热处理温度对生物医用Ti87Nb8Sn5合金微观组织和力学性能影响Effect of heat treatment temperature on microstructure and mechanical properties of biomedical Ti87Nb8Sn5 alloy
王永善,李培友,马昕迪,蒲娇
摘要(Abstract):
采用X射线衍射仪、光学显微镜、万能试验机、显微硬度计以及纳米压痕仪等研究了不同热处理温度下Ti_(87)Nb_8Sn_5合金的显微组织和力学性能。结果表明:铸态和在773 K热处理下合金的组织是由大量α-Ti相和少量的第二相Ti_3Sn相所组成,在873 K和973 K热处理下合金的组织是由大量的α-Ti和少量β-Ti相所组成。室温铸态试样以及在773 K热处理试样的应力-应变曲线呈现出超弹性;而在873 K和973 K热处理的合金具有高的屈服强度,大的塑性形变以及大的弹性能。在873 K和973 K热处理下合金的约化弹性模量(E_r)值分别为43.3 GPa和36.2 GPa,接近人骨的弹性模量值(10~30 GPa)。另外,在873 K和973 K热处理下合金具有大的H/E_r和H~3/E■值,说明了该热处理条件下合金分别具有高的耐磨抗力和高的耐磨性。
关键词(KeyWords): Ti-Nb-Sn合金;显微组织;热处理温度;力学性能;纳米压痕
基金项目(Foundation): 陕西理工大学博士科研启动基金(SLGKYQD2-22)
作者(Author): 王永善,李培友,马昕迪,蒲娇
DOI: 10.13289/j.issn.1009-6264.2020-0046
参考文献(References):
- [1] Liu Y J,Li X P,Zhang L C,et al.Processing and properties of topologically optimised biomedical Ti-24Nb-4Zr-8Sn scaffolds manufactured by selective laser melting [J].Materials Science and Engineering A,2015,642:268-278.
- [2] Ninomi M.Recent metallic materials for biomedical applications [J].Metallurgical and Materials Transactions A,2002,33:477-486.
- [3] Song B,Dong S J,Zhang B C,et al.Effects of processing parameters on microstructure and mechanical property of selective laser melted Ti6Al4V [J].Materials and Design,2012 35:120-125.
- [4] Niinomi M.Recent research and development in titanium alloys for biomedical applications and healthcare goods [J].Science and Technology of Advanced Materials,2003,4:445-454.
- [5] Hon Y H,Wang J Y,Pan Y N.Composition/phase structure and properties of titanium-niobium alloys [J].Materials Transactions,2003,44:2384-2390.
- [6] Li P Y.Microstructural and mechanical properties of novel β-type Ti-Nb-Ni alloys containing a second phase [J].International Journal of Materials Research,2018,109:708-715.
- [7] Ozaki T,Matsumoto H,Watanabe S,et al.Beta Ti alloys with low Young’s modulus [J].Materials Transactions,2004,45:2776-2779.
- [8] Moraes P E L,Contieri R J,Lopes E S N,et al.Effects of Sn addition on the microstructure,mechanical properties and corrosion behavior of Ti-Nb-Sn alloys [J].Materials Characterization,2014,96:273-281.
- [9] Silva H,Schneider S,Neto C M.Study of nontoxic aluminum and vanadium-free titanium alloys for biomedical applications [J].Materials Science and Engineering C,2004,24:679-682.
- [10] Chang L L,Wang Y D,Ren Y.In-situ investigation of stress-induced martensitic transformation in Ti-Nb binary alloys with low Young’s modulus [J].Materials Science and Engineering A,2016,651:442-448.
- [11] Haghighi S E,Liu Y J,Cao G H,et al.Phase transition,microstructural evolution and mechanical properties of Ti-Nb-Fe alloys induced by Fe addition [J].Materials and Design,2016,97:279-286.
- [12] Haghighi S E,Liu Y J,Cao G H,et al.Influence of Nb on the β→α″ martensitic phase transformation and properties of the newly designed Ti-Fe-Nb alloys [J].Materials Science and Engineering C,2017,60:503-510.
- [13] Li P Y,Zhang H,Tong T,et al.The rapidly solidified β-type Ti-Fe-Sn alloys with high specific strength and low elastic modulus [J].Journal of Alloys and Compounds,2019,786:986-994.
- [14] Nnamchi P S,Obayi C S,Todd I,et al.Mechanical and electrochemical characterisation of new Ti-Mo-Nb-Zr alloys for biomedical applications [J].Journal of the Mechanical Behavior of Biomedical Materials,2016,60:68-77.
- [15] Ruzic J,Emura X,Ji X,et al.Mo segregation and distribution in Ti-Mo alloy investigated using nanoindentation [J].Materials Science and Engineering A,2018,718:48-55.
- [16] Li P Y.Microstructure and mechanical properties of novel β-type Ti-Co-Zr alloys with high specific strength [J].Materials Research Express,2019,6:076559.
- [17] Miura K K,Yamada N,Hanada S J,et al.The bone tissue compatibolity of a new Ti-Nb-Sn alloy with low Young’s modulus [J].Acta Biomaterialia 2011,7:2320-2326.
- [18] Hanada S,Masahashi N,Jung T K,et al.Fabrication of a high-performance hip prosthetic stem using β Ti-33.6Nb-4Sn [J].Journal of the Mechanical Behavior of Biomedical Materials,2014,30:140-149.
- [19] Li P Y,Ma X D,Wang D,et al.Microstructural and mechanical properties of β-type Ti-Nb-Sn biomedical alloys with low elastic modulus [J].Metals,2019,9:712-1-16.
- [20] Guo S,Shang Y,Zhang J S,et al.In situ synchrotron X-ray diffraction study of deformation behaviour of a metastable β-type Ti-33Nb-4Sn alloy [J].Materials Science and Engineering A,2017,692:81-89.
- [21] Fischer F D,Reisner G,Werner E,et al.A new view on transformation induced plasticity (TRIP) [J].International Journal of Plasticity,2000,16:723-748.
- [22] Haghighi S E,Cao G H,Zhang L C.Nanoindentation study of mechanical properities of Ti based alloys with Fe and Ta additions [J].Journal of Alloys and Compounds,2017,692:892-897.
- [23] Xu J,Wang G D,Lu X,et al.Mechanical and corrosion-resistant properties of Ti-Nb-Si-N nanocomposite films prepared by a double glow discharge plasma technique [J].Ceramics International,2014,40:8621-8630.
- [24] Musil J,Kunc F,Zeman H,et al.Relationships between hardness,Young’s modulus and elastic recovery in hard nanocomposite coatings [J].Surface and Coatings Technology,2002,154:304-313.
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