球化的动力学研究[J].金属学报,1999,35(2):207-210.LI Yan-jun,JIANG Qi-chuan,ZHAO Yu-guang,et al.A dynamic study on the spheroidizing of eutectic carbide in the modified M2 steel[J].Acta Metallurgica Sinica,1999,35(2):207-210.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||