0.3GO-0.3Ag/Al2O3-Cu/30Cr复合材料的热变形行为及热加工图Hot deformation behavior and hot processing map of 0.3GO-0.3Ag/Al2O3-Cu/30Cr composites
刘秋杰,田保红,周孟,刘勇,张启萌,楚春贺
摘要(Abstract):
采用真空快速热压烧结-内氧化法制备了0.3GO-0.3Ag/Al_2O_3-Cu/30Cr复合材料,借助显微硬度计、数字电导率仪、扫描电镜、能谱仪、X射线衍射、透射电镜和拉伸实验机等研究了复合材料烧结态的硬度、导电率、物相、微观组织与力学性能。在变形温度为650~950℃,应变速率为0.001~10 s~(-1)的条件下,采用Gleeble-1500D型热模拟实验机上对复合材料进行等温压缩试验,绘制了其真应力-真应变曲线;基于动态材料学模型,计算并建立了复合材料的本构方程,构建了热加工图,确定了该复合材料最佳热加工参数。结果表明:纳米γ-Al_2O_3颗粒弥散强化了0.3GO-0.3Ag/Al_2O_3-Cu/30Cr复合材料基体,Cr_(23)C_6颗粒钉扎相界面;复合材料结构致密,综合性能良好,其致密度为98.20%,导电率为46.1%IACS,硬度为158 HV0.5,抗拉强度为413 MPa;复合材料真应力-应变曲线具有典型的动态再结晶特征,其热激活能为279.954 kJ/mol,适宜的加工工艺参数范围为变形温度为750~950℃,应变速率为0.008~0.223 s~(-1)。
关键词(KeyWords): 弥散铜-Cr复合材料;热变形行为;热加工图;热激活能
基金项目(Foundation): 中国博士后科学基金资助项目(2023TQ0107);; 河洛青年人才托举工程(2023HLTJ12)
作者(Author): 刘秋杰,田保红,周孟,刘勇,张启萌,楚春贺
DOI: 10.13289/j.issn.1009-6264.2024-0530
参考文献(References):
- [1] Bodrova L E,Melchakov S Y,Shubin A B,et al.Smart-microstructures of composites for electrical contacts with frameless packing of Cr and W in copper[J].Transactions of Nonferrous Metals Society of China,2021,31(9):2773-2786.
- [2] Yang K,Wang Y H,Guo M X,et al.Recent development of advanced precipitation-strengthened Cu alloys with high strength and conductivity:A review[J].Progress in Materials Science,2023,138:101141.
- [3] Li H,Zhou M,Tian B H,et al.Microstructure and electrical contact properties of Al2O3-Cu/(Cr,Zr) composites[J].Materials Today Communications,2024,38:107747.
- [4] Zhang X H,Zhang Y,Tian B H,et al.Arc erosion behavior of the Al2O3-Cu/(W,Cr) electrical contacts[J].Composites Part B:Engineering,2019,160:110-118.
- [5] Inada Y,Kikuchi R,Nagai H,et al.Influence of CuCr electrode composition on 2D electron and metal vapor density distribution over vacuum arc[J].Journal Physics D:Applied Physics,2020,53:305201.
- [6] Zhou X Y,Yi D Q,Nyborg L,et al.Influence of Ag addition on the microstructure and properties of copper-alumina composites prepared by internal oxidation[J].Journal of Alloys and Compounds,2017,722:962-969.
- [7] Zhang X X,Yuan Y L,Zhao S Q,et al.Microstructure stability,softening temperature and strengthening mechanism of pure copper,CuCrZr and Cu-Al2O3 up to 1000 ℃[J].Journal of Nuclear Materials,2022,30:101123.
- [8] Chu K,Wang F,Li Y B,et al.Interface structure and strengthening behavior of graphene/CuCr composites[J].Carbon,2018,133:127-139.
- [9] 鲍瑞,张文府,易健宏,等.粉末冶金法制备协同增强铜基复合材料的研究进展[J].粉末冶金材料科学与工程,2022,27(1):1-12.BAO Rui,ZHANG Wen-fu,YI Jian-hong,et al.Research progress of synergistic reinforced copper matrix composites prepared by powder metallurgy[J].Materials Science and Engineering of Powder Metallurgy,2022,27(1):1-12.
- [10] 冯江,田保红,孙永伟,等.Al2O3/Cu-WC复合材料热变形行为及热加工图[J].中国有色金属学报,2012,22(12):3462-3467.FENG Jiang,TIAN Bao-hong,SUN Yong-wei,et al.Hot deformation behavior and processing maps of Al2O3/Cu-WC composites[J].The Chinese Journal of Nonferrous Metals,2012,22(12):3462-3467.
- [11] 雷沙沙,刘洪军.铜基复合材料制备工艺的研究进展[J].机械工程材料,2021,45(10):13-21.LEI Sha-sha,LIU Hong-jun.Research progress on preparation technology of copper matrix composites[J].Materials for Mechanical Engineering,2021,45(10):13-21.
