烧结温度对Al3(Zr, Ti)/2024Al复合材料组织与性能的影响Effect of sintering temperature on microstructure and properties of Al3(Zr, Ti)/2024Al composites
骆宏文,徐琨,张文昌,龙威,周小平
摘要(Abstract):
以2024铝合金粉末为基体材料,纯Zr粉和纯Ti粉作为增强体材料,采用粉末冶金的方法制备出了Al_3(Zr, Ti)/2024Al复合材料。通过对Al-Ti-Zr三元体系进行差示扫描量热分析(DSC),确定了初步烧结温度。利用X射线衍射(XRD)、扫描电镜(SEM)、能谱仪(EDS)、万能拉伸试验、显微硬度仪以及电化学性能测试等研究了烧结温度对复合材料组织与性能的影响。结果表明:随着烧结温度的升高,复合材料的抗拉强度和硬度均呈现出先增大后减小的趋势,耐腐蚀性能呈现出先上升后下降的趋势。当烧结温度为850℃时,复合材料的抗拉强度、硬度和腐蚀电位达到最大,分别为458.06 MPa、149.8 HV0.01和-0.451 V,腐蚀电流密度为1.888×10~(-6) A/cm~2。随着烧结温度的升高,复合材料的致密度呈现出上升的趋势,孔隙度呈现出下降的趋势,当烧结温度为950℃时,复合材料的致密度达到了98.88%,孔隙度下降到了1.12%,说明烧结温度的适当提高可以使复合材料的致密度提高。
关键词(KeyWords): Al_3(Zr, Ti)/2024Al复合材料;烧结温度;硬度;抗拉强度;耐腐蚀性
基金项目(Foundation):
作者(Author): 骆宏文,徐琨,张文昌,龙威,周小平
DOI: 10.13289/j.issn.1009-6264.2021-0472
参考文献(References):
- [1] Muralidharan N,Chockalingam K,Dinaharan I,et al.Microstructure and mechanical behavior of AA2024 aluminum matrix composites reinforced with in situ synthesized ZrB2 particles[J].Journal of Alloys and Compounds,2018,735:2167-2174.
- [2] Zhang Z Y,Chen G,Zhang S L,et al.Enhanced strength and ductility in ZrB2/2024Al nanocomposite with a quasi-network architecture[J].Journal of Alloys and Compounds,2018,778:833-838.
- [3] 贺春林,吕帅,白莹莹,等.淬火方式对2024 Al合金腐蚀行为的影响[J].沈阳大学学报(自然科学版),2016,28(2):87-91.HE Chun-lin,Lü Shuai,BAI Ying-ying,et al.Effect of quenching method on corrosion behavior of 2024 Al alloy[J].Journal of Shenyang University(Natural Science),2016,28(2):87-91.
- [4] Wang J,Yang H,Du M,et al.Corrosion mechanism of 5083 aluminum alloy in seawater containing phosphate[J].Journal of Ocean University of China,2021,20(2):372-382.
- [5] 张呈呈.原位(ZrB2+Al3Zr)颗粒增强2024铝基复合材料的制备[D].长春:吉林大学,2014.ZHANG Cheng-cheng.Preparation of in situ (ZrB2+Al3Zr) particle reinforced 2024Al matrix composites[D].Changchun:Jilin University,2014.
- [6] 王建华,刘东雨.铝合金耐蚀性的研究[J].中国金属通报,2020(15):97-98.WANG Jian-hua,LIU Dong-yu.Study on corrosion resistance of aluminum alloy[J].China Metal Bulletin,2020(15):97-98.
- [7] 王禹慧,赵景茂,左禹.铝合金耐蚀膜的制备及其性能研究[J].腐蚀与防护,2005,26(10):432-435.WANG Yu-hui,ZHAO Jing-mao,ZUO Yu.Preparation of resistant film of aluminum[J].Corrosion and Protection,2005,26(10):432-435.
