退火时间对AgCuZnNiMn/Cu/AgCuZnNiMn多层复合钎料元素扩散行为的影响Effect of annealing time on element diffusion behavior of AgCuZnNiMn/Cu/AgCuZnNiMn multilayer composite brazing filler metal
刘晓芳,张冠星,钟素娟,常云峰
摘要(Abstract):
采用扫描电镜(SEM)、能谱仪(EDS)和万能力学试验机等研究了500℃退火不同时间对AgCuZnNiMn/Cu/AgCuZnNiMn多层复合钎料界面元素扩散行为与钎焊力学性能的影响。结果表明:复合钎料界面扩散层主要为银基固溶体、铜基固溶体;随退火时间的增加,物相发生明显粗化,界面两侧元素不断发生互扩散,当退火时间为24 h时,界面扩散层厚度达20μm。同时,随退火时间的增加,钎焊接头界面处的应力缓释Cu层逐渐减少直至消失,接头强度从224 MPa下降到165 MPa,接头断裂机制从以韧窝为主的韧性断裂向韧-脆混合性断裂转变。表明退火时间对多层复合钎料中间层宽度设定有重要影响,而中间层的相对宽度也影响钎料的使用性能。
关键词(KeyWords): AgCuZnNiMn/Cu/AgCuZnNiMn钎料;退火时间;扩散行为
基金项目(Foundation): 国家自然科学基金(U1904197)
作者(Author): 刘晓芳,张冠星,钟素娟,常云峰
DOI: 10.13289/j.issn.1009-6264.2022-0584
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