基于Thermo-Calc的马氏体耐热不锈钢析出相分析Analysis of precipitated phases of martensitic heat resistant stainless steel based on Thermo-Calc
张凯强,唐广波,李激光
摘要(Abstract):
基于Thermo-Calc热力学计算软件,研究了600℃、650℃时马氏体耐热不锈钢中Cr、W、Mo合金元素含量变化对析出相的影响。计算结果表明:钢中析出相主要为M_(23)C_6、金属间化合物Laves相和σ相。温度和合金元素Cr、W、Mo含量变化对M_(23)C_6碳化物析出影响较小,对Laves相和σ相的析出影响较大,W、Mo含量在一定范围内变化时会析出CHI相。随Cr含量增加,Laves相析出量先保持不变,但当σ相开始析出后线性减少。温度和W含量变化对σ相析出量影响较大。随Mo含量增加,Laves相析出量线性增加;600℃时当σ相开始析出后,Laves相析出量缓慢增加;650℃时无σ相析出,但当CHI相大量析出后,Laves相析出量急剧减少。
关键词(KeyWords): 马氏体耐热不锈钢;计算热力学;合金元素;析出相
基金项目(Foundation): 国家重点研发计划资助项目(2016YFB0700505)
作者(Author): 张凯强,唐广波,李激光
DOI: 10.13289/j.issn.1009-6264.2016-X254
参考文献(References):
- [1]余涛,刘新宝,郝巧娥,等.高铬钢蠕变析出相变化分析概述[J].金属世界,2016(2):26-29.YU Tao,LIU Xin-bao,HAO Qiao-e,et al.Analysis overview of high-chromium steel creep precipitated phase change[J].Metal World,2016(2):26-29.
- [2]Prat O,Garcia J,Rojas D,et al.Investigations on coarsening of MX and M23C6precipitates in 12%Cr creep resistant steels assisted by computational thermodynamics[J].Materials Science and Engineering A,2010,527:5976-5983.
- [3]张斌,胡正飞,王起江,等.国产T91耐热钢650℃蠕变断裂微观机理[J].金属热处理,2010,35(9):41-46.ZHANG Bin,HU Zheng-fei,WANG Qi-jiang,et al.Creep-rupture micromechanism of domestic T91 heat-resistant steel at 650℃[J].Heat Treatment of Metals,2010,35(9):41-46.
- [4]王学,于淑敏,任遥遥,等.P92钢时效的Laves相演化行为[J].金属学报,2014,50(10):1195-1202.WANG Xue,YU Shu-min,REN Yao-yao,et al.Laves phase evolution in P92 steel during aging[J].Acta Metallurgica Sinica,2014,50(10):1195-1202.
- [5]中国航空材料手册编辑委员会.中国航空材料手册:第1卷,结构钢、不锈钢[M].北京:中国标准出版社,2001.
- [6]Andersson J O,Helander T,Hoglund L,et al.Thermo-Calc&dictra,computational tools for materials science[J].Calphad,2002,26:273-312.
- [7]王国华.σ相的析出对双相不锈钢组织性能的影响[J].中国冶金,2011,21(6):15-18.WANG Guo-hua.Influence of the sigma phase precipitation on the microstructure and properties in duplex stainless steel[J].China Metallurgy,2011,21(6):15-18.
- [8]刘鸿国,李生志,熊伟,等.马氏体耐热钢中Laves相的析出行为[J].材料热处理学报,2015,36(9):109-113.LIU Hong-guo,LI Sheng-zhi,XIONG Wei,et al.Precipitation behavior and influence of Laves phase in martensitic heat resistant steel[J].Transactions of Materials and Heat Treatment,2015,36(9):109-113.
- [9]焦占坡,高加强,洪杰,等.T92钢在649℃不同应力蠕变过程中Laves相的析出行为及对强度的影响[J].机械工程材料,2010,34(10):5-8.JIAO Zhan-po,GAO Jia-qiang,HONG Jie,et al.Precipitation behavior of Laves phase and its influence on strength of T92 steel during creep at 649℃with different stresses.[J].Materials for Mechanical Engineering,2010,34(10):5-8.
- [10]彭志方,蔡黎胜,彭芳芳.P92钢625℃持久性能分段特征与各段中M23C6及Laves相相参数的定量变化研究[J].金属学报,2010,46(4):429-434.PENG Zhi-fang,CAI Li-sheng,PENG Fang-fang.Study on the multi-segment feature of 625℃creep-rupture property and the quatitative change of phase parameters of M23C6and Laves phases in each segment of P92 steel[J].Acta Metallurgica Sinica,2010,46(4):429-434.
- [11]Lee J S,Armaki H G,Maruyama K.Causes of breakdown of creep strength in 9Cr-1.8W-0.5Mo-VNb steel[J].Materials Science and Engineering A,2006,428:270-275.
- [12]Hattestrand M,Andren H.Evaluation of particle size distributions of precipitates in a 9%chromium steel using energy filtered transmission electron microscopy[J].Micron,2001,32(8):789-797.
- [13]王学,李勇,任遥遥,等.Laves相析出对P92钢合金元素再分布的影响[J].金属学报,2014,50(10):1203-1209.WANG Xue,LI Yong,REN Yao-yao,et al.Effect of Laves phase precipitation on redistribution of alloying elements in P92steel[J].Acta Metallurgica Sinica,2014,50(10):1203-1209.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||