退火温度对预制波纹轧制钛/钢复合板组织和性能的影响Effect of annealing temperature on microstructure and properties of pre-corrugated rolled titanium/steel composite plate
冯莹莹,单杰,廖宏义,耿硕,王明坤
摘要(Abstract):
钛/钢复合板具有良好的耐蚀性和较低的成本,但其较差的综合力学性能限制了其应用范围的拓展,如何提升其综合性能成为研究热点。研究了不同退火温度对预制波纹轧制的钛/钢复合板界面不同位置的微观组织和力学性能的影响。结果表明:随着退火温度的升高,界面处Fe和Ti元素跨界面的扩散距离不断增加,C元素向界面集中,这一现象促进了TiC颗粒的形核与长大,同时,(α-Ti+β-Ti)层的厚度不断增加,值得注意的是,波峰处的元素扩散行为和组织转变特征与其他位置存在显著差异;随着退火温度的升高,钢侧基材位错密度显著降低和再结晶晶粒显著增多,钢侧和钛侧小角度晶界减少,大角度晶界增多;退火温度的升高促使钢侧基材内马氏体数量锐减,因此复合板延展性提升,抗拉强度降低;当在750℃退火时,生成的脆性金属间化合物严重削弱了界面结合强度;在550℃退火时,复合板的综合力学性能最佳,抗拉强度为625 MPa,总伸长率为25.2%,剪切强度为291 MPa。
关键词(KeyWords): 钛/钢复合板;预制波纹轧制;退火温度;元素扩散;金属间化合物
基金项目(Foundation): 国家自然科学基金(52105322)
作者(Author): 冯莹莹,单杰,廖宏义,耿硕,王明坤
DOI: 10.13289/j.issn.1009-6264.2024-0594
参考文献(References):
- [1] Su H,Luo X B,Chai F,et al.Manufacturing technology and application trends of titanium clad steel plates[J].Journal of Iron and Steel Research International,2015,22(11):977-982.
- [2] Li B X,Chen Z J,He W J,et al.Effect of titanium grain orientation on the growth of compounds at diffusion bonded titanium/steel interfaces[J].Materials Characterization,2019,148:243-251.
- [3] 王小勇,张海,刘建明,等.热轧不锈钢复合板力学性能及工艺优化[J].中国冶金,2018,28(7):24-27.WANG Xiao-yong,ZHANG Hai,LIU Jian-ming,et al.Mechanical properties and process optimization of hot rolled stainless clad steel plate[J].China Metallurgy,2018,28(7):24-27.
- [4] Wang T,Gao X Y,Zhang Z X,et al.Interfacial bonding mechanism of Cu/Al composite plate produced by corrugated cold roll bonding[J].Rare Metals,2021,40:1284-1293.
- [5] Guo X W,Ren Z K,Chai Z,et al.Research on microstructure and mechanical properties of TC4/304 clad plates by asymmetric rolling with local strong stress[J].Materials Science and Engineering A,2024,893:146166.
- [6] Wang W J,Tu Y M,Liu M H,et al.Effect of inhomogeneous plastic deformation on the interfacial microstructure and properties of titanium/stainless steel[J].Journal of Materials Research and Technology,2023,24:1240-1251.
- [7] 董富军,王瑞珍,杨才福,等.热处理工艺对XG630DR钢板组织与力学性能的影响[J].热加工工艺,2019,48(18):133-136.DONG Fu-jun,WANG Rui-zhen,YANG Cai-fu,et al.Effects of heat treatment process on microstructure and mechanical properties of XG630DR steel plate[J].Hot Working Technology,2019,48(18):133-136.
- [8] Kumar R R,Gupta R K,Sarkar A,et al.Vacuum diffusion bonding of α-titanium alloy to stainless steel for aerospace applications:interfacial microstructure and mechanical characteristics[J].Materials Characterization,2022,183:111607.
- [9] Kundu S,Chatterjee S.Diffusion bonding between commercially pure titanium and micro-duplex stainless steel[J].Materials Science and Engineering A,2008,480(1/2):316-322.
- [10] Sunilkumar D,Dey H C,Albert S K,et al.Characterization of interfacial microstructure and mechanical properties of the diffusion bonded CP-Ti to AISI 304L stainless steel[J].Transactions of the Indian Institute of Metals,2021,74:9-20.
