微弧氧化处理对Q235钢电镀铝层相结构和性能的影响Influence of micro-arc oxidation process on phase structure and properties of electroplating aluminum coating on Q235 steel
丁志敏,陈凯敏,沈长斌,阎颖,高宏
摘要(Abstract):
用AlCl3-NaCl-KCl低温熔融盐体系在Q235钢表面上获得了电镀铝层,并对电镀铝层进行微弧氧化处理。用扫描电镜和X射线衍射分析仪观察和测定了微弧氧化层的表面形貌和相结构,并对其硬度和耐蚀性能进行了测试。结果表明:Q235钢表面上的电镀铝层经不同时间的微弧氧化处理后,其表面形貌与铝及其合金经微弧氧化处理后的相似,为多孔熔融凝固形貌。经30min的微弧氧化处理后,其电镀铝层表面除了存在Al相之外,还出现了-γAl2O3相。经不同时间微弧氧化处理后,电镀铝层的表面硬度和在3.5%NaCl溶液中的电化学耐蚀性能均得到了较大程度的提高,且随微弧氧化时间的延长硬度增加,而电化学耐蚀性能先增加而后降低,最佳处理时间为20min。
关键词(KeyWords): 电镀铝;微弧氧化;表面形貌;相结构;耐蚀性
基金项目(Foundation): 辽宁省高等学校重点实验室项目(2008S308)
作者(Author): 丁志敏,陈凯敏,沈长斌,阎颖,高宏
参考文献(References):
- [1]Jun-jchi Uchida,Tetsuaki Tsuda,Yasuhiro Yamamoto,et al.Electroplating of amorphous aluminum-manganese alloy from molten salts[J].ISIJ International,1993,33(9):1029-1030.
- [2]宋国泰,牛洪军,孙一唐.黄铜熔盐电解沉积铝工艺研究[J].吉林工业大学学报,1992,22(3):114-118.SONG Guo-tai,NIU Hong-jun,SUN Yi-tang.Electro-depositing aluminum upon brass from chloride molten salt bath[J].Journal of Jilin University ofTechnology,1992,22(3):114-118.
- [3]杜道斌.熔盐电解渗铝沉积过程及渗铝层性能研究[J].金属热处理.1993,(10):16-21.DU Dao-bin.Process and properties of electrolytic aluminum diffused deposition in molten salt[J].Heat Treatment of Metals,1993,(10):16-21.
- [4]牛洪军,孙国恩,宋国泰.AlCl3-NaCl熔盐电镀铝及其耐蚀性[J].腐蚀与保护,1994,15(2):61-63.NIU Hong-jun,SUN Guo-en,SONG Guo-tai.Electroplating aluminum in molten AlCl3-NaCl and the corrosion resistance of the coating[J].Corrosion andProtection,1994,15(2):61-63.
- [5]丁志敏,冯秋元,石子源,等.Q235钢表面熔盐电镀铝及其耐蚀性的研究[J].金属热处理,2004,29(7):41-43.DING Zhi-min,FENG Qiu-yun,SHI Zi-yuan,et al.Study on electroplating aluminum of Q235 steel in molten salt and the corrosion resistance[J].HeatTreatment of Metals,2004,29(7):41-43.
- [6]丁志敏,冯秋元,石子源,等.钢铁件熔融盐电镀铝及其抗高温氧化性的研究[J].热加工工艺,2004,(7):27-28,31.DING Zhi-min,FENG Qiu-yun,SHI Zi-yuan,et al.Study on electroplating aluminum of steel in molten salt and high temperature oxidation resistance[J].HotWorking Technology,2004,(7):27-28,31.
- [7]朱祖芳.铝合金阳极氧化与表面处理技术[M].北京:化学工业出版社,2004.
- [8]薛文斌,邓志威,来永春,等.有色金属表面微弧氧化技术评述[J].金属热处理,2000,25(1):1-3.XUE Wen-bin,DENG Zhi-wei,LAI Yong-chun.Review of microarc oxidation technique on surface of non-ferrous[J].Heat Treatment of Metals,2000,25(1):1-3.
- [9]刘建平,旷亚非.微弧氧化技术及其发展[J].材料导报,1998,12(5):27-29.LIU Jian-ping,KUANG Ya-fei.Microarc anodization technique and its development[J].Materials Review,1998,12(5):27-29.
- [10]吴汉华,龙北红,吕宪义.铝合金微弧氧化过程中电学参量的特性研究[J].物理学报,2005,54(4):1697-1701.WU Han-hua,LONG Bei-hong,LV Xian-yi.Study on the electrical parameter variation during microarc oxidation of aluminium alloys[J].Acta Physica Sinica,2005,54(4):1697-1701.
- [11]刘兆晶,左洪波,束术军.铝合金表面陶瓷层形成机理[J].中国有色金属学报,2000,10(6):859-863.LIU Zhao-jing,ZUO Hong-bo,SHU Shu-jun.Formation mechanism of surface ceramic coating on aluminum alloy[J].The Chinese Journal of NonferrousMetals,2000,10(6):859-863.
- [12]Krysmann W,Kurze P,Dittrich K H,et al.Proccss characteristics and parameters of anodic oxidization by spark discharge[J].Crystal Research andTechnlolgy,1984,19(7):973-979.
- [13]杜军,陈东初,李文芳,等.铝合金微弧氧化陶瓷膜的微观结构和耐蚀性[J].华南理工大学学报(自然科学版),2007,35(3):6-10.DU Jun,CHEN Dong-chu,LI Wen-fang,et al.Microstructure and corrosion resistance of ceramic coatings formed on aluminum alloy by micro-arc oxidation[J].Journal of South China University of Technology(Natural Science Edition),2007,35(3):6-10.
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