VW54镁合金挤压线材的微观组织与力学性能Microstructure and mechanical properties of VW54 magnesium alloy extruded wire
车柄潭,吴迪,张承宇,潘文宇,邹航,何长树,李金国
摘要(Abstract):
采用光学显微镜、扫描电镜、显微维氏硬度计和拉伸试验机等研究了铸态VW54镁合金及其挤压态线材及退火态线材的显微组织和力学性能。结果表明:固溶处理使铸态VW54镁合金组织中晶界处分布的Mg_(24)(Gd, Y)_5相全部回溶,仅保留部分GdH_2稀土氢化物;热挤压后,线材发生了动态再结晶(DRX),晶粒尺寸显著细化,形成了以第二相流线为间隔的粗细等轴晶混合的双峰晶粒结构;在300℃低温退火时,第二相流线处会发生二次析出,形成短棒状或点状的第二相;而在400℃和500℃较高温度退火时,流线状分布的第二相会发生不同程度的回溶;挤压态样品具有(0001)//ED的基面织构,经过300℃×2 h和400℃×2 h退火后,再结晶使组织的织构取向趋于随机,而500℃×2 h退火后的合金线材则形成了典型的稀土织构;挤压态样品的屈服强度、抗拉强度和伸长率分别为169 MPa、255 MPa和17.5%,经300℃×0.5 h退火后,分别为148 MPa、253 MPa和20.3%,经400℃×0.5 h退火后,则分别为153 MPa、244 MPa和16.4%。
关键词(KeyWords): VW54镁合金;挤压线材;退火处理;微观组织;力学性能
基金项目(Foundation): 国家自然科学基金(52371037,52171055)
作者(Author): 车柄潭,吴迪,张承宇,潘文宇,邹航,何长树,李金国
DOI: 10.13289/j.issn.1009-6264.2025-0098
参考文献(References):
- [1] Ouyang L,Liu F,Wang H,et al.Magnesium-based hydrogen storage compounds:A review[J].Journal of Alloys and Compounds,2020,832:154865.
- [2] Luo A A,Mishra R K,Powell B R,et al.Magnesium alloy development for automotive applications[J].Materials Science Forum,2012,706/709(1):69-82.
- [3] Joost W J,Krajewski P E.Towards magnesium alloys for high-volume automotive applications[J].Scripta Materialia,2017,128:107-112.
- [4] Hort N,Huang Y D,Fechner D,et al.Magnesium alloys as implant materials-principles of property design for Mg-RE alloys[J].Acta Biomaterialia,2010,6(5):1714-1725.
- [5] 吴国华,陈玉狮,丁文江.镁合金在航空航天领域研究应用现状与展望[J].载人航天,2016,22(3):281-292.WU Guo-hua,CHEN Yu-shi,DING Wen-jiang.Current research,application and future prospect of magnesium alloys in aerospace industry[J].Manned Spaceflight,2016,22(3):281-292.
- [6] 魏振伟,陈皓晖,沈佳萌,等.WE43A镁合金补焊组织及性能研究[J].失效分析与预防,2022,17(5):328-333.WEI Zhen-wei,CHEN Hao-hui,SHEN Jia-meng,et al.Study on the microstructure and properties of repair welding joints in WE43A magnesium alloys[J].Failure Analysis and Prevention,2022,17(5):328-333.
- [7] 王美玲,常海.初始组织对Mg-8Gd-2Y-0.5Zr合金蠕变性能的影响[J].航空材料学报,2022,42(6):65-71.WANG Mei-ling,CHANG Hai.Effect of initial microstructure on creep properties of Mg-8Gd-2Y-0.5Zr alloy[J].Journal of Aeronautical Materials,2022,42(6):65-71.
- [8] 刘倩,单忠德.镁合金在汽车工业中的应用现状与发展趋势[J].铸造技术,2007(12):1668-1671.LIU Qian,SHAN Zhong-de.Application and prospect of magnesium alloys in automotive industry[J].Foundry Technology,2007,28(12):1668-1671.
- [9] Yi H,Wang Q,Cao H.Wire-arc directed energy deposition of magnesium alloys:Microstructure,properties and quality optimization strategies[J].Journal of Materials Research and Technology,2022,20:627-649.
- [10] Motallebi R,Savaedi Z,Mirzadeh H.Post-processing heat treatment of lightweight magnesium alloys fabricated by additive manufacturing:A review[J].Journal of Materials Research and Technology,2022,20:1873-1892.
- [11] Li X,Fang X,Zhang M,et al.Enhanced strength-ductility synergy of magnesium alloy fabricated by ultrasound assisted directed energy deposition[J].Journal of Materials Science & Technology,2024,178:247-261.
- [12] Cao Q,Zeng C,Qi B,et al.Excellent isotropic mechanical properties of directed energy deposited Mg-Gd-Y-Zr alloys via establishing homogeneous equiaxed grains embedded with dispersed nano-precipitation[J].Additive Manufacturing,2023,67:103498.
