超快冷工艺生产X90管线钢组织性能与析出行为Microstructure,properties and precipitation behavior of X90 pipeline steel produced by ultra fast cooling
张鹤松,朱国明,康永林
摘要(Abstract):
利用超快冷工艺在2250热连轧生产线生产X90管线钢,通过光学显微镜和扫描电镜观察组织,利用透射电镜观察微观结构和析出形貌,通过物理化学相分析及理论计算对析出规律进行研究,并对应变时效性能进行了研究。结果表明,X90管线钢屈服强度615~645 MPa,抗拉强度808~844 MPa,屈强比低于0.8,-20℃冲击功均在300 J以上;基体为由准多边形铁素体、粒状贝氏体、贝氏体铁素体及马氏体奥氏体组元构成的复相组织;析出为Ti、Nb的碳氮化物,超快冷工艺使管线钢中析出过程有效避开了析出鼻尖温度,从而使析出粒子更加细小弥散,析出沉淀强化作用理论计算值为92 MPa;经应变时效后拉伸曲线由Round-House形转变为Luders伸长型,出现明显的屈服平台,屈服强度增加250~280 MPa。
关键词(KeyWords): 超快冷;X90;组织性能;强化机制;应变时效
基金项目(Foundation): 国家高技术研究发展计划(863计划)项目(2013AA031601);; 国家“十二五”科技支撑计划项目(2012BAF04B01)
作者(Author): 张鹤松,朱国明,康永林
DOI: 10.13289/j.issn.1009-6264.2015.12.018
参考文献(References):
- [1]Hara T,Fujishiro T,Shinohara Y,et al.Metallurgical design and development of high-grade line pipe[C]//Proceedings of the 2012 9th International Pipeline Conference.Calgary,Alberta,Canada,2012:149-157.
- [2]牛涛,康永林,顾宏伟,等.高级别X80/X100管线钢的包辛格效应[J].北京科技大学学报,2010,32(9),1144-1149.NIU Tao,KANG Yong-lin,GU Hong-wei,et al.Bauschinger effect of high grade X80/X100 pipeline steels[J].Journal of University of Science and Technology Beijing,2010,32(9):1144-1149.
- [3]Rahmatollah G,Giuseppe M,Arash K.Ductile failure of X100 pipeline steel-experiments and fractography[J].Materials&Design,2013,43:513-525.
- [4]史立强,牛辉,杨军,等.大口径JCOE工艺生产X90管线钢组织与性能的研究[J].热加工工艺,2015,44(3),226-229.SHI Li-qiang,NIU Hui,YANG Jun,et al.Research on structure-properties of large diameter X90 pipeline steel produced by JCOE technological parameters[J].Hot Working Technology,2015,44(3):226-229.
- [5]田勇,王昭东,王国栋,等.超快速冷却装置的开发及其在管线钢生产中的应用[J].东北大学学报:自然科学版,2012,33(8):1141-1144.TIAN Yong,WANG Zhao-dong,WANG Guo-dong.Development of ultra-fast cooling equipment and its application to production of pipeline steel[J].Journal of Northeastern University:Natural Science,2012,33(8):1141-1144.
- [6]王国栋.以超快速冷却为核心的新一代TMCP技术[J].上海金属,2008,30(2):1-5.WANG Guo-dong.The new generation TMCP with the key technology of ultra-fast cooling[J].Shanghai Metals,2008,30(2):1-5.
- [7]Kuang C F,Li J,Zhang S G,et al.Effects of quenching and tempering on the microstructure and bake hardening behavior of ferrite and dual phase steels[J].Materials Science&Engineering A,2014,613:178-183.
- [8]齐丽华,牛靖,杨龙,等.X100级高强度管线钢的应变时效行为[J].材料热处理学报,2011,32(2):65-69.QI Li-hua,NIU Jing,YANG Long,et al.Effects of strain aging on microstructure and properties of X100 pipeline steel[J].Transactions of Materials and Heat Treatment,2011,32(2):65-69.
- [9]Yasuhiro S,Takuya H,Eiji T,et al.Change of mechanical properties of high strength line pipe by thermal coating treatment[C]//24th International Conference on Offshore Mechanics and Arctic Engineering(OMAE 2005).Halkidiki,Greece,2005:27-34.
- [10]齐亮,赵爱民,赵征志,等.铌对高钢级管线钢中碳氮化物析出热力学影响[J].材料科学与工艺,2012,20(6):29-34.QI Liang,ZHAO Ai-min,ZHAO Zheng-zhi,et al.Effect of niobium on the carbonitride complex precipitation in high-grade pipeline steels[J].Materials Science&Technology,2012,20(6):29-34.
- [11]Craven A J,He K,Garvie L A J,et al.Complex heterogeneous precipitation in titanium-niobium microalloyed Al-killed HSLA steels-I.(Ti,Nb)(C,N)particles[J].Acta Materialia,2000,48(15):3857-3868.
- [12]Poths R M,Higginson R L,Palmiere E J.Complex precipitation behaviour in a microalloyed plate steel[J].Scripta Materialia,2001,44(1):147-151.
- [13]Shanmugam S,Tanniru M,Misra R D K,et al.Microalloyed V-Nb-Ti and V steels part 2-precipitation behaviour during processing of structural beams[J].Materials Science and Technology,2005,21(2):165-177.
- [14]Cahn J W.Nucleation on dislocations[J].Acta Metallurgica,1957,5(3):169-172.
- [15]雍岐龙.钢铁材料中的第二相[M].北京:冶金工业出版社,2006
- [16]Kampa N,Sullivana A,Tomasi R,et al.Modelling of heterogeneous precipitate distribution evolution during friction stir welding process[J].Acta Materialia,2006,54(8):2003-2014.
- [17]Robson J D.Modelling the overlap of nucleation,growth and coarsening during precipitation[J].Acta Materialia,2004,52(15):4669-4672.
- [18]曹建春,雍岐龙,刘清友,等.含铌钼钢中微合金碳氮化物沉淀析出及其强化机制[J].材料热处理学报,2006,27(5):51-55.CAO Jian-chun,YONG Qi-long,LIU Qing-you,et al.Microalloy carbonitride precipitation in Ni-Mo steel and the strengthening mechanism[J].Transactions of Materials and Heat Treatment,2006,27(5):51-55.
- [19]Gladman T.Precipitation hardening in metals[J].Materials Science and Technology,1999,15(1):30-36.
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