不同Mo、W含量叶片用GY200镍基合金中碳化物的析出行为Precipitation behavior of carbides in GY200 Ni-based alloy for blade with different W and Mo contents
龚志华,杨钢,马龙腾,定巍
摘要(Abstract):
利用微观组织分析及化学相分析的方法研究了9种不同Mo、W含量的汽轮机叶片用GY200镍基合金中碳化物及γ'强化相的析出规律。结果表明,合金中出现MC、M_6C、M_(23)C_6型碳化物,MC相由一次未溶TiC和少量二次析出的TiC组成,MC相含量随W、Mo添加量增加而增加。M_6C在1080℃就开始析出,对于GY200镍基合金,M_6C析出条件可由Cr/(Cr+Mo+0.7W)≤0.847(at%)经验公式来表达。Mo添加后,M_(23)C_6含量随W添加量的增加有减少趋势。Mo促进TCP相析出的动力学比W元素的要强,利用W来替代部分Mo,能够减少Laves相、TCP相的析出。W添加4%以内将明显改善合金高温强塑性。
关键词(KeyWords): GY200;镍基合金;M23C6;M6C;动力学
基金项目(Foundation): 国家重点研发计划项目(2016YFB0300203)
作者(Author): 龚志华,杨钢,马龙腾,定巍
DOI: 10.13289/j.issn.1009-6264.2017-0178
参考文献(References):
- [1]Wright I G,Maziasz P J,Ellis F V,et al.Proceedings of the 29thinternational conference on coal utilization and fuel systems[C]//Florida,2004:1079-1092
- [2]Agarwal D C,Gehrmann B.Nickel alloys for high efficiency fossil power plants[C]//The 5th International Conference in Materials Technology for Fossil Power Plants,Florida,2007:271-280.
- [3]Blum R.2009 symposium on advanced power plant heat resistant steels and alloys[C]//Shanghai,China,2009:89
- [4]Fukuda M.The 3rd symposium on heat resistant steels and alloys for high efficiency USC power plants 2009[C]//Tsukuba,Japan,2009:12
- [5]Lin F S,Cheng S C,Xie X S.Fifth international conference on advances in materials technology for fossil power plants[C]//USA,2007:58
- [6]Bugge J,Kjr S,Blum R.High-efficiency coal-fired power plants development and perspectives[J].Energy,2006,31(10):1437-1445.
- [7]Viswanathan R,Henry J F,Tanzosh J,et al.U.S.program on materials technology for ultra-supercritical coal power plants[J].Journal of Materials Engineering and Performance,2005,14(3):281-292.
- [8]Fukuda M,Saito E,Semba H,et al.Advanced USC technology development in japan[C]//Proceedings of the 6th International Conference on Advances in Materials Technology for Fossil Power Plants,New Mexico,2010:325-341.
- [9]Fujio Abe,Torsten-Ulf Kern,Viswanathan R.Creep-resistant Steels[M].North America:CRC Press,2008.
- [10]Ryuichi Yamamoto,Yoshikuni Kadoya,Takashi Nakano.Proceedings from the fifth International conference on advances in materials technology for fossil power plant[C]//Florida,2007:434.
- [11]Kamoshida H,Imano S,Saito E,et al.Advances in materials technology for fossil power plants:Proceedings from the sixth international conference[C]//New Mexico,USA:Electric Power Research Institute,2011:373-385.
- [12]Fujimitsu Masuyama.History of power plants and progress in heat resistant steels[J].ISIJ Internatioal,2001,42(6):612-625.
- [13]Stoltz R E,Pineau A G.Dislocation-precipitate interaction and cyclic stress-strain behavior of aγ’strengthened superalloy[J].Materials Science and Engineering,1987,34:275-284.
- [14]Kim H Y,Sohn W H,Hong S H.High temperature deformation of Ti-(46-48)Al-2W intermetallic compounds[J].Materials Science and Engineering A,1998,251(1/2):216-225.
- [15]郭建亭.高温合金材料学,上册,应用基础理论[M].北京,科学出版社,2008:332.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||