镍铜铁氧体纳米粉的磁性与介电性能Magnetic and dielectric properties of nickel copper Ferrite nano powder
张变芳,沈英明,张承臣,史严
摘要(Abstract):
用溶胶-凝胶制备了系列Ni_(0.5)Cu_(0.5)Fe_2O_4铁氧体微粉。采用扫描电子显微镜、X射线衍射仪、振动样品磁强计和网络矢量分析仪对粉末的形貌、结构、磁性以及介电性能进行了表征。结构表明,反应温度为40℃,前驱体在1000℃煅烧转变成纯尖晶石结构。三粉末样品在室温和低温都具有铁磁特性,而且出现交换偏置效应。纯尖晶石结构样品3的电磁损耗角正切值tanδ在2~6.5 GHz范围内随频率的增大而增大,以后逐渐减小。
关键词(KeyWords): 铁氧体;交换偏置效应;介电性能
基金项目(Foundation): 国家杰出青年基金(50625518);; 河北省自然科学基金(A2014210025);; 河北省教育厅重点课题(ZD20131012)
作者(Author): 张变芳,沈英明,张承臣,史严
DOI: 10.13289/j.issn.1009-6264.2016.10.003
参考文献(References):
- [1]Tsai Wen-chou,Liou Ying-hung,Liou Yi-cheng.Microwave dielectric properties of Mg Al2O4-Co Al2O4spinel compounds prepared by reactionsintering process[J].Materials Science and Engineering B,2012,177:1133-1137.
- [2]Bhowmik R N,Panneer Muthuselvam I.Dielectric properties and signature of multi-ferroelectricity in Co Fe2O4:A structurally single phased and biphased spinel oxide[J].Journal of Alloys and Compounds,2014,589:247-257.
- [3]Padmaraj O,Venkateswarlu M,Satyanarayana N.Structural,electrical and dielectric properties of spinel type Mg Al2O4nanocrystalline ceramic particles synthesized by the gel-combustion method[J].Science Direct,2015,14:3178-3185.
- [4]Dinesh Varshney,Kavita Verma.Substitutional effect on structural and dielectric properties of Ni1-xAxFe2O4(A=Mg,Zn)mixed spinel ferrites[J].Materials Chemistry and Physics,2013,140:412-418.
- [5]CHEN Chin-wen.Magnetism and Metallurgy of Soft Magnetic Materials[M].Amsterdam:North-Holland Publishing Company,1977:171.
- [6]Deepak Venkateshvaran,Matthias Althammer,Andrea Nielsen,et al.Epitaxial ZnxFe3-xO4thin films:A spintronic material with tunable electrical and magnetic properties[J].Phys Rev B,2009,79:897-899.
- [7]吴知方,黄文旵,周萘,等.磁热效应的铁钙磷酸盐生物微晶玻璃研制[J].建筑材料学报,2001,4(2):154-158.WU Zhi-fang,HUANG Wen-hai,ZHOU Nai,et al.Preparation and investigation of Ca O-Fe2O3-P2O5bioglass with thermomagnetic effect[J].Journal of Building Materials,2001,4(2):154-158.
- [8]刁春丽,娄广辉.铁氧体磁性材料的研究现状与展望[J].山东陶瓷,2006,29(1):18-21.DIAO Chun-li,LOU Guang-hui.The research status and prospect of ferrite magnetic materials[J].Shandong Ceramics,2006,29(1):18-21.
- [9]张变芳,沈英明,郭海勇,等.Ni Mn Zn铁氧体的制备和磁电性能[J].材料热处理学报,2015,36(10):28-31.ZHANG Bian-fang,SHEN Ying-ming,GUO Hai-yong,et al.Preparation and magnetoelectric properties of Ni Mn Zn ferrite[J].Transactions of Materials and Heat Treatment,2015,36(10):28-31.
- [10]Yi J B,Ding J,Feng Y P,et al.Size-dependent magnetism and spin-glass behavior of amorphous Ni O bulk,clusters,and nanocrystals:Experiments and first-principles calculations[J].Physical Review B,2007,76:224-402.
- [11]Makhlouf S A,Al-Attar H,Kodama R H.Particle size and temperature dependence of exchange bias in Ni O nanoparticles[J].Solid State Commun,2008,145:1-4.
- [12]Golosovsky I V,Mirebeau I,Fauth F.Magnetic structure of hematite nanostructured in a porous glass[J].Science Direct,2007,141:178-182.
- [13]罗毅,赵国平,杨海涛,等,单一晶相氧化锰纳米颗粒的交换偏置效应[J].物理学报,2013,62(17):363-367.LUO Yi,ZHAO Guo-ping,YANG Hai-tao,et al.Exchange bias effect in single crystalline phase Mn O nanoparticles[J].Acta Phys Sin,2013,62(17):363-367.
- [14]Yoshida J,Iida S.X-Ray Diffraction study on the low temperature phase of magnetite[J].J Phys Soc Jpn,1977,42(1):230-237.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||