钛基体上IrO2+MnO2涂层的表面形貌和电催化活性(英文)Surface morphology and electro-catalytic activity of IrO2+ MnO2 coatings on titanium substrates
谢秋霞,叶志国,刘磊,孟惠民,范庆国,黄广斌
摘要(Abstract):
对表面粗糙度不同的钛(Ti)基体进行抛光和喷砂处理,通过H2IrCl6和Mn(NO3)2水溶剂在处理后的基体上制备IrO2+MnO2涂层。采用扫描电子显微镜(SEM),场发射扫描电子显微镜(FESEM),循环伏安法(CV)和阳极极化曲线研究了不同表面粗糙度的IrO2+MnO2涂层的表面特性,结构和电催化活性。在所有通过喷砂处理的基体表面上制备的IrO2+MnO2涂层中,都可以分离出二氧化铱纳米棒,但通过抛光处理的涂层不能形成。通过喷砂处理的IrO2+MnO2涂层的qT,qo,qi和i/qT值远远高于抛光处理的涂层。表面粗糙度为1.3μm的IrO2+MnO2涂层比其他涂层具有更好的电催化活性。
关键词(KeyWords): IrO2+MnO2涂层;IrO2纳米棒;喷砂处理;抛光处理;电催化活性
基金项目(Foundation): 国家自然科学基金和航空基金项目(21103085,2013ZF56022)
作者(Author): 谢秋霞,叶志国,刘磊,孟惠民,范庆国,黄广斌
DOI: 10.13289/j.issn.1009-6264.2015.s1.045
参考文献(References):
- [1]Ges I A,Ivanov B L,Schaffer D K,et al.Thin-film Ir Ox p H microelectrode for microfluidic-based microsystems[J].Biosens Bioelectron,2005,21(2):248-256.
- [2]Yao S,Wang M,Madou M.A p H Electrode Based on Melt-Oxidized Iridium Oxide[J].Journal of the Elettrochemical Society,2001,148(4):29-36.
- [3]Karthigeyan A,Gupta R P,Scharnagl K,et al.A room temperature HSGFET ammonia sensor based on iridium oxide thin film[J].Sensor Actuat BChem,2002,85(1/2):145-153.
- [4]Grumet A E,Wyatt J L,Rizzo J F,et al.Multi-electrode stimulation and recording in the isolated retina[J].Journal of Neuroscience Methods,2000,101(1):31-42.
- [5]Park T J,Jeong D S,Hwang C S,et al.Fabrication of ultrathin Ir O2top electrode for improving thermal stability of metal-insulator-metal field emission cathodes[J].Thin Solid Films,2005,471(1/2):236-242.
- [6]Lee H S,Um W S,Hwang K T,et al.Ferroelectric properties of Pb(Zr,Ti)O3thin films deposited on annealed Ir O2and Ir bottom electrodes[J].Journal of Vacuum Science and Technology A,1999,17:2939-2943.
- [7]Hackwood S,Beni G,Bsch M A,et al.New process for optical information storage[J].Physical Review B,1982,26:7073-7075.
- [8]Wang X M,Hu J M,Zhang J Q,et al.Characterization of surface fouling of Ti/Ir O2electrodes in 4-chlorophenol aqueous solutions by electrochemical impedance spectroscopy[J].Electrochim Acta,2008,53(8):3386-3394.
- [9]Wu J,Zhang H,Oturan N,et al.Application of response surface methodology to the removal of the antibiotic tetracycline by electrochemical process using carbon-felt cathode and DSA(Ti/Ru O2-Ir O2)anode[J].Chemosphere,2012,87(6):614-620.
- [10]Zhang J J,Hu J M,Zhang J Q,et al.Ir O2-Si O2binary oxide films:Geometric or kinetic interpretation of the improved electrocatalytic activity for the oxygen evolution reaction[J].International Journal of Hydrogen Energy,2011,36(9):5218-5226.
- [11]Cruz J C,Baglio V,Siracusano S,et al.Nanosized Pt/Ir O2electrocatalyst prepared by modified polyol method for application as dual function oxygen electrode in unitized regenerative fuel cells[J].International Journal of Hydroyen Energy,2012,37(7):5508-5517.
