Cd对AM50-Y-0.6Sb镁合金组织与腐蚀性能的影响Effects of Cd addition on microstructure and corrosion resistance of AM50-Y-0.6Sb magnesium alloy
刘子利,周桂斌,刘希琴,朱晓春
摘要(Abstract):
研究了合金元素Cd含量对AM50-Y-0.6Sb镁合金的显微组织和腐蚀性能的影响。研究表明,AM50-Y-0.6Sb合金组织主要由α-Mg固溶体、β-Mg17Al12相、Al2Y相、YSb相组成。随着Cd含量增加,合金组织逐渐细化,Cd固溶于基体不形成新相,当Cd含量为1%时,晶粒和析出相最为均匀细小分布。合金腐蚀速率和腐蚀电流密度随着Cd的增加而降低,而自腐蚀电位正移。当Cd含量为1%时,合金耐蚀性最佳,腐蚀速率仅有1.07 mg.cm-2.d-1,比未添加Cd合金降低了42.5%。
关键词(KeyWords): AM50-Y-0.6Sb;Cd;显微组织;腐蚀性能
基金项目(Foundation): 江苏省自然科学基金(BK2009577);; 江苏省科技支撑计划项目(BE2010103)
作者(Author): 刘子利,周桂斌,刘希琴,朱晓春
DOI: 10.13289/j.issn.1009-6264.2013.01.014
参考文献(References):
- [1]黄伟九,林强,郭源君,等.热处理对AS41镁合金显微组织及摩擦学性能的影响[J].材料热处理学报,2010,31(9):89-93.Huang Wei-jiu,Lin Qiang,Guo Yuan-jun,et al.Effects of heat treatment on microstructure and tribological properties of AS41 magnesium alloy[J].Transactions of Materials and Heat Treatment,2010,31(9):89-93.
- [2]Liao L H,Zhang X Q,Wang H W,et al.Influence of Sb on damping capacity and mechanical properties of Mg2Si/Mg-9Al composite materials[J].Journal of Alloys and Compounds,2007,430(1-2):292-296.
- [3]Liu H B,Gong N N,Pang L,et al.Microstructure and mechanical properties of as-cast AZ31 with the addition of Sb[J].Materials Science andEngineering A,2008,397(1-2):254-259.
- [4]Liu W J,Cao F H,Chang L R,et al.Effect of rare earth element Ce and La on corrosion behavior of AM60 magnesium alloy[J].CorrosionScience,2009,51(5):1334-1343.
- [5]Nam N D,Kim J G,Shinb K S,et al.The effect of rare earth additions on the electrochemical properties of Mg-5Al-based alloys[J].ScriptaMaterialia,2010,63(6):625-628.
- [6]Tian X,Wang L M,Wang J L,et al.The microstructure and mechanical properties of Mg-3Al-3RE alloys[J].Journal of Alloys and Compounds,2008,465(1-2):412-416.
- [7]刘子利,潘青林,温建萍,等.Sb对AE41镁合金组织和性能的影响[J].航空材料学报,2005,25(6):1-4.Liu Zi-li,Pan Qing-lin,Wen Jian-ping,et al.Effects of antimony on microstructure and properties of AE41 magnesium alloy[J].Journal ofAeronautical Materials,2005,25(6):1-4.
- [8]刘子利,陈照峰,刘希琴,等.Sb合金化对AE41镁合金耐热性能的影响[J].材料研究学报,2006,20(2):186-190.Liu Zi-li,Chen Zhao-feng,Liu Xi-qing,et al.Influence of antimony addition on heat resistance of AE41 magnesium alloy[J].Chinese Journal ofMaterials Research,2006,20(2):186-190.
- [9]Li J Q,Dong X P,Fan Z T,et al.Effects of Ce and Sb on the microstructure and properties of AZ91D magnesium alloy prepared by the EPC process[J].Rare Metals,2008,27(1):41-45.
- [10]刘子利,周桂斌,刘希琴,等.Sb对AM50-Y镁合金耐蚀性能的影响[J].材料研究学报,2011,25(5):527-533.Liu Zi-li,Zhou Gui-bin,Liu Xi-qin,et al.Effects of Sb addition on corrosion resistance of AM50-Y magnesium alloy[J].Chinese Journal ofMaterials Research,2011,25(5):527-533.
- [11]田学锋,樊自田,黄乃瑜.基于消失模铸造AZ91+x%Cd+y%M M镁合金的研制[J].铸造,2009,58(1):28-31.Tian Xue-feng,Fan Zi-tian,Huang Nai-yu.Development of AZ91+X%Cd+Y%MM magnesium alloy prepared by lost foam casting[J].Foundry,2009,58(1):28-31.
- [12]虞觉奇,易文质,等.二元合金状态图集[M].上海:上海科学技术出版社,1987.
- [13]黄建中,左禹.材料的耐蚀性和腐蚀数据[M].北京:化学工业出版社,2002.
- [14]杨洁,易丹青,邓姝皓,等.微量Ce对AZ91镁合金微观组织及耐蚀性的影响[J].中国腐蚀与防护学报,2008,28(4):205-209.Yang Jie,Yi Dan-qing,Deng Shu-hao,et al.Effect of trace Ce on the microstructure and corrosion resistance of magnesium alloy[J].Journal ofChinese Society for Corrosion and Protection,2008,28(4):205-209.
- [15]龚敏,余祖孝,陈琳.金属腐蚀理论及腐蚀控制[M].北京:化学工业出版社,2009.
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