- [12] 朱永丽,林楠.颗粒增强铝基复合材料热变形行为研究进展[J].铸造技术,2016,37(4):642-646.ZHU Yong-li,LIN Nan.Development of hot deformation of particle reinforced aluminum matrix composites[J].Foundry Technology,2016,37(4):642-646.
- [13] 张兵,刘鹏茹,张志娟,等.W80-Cu20复合材料热变形行为及加工图[J].稀有金属材料与工程,2022,51(1):203-210.ZHANG Bing,LIU Peng-ru,ZHANG Zhi-juan,et al.Thermal deformation behavior and processing map of W80-Cu20 composite by hot compressing[J].Rare Metal Materials and Engineering,2022,51(1):203-210.
- [14] 毛卫民,赵新兵.金属的再结晶与晶粒长大[M].北京:冶金工业出版社,1994.MAO Wei-min,ZHAO Xin-bing.The Metal Recrystallization and Grain Growth[M].Beijing:Metallurgical Industry Press,1994.
- [15] An J C,Zhou M,Tian B H,et al.Hot deformation behavior of nano-Al2O3-dispersion-strengthened Cu20W composite[J].Science and Engineering of Composite Materials,2021,28(1):500-509.
- [16] Roucoules C,Pietrzyk M,Hodgson P D.Analysis of work hardening and recrystallization during the hot working of steel using a statistically based internal variable model[J].Materials Science and Engineering A,2003,339(1/2):1-9.
- [17] 王能能,田保红,周孟,等.Cu-2Ti-0.3Zr合金的热变形行为及组织演变[J].材料热处理学报,2024,45(6):147-154.WANG Neng-neng,TIAN Bao-hong,ZHOU Meng,et al.Hot deformation behavior and microstructure evolution of Cu-2Ti-0.3Zr alloy[J].Transactions of Materials and Heat Treatment,2024,45(6):147-154.
- [18] Sellars C M,McTegart W J.On the mechanism of hot deformation[J].Acta Metallurgica,1996,14(9):1136-1138.
- [19] Zener C,Hollomon J H.Effect of strain rate upon the plastic flow of steel[J].Journal of Applied Physics,1944,15(1):22-27.
- [20] 李庆波,周海涛,蒋永峰,等.加工图的理论研究现状与展望[J].有色冶金设计与研究,2009,30(4):1-6.LI Qing-bo,ZHOU Hai-tao,JIANG Yong-feng,et al.Research status quo and prospect of the theory of shop drawing[J].Nonferrous Metals Engineering & Research,2009,30(4):1-6.
- [21] 王冰洁,田保红,张毅,等.Cu-0.8%Mg-0.2%Fe合金热变形行为及热加工图[J].材料热处理学报,2018,39(1):145-151.WANG Bing-jie,TIAN Bao-hong,ZHANG Yi,et al.Hot deformation behavior and processing maps of Cu-0.8%Mg-0.2%Fe alloy[J].Transactions of Materials and Heat Treatment,2018,39(1):145-151.
- [22] 班宜杰,张毅,田保红,等.Cu-0.8Cr-0.3Zr-0.2Mg合金热变形行为及热加工图[J].材料热处理学报,2019,40(9):44-49.BAN Yi-jie,ZHANG Yi,TIAN Bao-hong,et al.Hot deformation behavior and hot processing map of Cu-0.88Cr-0.3Zr-0.2Mg alloy[J].Transactions of Materials and Heat Treatment,2019,40(9):44-49.
- [23] Prasad Y,Seshacharyulu T.Processing maps for hot working of titanium alloys[J].Materials Science and Engineering A,1998,243(1/2):82-88.
- [24] 常锴骞,王军用,张清,等.Mg-4Sm-3Gd-0.5Zr合金的热变形行为及热加工图[J].材料热处理学报,2024,45(10):183-191.CHANG Kai-qian,WANG Yong-jun,ZHANG Qing,et al.Hot deformation behavior and hot processing map of Mg-4Sm-3Gd-0.5Zr alloy[J].Transactions of Materials and Heat Treatment,2024,45(10):183-191.
- [25] Prasad Y,Gegel H L,Doraivelu S M,et al.Modeling of dynamic material behavior in hot deformation:Forging of Ti-6242[J].Metallurgical Transactions A,1984,15:1883-1892.
- [26] 王冰洁,田保红,张毅,等.稀土元素Y对Cu-0.4%Mg合金热变形行为的影响[J].材料热处理学报,2018,39(7):126-134.WANG Bing-jie,TIAN Bao-hong,ZHANG Yi,et al.Effects of rare earth element Y on thermal deformation behavior of Cu-0.4%Mg alloy[J].Transactions of Materials and Heat Treatment,2018,39(7):126-134.
- [27] 黄有林,王建波,凌学士,等.热加工图理论的研究进展[J].材料导报,2008,22(S3):173-176.HUANG You-lin,WANG Jian-bo,LING Xue-shi,et al.Research development of hot processing map theory[J].Materials Review,2008,22(S3):173-176.
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