- [8] 张亚洲,杨俊瑞,杨瑞宾,等.球磨与烧结对Al2Ti3V2ZrB/2024Al复合材料组织与硬度的影响[J].特种铸造及有色合金,2020,40(4):420-426.ZHANG Ya-zhou,YANG Jun-rui,YANG Rui-bin,et al.Effect of ball milling and sintering on microstructure and hardness of Al2Ti3V2ZrB/2024Al composites[J].Special Casting and Nonferrous Alloys,2020,40(4):420-426.
- [9] Jiao L,Zhao Y T,Chen J C,et al.Microstructure and properties of Al3Zr/2024Al in situ composites after forging[J].Rare Metals,2016,35(12):920-925.
- [10] 李庆鹏,许茜,晏智强,等.2024铝合金表面无铬钛锆转化膜的制备与性能[J].腐蚀科学与防护技术,2016,28(5):475-479.LI Qing-peng,XU Qian,YAN Zhi-qiang,et al.Preparation and performances of chromium-free titanatezirconate conversion coating on 2024 aluminum alloy[J].Corrosion Science and Protection Technology,2016,28(5):475-479.
- [11] 李相荣,徐瀛,宋相宇,等.烧结温度对粉末冶金铁基材料组织与性能的影响[J].精密成形工程,2021,13(2):36-41.LI Xiang-rong,XU Ying,SONG Xiang-yu,et al.Effect of sintering temperature on microstructure and properties of powder metallurgy iron-based materials[J].Journal of Netshape Forming Engineering,2021,13(2):36-41.
- [12] Karmakar S,Kiran R,Vaish R,et al.Effect of sintering temperature on sensing,actuation and energy harvesting performance of (Ba0.85Ca0.15)(Ti0.9Zr0.1)O ceramics:A numerical and simulation based study[J].Engineering Research Express,2021,3(2):1-12.
- [13] Islam M N,Harun-Or-Rashid M,Islam J,et al.Improvement of microstructure and initial permeability of Mn0.5Ni0.1Zn0.4GdxFe2-xO4 with sintering temperature[J].Results in Physics,2021,24:104157.
- [14] Feng H,Liu S H,Du Y,et al.Effect of the second phases on corrosion behavior of the Mg-Al-Zn alloys[J].Journal of Alloys and Compounds,2017,695:2330-2338.
- [15] Zhang R,Wang H F,Xing X G,et al.Effects of Ni addition on tribocorrosion property of TiCu alloy[J].Tribology International,2017,107:39-47.
- [16] Xu D B,Long W,Zhou X P.Microstructure and corrosion resistance of Al3(Zr,Ti)/Al composite prepared by powder metallurgy[J].Advanced Composites Letters,2020,29(23):1-9.
- [17] Gan Y X,Dong J,Gan J B.Carbon network/aluminum composite made by powder metallurgy and its corrosion behavior in seawater[J].Materials Chemistry and Physics,2017,202:190-196.
- [18] Lei X W,Nuam V L,Yuan Y X,et al.Investigation on laser beam remelted Al-Cu-Li alloy part II:Corrosion behavior and mechanical properties[J].Journal of Alloys and Compounds,2021,873:159765.
- [19] Zhang B B,Wang J Z,Yuan J Y,et al.Tribocorrosion behavior of nickel-aluminium bronze sliding against alumina under the lubrication by seawater with different halide concentrations[J].Friction,2019,7(5):444-456.
- [20] Wang K,Su R,Liu T,et al.Electrochemical assessment of laser heat treatment of an Al-Zn-Mg-Cu alloy[J].Materials and Corrosion,2020,71(3):374-381.
- [21] Liang M C,Chen L,Zhao G Q,et al.Effects of solution treatment on the microstructure and mechanical properties of naturally aged EN AW 2024 Al alloy sheet[J].Journal of Alloys and Compounds,2020,824:153943.
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