- [12]Thanawala S S,Baird R J,Georgiev D G,et al.Amorphous and crystalline Ir O2thin films as potential stimulation electrode coatings[J].Applied Surface Science,2008,254(16):5164-5169.
- [13]Ritterhaus Y,Hur'yeva T,Lisker M,et al.Iridium thin films deposited by liquid delivery MOCVD using Ir(Et Cp)(1,5-COD)with toluene solvent[J].Chemical Vapor Deposition,2007,13(12):698-704.
- [14]Nishio K,Watanabe Y,Tsuchiya T,et al.Preparation and properties of electrochromic iridium oxide thin film by sol-gel process[J].Thin Solid Films,1999,350(1/2):96-100.
- [15]Zhang L M,Gong Y S,Wang C B,et al.Substrate temperature dependent morphology and resistivity of pulsed laser deposited iridium oxide thin films[J].Thin Solid Films,2006,496(2):371-375.
- [16]Kristof J,Szilagyi T,Horvath E,et al.Investigation of Ir O2/Ta2O5thin film evolution[J].Thermochimica Acta,2004,413(1/2):93-99.
- [17]Patil P S,Chigare P S,Sadale S B,et al.Thickness-dependent properties of sprayed iridium oxide thin films[J].Materials Chemistry and Physics,2003,80(3):667-675.
- [18]Ye Z G,Meng H M,Chen D,et al.Structure and characteristics of Ti/Ir O2(x)+Mn O2(1-x)anode for oxygen evolution[J].Solid State Sciences,2008,10(3):346-354.
- [19]Ye Z G,Meng H M,Sun D B.New degradation mechanism of Ti/Ir O2+Mn O2anode for oxygen evolution in 0.5 M H2SO4solution[J].Electrochimica Acta,2008,53(18):5639-5643.
- [20]De Faria L A,Boodts J F C,Trasatti S.Electrocatalytic properties of Ru+Ti+Ce mixed oxide electrodes for the Cl2evolution reaction[J].Electrochimica Acta,1997,42(23/24):3525-3530.
- [21]Da Silva L A,Alves V A,Trasatti S,et al.Surface and electrocatalytic properties of ternary oxides Ir0.3Ti(0.7-x)PtxO2.Oxygen evolution from acidic solution[J].Journal Electroandytical Chemistry,1997,427(1/2):97-104.
- [22]Panic V V,Dekanski A B,Vidakovic T R,et al.Oxidation of phenol on Ru O2-Ti O2/Ti anodes[J].Solid State Electronics,2005,9(1):43-54.
- [23]Vercesi G P,Salamin J Y,Comninellis C.Morphological and microstructural the Ti/Ir O2Ta2O5electrode:effect of the preparation temperature[J].Electrochimica Acta,1991,36(5/6):991-995.
- [24]Krysa J,Kule L,Mráz R,et al.Effect of coating thickness and surface treatment of titanium on the properties of Ir O2-Ta2O5anodes[J].Journal of Applised Electrochemica,1996,26(10):999-1005.
- [25]Spinolo G,Ardizzone S,Trasatti S.Surface characterization of Co3O4electrodes prepared by the sol-gel method[J].Journal of Electroandytical Chemistry,1997,423(1/2):49-57.
- [26]Burke L D,Whelan D P.A voltammetric investigation of the charge storage reactions of hydrous iridium oxide layers[J].Journal of Electroandytical Chemistry,1984,162(1/2):121-141.
- [27]Pickup P G,Birss V I.The kinetics of charging and discharging of iridium oxide films in aqueous and non-aqueous media[J].Journal of Electroandytical Chemistry,1988,240(1/2):185-199.
- [28]Atanasoska L,Atanasoski R,Trasatti S.XPS and AES study of mixed layers of Ru O2and Ir O2[J].Vacuum,1990,40(1/2):91-94.
- [29]Li Y J,Chang C C,Wen T C.A mixture design approach to thermally prepared Ir-Pt-Au ternary electrodes for oxygen reduction in alkaline-solution[J].Journal of Applied Appl Electrochemistry,1997,27(2):227-234.
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