- [13] 孙明,程广奎,李喜阔,等.Mg-Zn-Y系镁合金的研究现状与展望[J].有色金属材料与工程,2024,45(1):66-77.SUN Ming,CHENG Guang-kui,LI Xi-kuo,et al.Research status and prospect of Mg-Zn-Y magnesium alloys[J].Nonferrous Metal Materials and Engineering,2024,45(1):66-77.
- [14] Xue Z Y,Ren Y J,Luo W B,et al.Microstructure evolution and mechanical properties of a large-sized ingot of Mg-9Gd-3Y-1.5 Zn-0.5 Zr (wt%) alloy after a lower-temperature homogenization treatment[J].International Journal of Minerals,Metallurgy,and Materials,2017,24:271-279.
- [15] Martinho V R,Eriksson O,Bj??rkman T,et al.Realistic first-principles calculations of the magnetocaloric effect:Applications to hcp Gd[J].Materials Research Letters,2022,10(3):156-162.
- [16] 鲍键,李全安,陈晓亚,等.挤压镁合金的研究进展[J].材料导报,2022,36(10):112-123.BAO Jian,LI Quan-an,CHEN Xiao-ya,et al.Research progress on extruded magnesium alloys[J].Materials Reports,2022,36(10):112-123.
- [17] Peng Q,Huang Y,Meng J,et al.Strain induced GdH2 precipitate in Mg-Gd based alloys[J].Intermetallics,2011,19(3):382-389.
- [18] 王尔德.镁合金塑性加工产业技术研究进展[J].精密成形工程,2014,6(6):22-30.WANG Er-de.Recent researches in industrial plasticity processing of magnesium alloy[J].Journal of Netshape Forming Engineering,2014,6(6):22-30.
- [19] Chen M,Zhang H,Wang L,et al.Bimodal grain structure,phase transformation,and mechanical properties of a Mg-Gd-Y-Zn-Zr alloy during hot extrusion[J].Journal of Materials Research and Technology,2024,33:4410-4428.
- [20] Zengin H,Ari S,Turan M E,et al.Evolution of microstructure,mechanical properties,and corrosion resistance of Mg-2.2 Gd-2.2 Zn-0.2 Ca (wt%) alloy by extrusion at various temperatures[J].Materials,2023,16(8):3075.
- [21] Li L,Wu J,Wu Y Z,et al.Effect of static annealing on microstructure and texture in extruded Mg-Gd-Y-Zr alloy[J].Rare Metal Materials and Engineering,2016,45(9):2263-2268.
- [22] 谢鑫,唐建国,石洪吉,等.挤压温度对Mg-5.3Gd-2.6Y-1.1Nd-0.3Zr合金的力学性能和耐生物腐蚀性能的影响[J].材料工程,2019,47(10):76-81.XIE Xin,TANG Jian-guo,SHI Hong-ji,et al.Effect of extrusion temperature on mechanical properties and biological corrosion resistance of Mg-5.3Gd-2.6Y-1.1Nd-0.3Zr alloy[J].Journal of Materials Engineering,2019,47(10):76-81.
- [23] Zhang G,Meng Y,Yan F,et al.Microstructure and texture evolution of Mg-RE-Zn alloy prepared by repetitive upsetting-extrusion under different decreasing temperature degrees[J].Journal of Alloys and Compounds,2020,815:152452.
- [24] Yan L,Zhang Z,Li G,et al.Evolution of the microstructure,texture and mechanical properties of ZK60 alloy during processing by rotating shear extrusion[J].Journal of Alloys and Compounds,2021,877:160229.
- [25] Meng Y,Yu J,Liu K,et al.The evolution of long-period stacking ordered phase and its effect on dynamic recrystallization in Mg-Gd-Y-Zn-Zr alloy processed by repetitive upsetting-extrusion[J].Journal of Alloys and Compounds,2020,828:154454.
- [26] 崔晓明,王争光,于智磊,等.Mg-8.07Al-0.53Zn-1.36Nd轧制镁合金退火过程中的静态沉淀、再结晶及织构演变[J].稀有金属材料与工程,2022,51(4):1413-1419.CUI Xiao-ming,WANG Zheng-guang,YU Zhi-lei,et al.Static precipitation,recrystallization and texture evolution of Mg-8.07Al-0.53Zn-1.36Nd rolled magnesium alloy during annealing[J].Rare Metal Materials and Engineering,2022,51(4):1413-1419.
- [27] 杨庆波.高强耐热Mg-Gd-Y合金的微观组织和力学性能研究[D].沈阳:沈阳大学,2016.YANG Qing-bo.Microstructure and mechanical properties of a high-strength heat-resistant Mg-Gd-Y alloy[D].Shenyang:Shenyang University of Technology,2016.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||