热处理对气相沉积镁锌合金组织和性能的影响Effect of heat treatment on microstructure and properties of Mg-Zn alloy fabricated by vacuum evaporation
闫俞廷,牛立斌,龙裕轩,王晓刚,高冲
摘要(Abstract):
以工业级的粗镁和粗锌为原料,通过分别蒸发—混合—冷凝的方法得到合金试样,并分别对合金试样进行T4(340℃固溶处理24 h)、T6(340℃固溶处理24 h+175℃时效处理16 h)热处理。通过X射线衍射、扫描电镜、硬度计和拉伸强度测试仪对冷凝态、T4态以及T6态的显微组织、物相、力学性能以及断口形貌进行分析和表征。结果表明:冷凝态以α-Mg固溶体、MgZn和Mg_7Zn_3构成共晶组织为主,其形态以椭圆形、多角形以及层片状为主,断口为准解理断裂;T4处理后,合金中多角形以及层片状组织消失,而出现了黑色颗粒状组织,物相尺寸变大,韧窝数量增多,伸长率显著提升;T6处理后,合金内出现了树枝相,存在着大量的Mg_7Zn_3,α-Mg固溶体,MgZn,以及少量的MgZn_2,物相尺寸变小,断口内韧窝数量减少,撕裂棱数量增多,抗拉强度、硬度均有大幅度提升。
关键词(KeyWords): Mg-Zn合金;气相合金化;热处理;显微组织;力学性能
基金项目(Foundation): 陕西省纳米材料重点实验室开放课题(2016KF-01);; 榆林市产学研合作项目(2015CXY-01)
作者(Author): 闫俞廷,牛立斌,龙裕轩,王晓刚,高冲
DOI: 10.13289/j.issn.1009-6264.2018-0180
参考文献(References):
- [1]陈振华,刘俊伟,陈鼎,等.镁合金超塑性的变形机理、研究现状及发展趋势[J].中国有色金属学报,2008,18(2):193-202.CHEN Zhen-hua,LIU Jun-wei,CHEN Ding,et al.Deformation mechanisms,current status and development direction of superplastic magnesium alloys[J].The Chinese Journal of Nonferrous Metals,2008,18(2):193-202.
- [2]Haitani T,Tamura Y,Motegi T,et al.Solubility of iron in pure magnesium and cast structure of Mg-Fe alloy[J].Materials Science Forum,2003,419:697-702.
- [3]Haitani T,Tamura Y,Motegi T,et al.Solubility of iron into pure magnesium and Mg-Al alloy melts[J].Journal Japan Institude of Light Metals,2002,52(12):591-597.
- [4]庞松,吴国华,孙明,等.镁合金熔炼保护气体研究现状与展望[J].铸造,2011,60(3):259-264.PANG Song,WU Guo-hua,SUN Ming,et al.Present status and prospect on protective gas used in melting of magnesium alloy[J].Foundry,2011,60(3):259-264.
- [5]亢海娟,李安全,周伟.镁合金的腐蚀特性与防护措施[J].腐蚀科学与防护技术,2012,24:513-516.KANG Hai-juan,LI An-quan,ZHOU Wei.Corrosion properties and protective measures of magnesium alloy[J].Corrosion Science and Protect Technology,2012,24:513-516.
- [6]Incesu A,Gungor A.Effect of different heat treatment conditions on microstructural and mechanical behaviour of AZ63 magnesium alloy[J].Advances in Materials and Processing Technologies,2016,1(1/2):243-253.
- [7]Yang M,Liu Y H,Liu J A,et al.Effect of T6 heat treatment on corrosion resistance and mec-hanical properties of AM50magnesium alloy[J].Materials Research Innovations,2016,19(sup10):259-264.
- [8]Nie J F.Precipitation and hardening in magnesium alloys[J].Metallurgical and Materials Transactions A,2012,43(11):3891-3939.
- [9]Song Y,Han E H,Shan D,et al.The effect of Zn concentration on the corrosion behavior of Mg-x Zn alloys[J].Corrosion Science,2012,65(65):322-330.
- [10]张金玲,王社斌,卫英慧,等.真空熔炼AZ91镁合金过程中Mg元素的蒸发行为[J].稀有金属材料与工程,2007,36(9):1601-1604.ZHANG Jin-ling,WANG She-bin,WEI Ying-hui,et al.The evaporation of Mg during vacuum smelting of AZ91 magnesium alloy[J].Rare Metal Materials and Engineering,2007,36(9):1601-1604.
- [11]杨重恩.轻金属冶金学[M].北京:冶金工业出版社,1991:285-287.
- [12]钟胜,戴永年.真空蒸发冷凝制备超细锌粉的研究[J].昆明理工大学学报,1998,23(3):47-52.ZHONG Sheng,DAI Yong-nian.The study of ultrafine zinc power produced by vacuum evaporating distillating[J].Journal of Kunming University of Science and Technology,1998,23(3):47-52.
- [13]牛立斌,许臻,彭建洪,等.气相合金化制备镁锌二元合金的研究[J].真空科学与技术学报,2015,35(6):685-688.NIU Li-bin,XU Zhen,PENG Jian-hong,et al.Alloy of Mg-Zn by vacuum evaporation of crude Mg and Zn[J].Chinese Journal of Vacuum Science and Technology,2015,35(6):685-688.
- [14]熊庭辉,罗岚,刘勇,等.Mg-Zn合金的时效处理研究进展[J].材料热处理学报,2017,38(6):1-9.XIONG Ting-hui,LUO Lan,LIU Yong,et al.Research progress on aging treatment of Mg-Zn alloy[J].Transactions of Materials and Heat Treatment,2017,38(6):1-9.
- [15]Mima G,Tanaka Y.The aging characteristics of magnesium-4wt%zinc alloy[J].Materials Transactions Jim,2007,23(2):71-75.
- [16]Tane M,Kimizuka H,Hagihara K,et al.Effects of stacking sequence and short-range ordering of solute atoms on elastic properties of Mg-Zn-Y alloys with long-period stacking ordered stru-ctures[J].Acta Materialia,2015,96:170-188.
- [17]Xu C,Xu S W,Zheng M Y,et al.Microstructures and mechanical properties of high-strength Mg-Gd-Y-Zn-Zr alloy sheets processed by severe hot rolling[J].Journal of Alloys and Compounds,2012,524(524):46-52.
- [18]吴树森,柳玉起,等.材料成型原理[M].北京:机械工业出版社,2008.
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