- [11] Pan X Y,Jiang J,Wan T J,et al.Effect of high-temperature normalizing heat treatment on interfacial microstructure and mechanical properties of rolled titanium steel composite plate[J].Journal of Materials Engineering and Performance,2024,33(11):5517-5528.
- [12] 杨德翰.真空热轧钛/钢复合板的界面产物演变机理及工艺控制[D].沈阳:东北大学,2019.YANG De-han.Evolution mechanism and process control of interfacial products with titanium-steel clad plate by vacuum rolling cladding[D].Shenyang:Northeastern University,2019.
- [13] 王宽,朱海平,宋振莉,等.钛钢复合板界面特征研究述评[J].功能材料,2017,4(48):25-32.WANG Kuan,ZHU Hai-ping,SONG Zhen-li,et al.Review on characteristics of interface of titanium clad steel plate[J].Journal of Functional Materials,2017,4(48):25-32.
- [14] 李标峰.钛与钢及钛复合钢板的焊接性研究(Ⅰ)[J].材料开发与应用,2004,49(1):41-44.LI Biao-feng.Study on the weldability of titanium and steel and titanium clad steel plate(Ⅰ)[J].Development and Application of Materials,2004,49(1):41-44.
- [15] Baehr H D.Thermochemical properties of inorganic substances[J].Forschung im Ingenieurwesen,1992,58(4):103.
- [16] Xie G M,Yang D H,Luo Z A,et al.The determining role of niobium interlayer on interfacial microstructure and mechanical properties of a vacuum roll-cladding titanium-steel clad plate[J].Materials,2018,10(11):1-13.
- [17] Wang S F,Cao L W,Zhang Z.Influence of carbide morphology on the deformation and fracture mechanisms of spheroidized 14CrMoR steel[J].Metals,2019,9(11):1221.
- [18] 何广霞,孟宪震,黄军.热处理工艺对14Cr1MoR钢板组织和性能的影响[J].特钢技术,2017,23(2):10-14.HE Guang-xia,MENG Xian-zhen,HUANG Jun.Effect of heat treatment process on structure and properties of 14Cr1MoR steel plate[J].Special Steel Technology,2017,23(2):10-14.
- [19] Yu C,Fu L,Xiao H,et al.Effect of carbon content on the microstructure and bonding properties of hot-rolling pure titanium clad carbon steel plates[J].Materials Science and Engineering A,2021,820:141572.
- [20] Kang J Y.Qualities of electron backscatter diffraction patterns and image contrast from a ferritic-martensitic steel microstructure[J].Materials Characterization,2022,187:111826.
- [21] Wang M L,Luo Z A,Li D,et al.Investigation on the interfacial microstructure and mechanical properties of Ti alloy/HSLA steel clad plates fabricated by vacuum roll-cladding[J].Materials Science and Engineering A,2022,853:143774.
- [22] Wu Y,Wang T,Ren Z K,et al.Evolution mechanism of microstructure and bond strength based on interface diffusion and IMCs of Ti/steel clad plates fabricated by double-layered hot rolling[J].Journal of Materials Processing Technology,2022,310:117780.
- [23] Wang L,Kamachali R D.CALPHAD integrated grain boundary co-segregation design:Towards safe high-entropy alloys[J].Journal of Alloys and Compounds,2023,933:167717.
- [24] 于浩,张道达,肖荣亭,等.回火温度对Q960钢小角度晶界的影响[J].北京科技大学学报,2011,33(8):952-957.YU Hao,ZHANG Dao-da,XIAO Rong-ting,et al.Effect of tempering temperature on low angle grain boundaries in Q960 steel[J].Journal of University of Science and Technology Beijing,2011,33(8):952-957.
- [25] Guo X W,Ren Z K,Chai Z,et al.Research on microstructure and mechanical properties of TC4/304 clad plates by asymmetric rolling with local strong stress[J].Materials Science and Engineering A,2024,893:146166.
- [26] 薛峰,孟延军,崔会杰,等.淬火温度对14Cr1MoR钢相变的影响[J].金属热处理,2018,43(2):122-126.XUE Feng,MENG Yan-jun,CUI Hui-jie,et al.Effect of quenching temperature on phase transformation of 14Cr1MoR steel[J].Heat Treatment of Metals,2018,43(2):122-126.
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