铝含量对Fe-12Cr-1.5B-Al合金凝固组织和硬度的影响Effect of aluminum content on solidification structure and hardness of Fe-12Cr-1.5B-Al alloy
鞠江,符寒光,程美洁,符定梅,雷永平
摘要(Abstract):
用真空感应炉熔炼含0-8.0%Al的Fe-12Cr-1.5B-Al合金。采用光学显微镜、扫描电镜、XRD、洛氏、维氏硬度计,研究了铝含量对Fe-12Cr-1.5B-Al合金凝固组织和硬度的变化规律。结果表明:无铝Fe-Cr-B合金凝固组织由基体和硬质相组成。基体主要是马氏体和少量奥氏体组织。硬质相有M2(B,C)、M7(C,B)3和M23(C,B)6。铝的加入使Fe-12Cr-1.5B-Al合金基体转变为珠光体和铁素体组织,而对硬质相类型无明显影响。当铝含量超过6.0%时,部分铝元素与铁结合形成铁铝金属间化合物。Cr元素主要存在于硬质相中,基体中也含有一定量的Cr元素。Al元素主要存在于基体和铁铝金属间化合物中。B元素主要存在于M2(B,C)相中。无铝Fe-Cr-B合金洛氏硬度达到61.1 HRC,随着铝含量的增加,Fe-12Cr-1.5B-Al合金的洛氏硬度以及维氏硬度呈现先急剧下降后缓慢升高的趋势。
关键词(KeyWords): 铝合金化;Fe-12Cr-1.5B-Al合金;凝固组织;硬度
基金项目(Foundation): 国家自然科学基金(51274016);; 北京市自然科学基金(2142009)
作者(Author): 鞠江,符寒光,程美洁,符定梅,雷永平
DOI: 10.13289/j.issn.1009-6264.2016.09.024
参考文献(References):
- [1]Christodoulou P,Calos N.A step towards designing Fe-Cr-B-C cast alloys[J].Materials Science&Engineering A,2001,301(2):103-117.
- [2]Zhang H,Fu H,Jiang Y,et al.Effect of boron concentration on the solidification microstructure and properties of Fe-Cr-B alloy[J].Materialwissenschaft Und Werkstofftechnik,2011,42(8):765-770.
- [3]Xing J D,Gao Y M,Wang E Z,et al.Effect of phase stability on the wear resistance of white cast iron at 800℃[J].Wear,2002,252(9):755-760.
- [4]花晓燕,郭长庆,韩继炜,等.冷却速度对Fe-Cr-B合金显微组织的影响[J].材料热处理学报,2015,36(6):47-51.HUA Xiao-yan,GUO Chang-qing,HAN Ji-wei,et al.Effects of cooling rate on microstructure of Fe-Cr-B alloy[J].Transactions of Materials and Heat Treatment,2015,36(6):47-51.
- [5]Kitano M,Ishii H,Shirai Y,et al.High-corrosion-resistant Al2O3passivation-film formation by selective oxidation on austenitic stainless steel containing Al[J].Journal of Vacuum Science&Technology A:Vacuum Surfaces&Films,2011,29(2):021002-021002-9.
- [6]Airiskallio E,Nurmi E,Heinonen M H,et al.High temperature oxidation of Fe-Al and Fe-Cr-Al alloys:The role of Cr as a chemically active element[J].Corrosion Science,2010,52(10):3394-3404.
- [7]喇培清,刘闪光.Al元素对310S耐热钢组织和力学性能的影响研究[J].材料工程,2009,1(2):36-40.LA Pei-qing,LIU Shan-guang.Effect of aluminum on microstructure and mechanical properties of 310S steel[J].Journal of Materials Engineering,2009,1(2):36-40.
- [8]Joslin D L,Easton D S,Liu C T,et al.Processing of Fe3Al and Fe Al alloys by reaction synthesis[J].Intermetallics,1995,3(6):467-481.
- [9]Enayati M H,Salehi M.Formation mechanism of Fe3Al and Fe Al intermetallic compounds during mechanical alloying[J].Journal of Materials Science,2005,40(15):3933-3938.
- [10]Sen U,Sen S,Yilmaz F.Structural characterization of boride layer on boronized ductile irons[J].Surface and Coatings Technology,2004,176:222-228.
- [11]杜忠泽,李颖,符寒光,等.淬火工艺对Fe-Cr-B合金显微组织和硬度的影响[J].材料热处理学报,2014(S2):51-54.DU Zhong-ze,LI Ying,FU Han-guang,et al.Effects of quenching process on microstructure and hardness of Fe-Cr-B alloy[J].Transactions of Materials and Heat Treatment,2014(S2):51-54.
- [12]苏航,柴峰,王卓,等.热力学、动力学计算技术在钢铁材料研究中的应用[M].北京:科学出版社,2012:2-49.
- [13]邓培凯,黎振华,岑启宏,等.铬对亚共晶Fe-B-C合金组织和力学性能的影响[J].材料热处理学报,2013,34(12)68-72.DENG Pei-kai,LI Zhen-hua,CEN Qi-hong,et al.Effect of chromium content on microstructure and mechanical properties of Fe-B-C hypoeutectic alloys[J].Transactions of Materials and Heat Treatment,2013,34(12):68-72.
- [14]Wang X M,He X L.Effect of boron addition on structure and properties of low carbon bainitic steels[J].ISIJ International,2002,42,S38-S46.
- [15]Hanguang Fu,Zhenhua Li,Jiandong Xing.Solidification structure in a cast B-bearing stainless steel[J].Materials letters,2007,61(2):4504-4 507.
- [16]胡增智.铁铝金属间化合物组织和性能的研究[D].哈尔滨:哈尔滨工业大学,2010.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||