Ag-Cu-Ti钎焊金刚石/铜复合材料的组织和性能Microstructure and mechanical properties of diamond/Cu composite joint using Ag-Cu-Ti active brazing alloy
吴茂,曹车正,王越,陈晓玮,何新波,曲选辉
摘要(Abstract):
采用97(72Ag-28Cu)-3Ti活性钎料钎焊了Diamond/Cu复合材料和Al2O3陶瓷,研究了主要钎焊条件如钎焊温度和保温时间对接头强度的影响。结果表明,钎焊过程中Ti元素易聚集在金刚石颗粒周围并形成TiC化合物层。TiC化合物的形貌与Diamond/Cu钎焊接头剪切强度有密切关系,金刚石表面生长适当厚度的TiC化合物层能增强钎焊接头的剪切强度,但如果TiC为颗粒状或TiC化合物层生长过厚,将削弱钎焊接头的剪切强度。钎焊接头的最大剪切强度可达117 MPa。
关键词(KeyWords): diamond/Cu复合材料;Ag-Cu-Ti钎料;活性钎焊;剪切强度
基金项目(Foundation): 国家自然科学基金(51204016);; 高等学校博士学科点专项科研基金(20120006120011);; 中央高校基本科研业务费专项资金(FRF-TP-12-154A);; 国家博士后科学基金(11175020)
作者(Author): 吴茂,曹车正,王越,陈晓玮,何新波,曲选辉
DOI: 10.13289/j.issn.1009-6264.2013.03.029
参考文献(References):
- [1]Zweben C.Thermal materials solve power electronics challenges[J].Power Electronics Technology,2006,32(2):40-47.
- [2]Nogales S,Bhm H J.Modeling of the thermal conductivity and thermomechanical behavior of diamond reinforced composites[J].InternationalJournal of Engineering Science,2008,46(6):606-619.
- [3]童震松,沈卓身.金属封装材料的现状及发展[J].电子封装,2005,5(3):6-15.TONG Zhen-song,SHEN Zhuo-shen.Status and development of materials for metal packaging[J].Electronics&Packaging,2005,5(3):6-15.
- [4]Wu M,He X B,Rafi-ud-din,et al.Effect of various Ni plating layers and aging on microstructure and shear strength of Sn-2.5Ag-2.0Ni solder joint[J].Surface and Coatings Technology,2009,203(20-21):3011-3018.
- [5]Wu M,He X B,Rafi-ud-din,et al.Effect of P and aging on microstructure and shear strength of Sn-2.5Ag-2.0Ni/Ni(P)solder joints[J].MaterialsChemistry and Physics,2010,121(1-2):259-266.
- [6]Wu M,Qu X H,He X B,et al.Interfacial reactions between Sn-2.5Ag-2.0Ni solder and electroless Ni(P)on SiCp/Al composites[J].Transactionsof Nonferrous Metals Society of China,2010,20(6):958-965.
- [7]Ren S B,He X B,Qu X H,Islam S H,et al.Effect of calcinations process on the properties and microstructure of SiC perform and corresponding SiCp/Al composites synthesis by pressureless infiltration[J].Material Science and Engineering A,2007,444(1-2):104-112.
- [8]Yoshida K,Morigami H.Thermal properties of diamond-copper composite material[J].Microelectronics Reliability,2004,44(2):303-308.
- [9]Ekimov E A,Suetin N V,Popovich A F,et al.Thermal conductivity of diamond composites sintered under high pressures[J].Diamond and RelatedMaterials,2008,17(4-5):838-843.
- [10]Yasuyukii A.Thermal conductivity of copper composites dispersed with diamond particles prepared by spark plasma sintering[J].The27th JapanSymposium on Thermo-physical Properties.Kyoto,2006:328-335.
- [11]Tavangar R,Molina J M,Weber L.Assessing predictive schemes for thermal conductivity against diamond-reinforced silver matrix composites atintermediate phase contrast[J].Scripta Materialia,2007,56(5):357-360.
- [12]Shao W Z,Ivanov V V,Zhen L,et al.A study on graphitization of diamond in copper-diamond composite materials[J].Materials Letters,2004,58(1-2):146-149.
- [13]沈卓身,贾松良.电子封装材料与工艺[M].化学工业出版社,北京,2006:85-141.
- [14]Kozlova O,Braccini M,Voytovych R,et al.Brazing copper to alumina using reactive CuAgTi alloys[J].Acta Materialia,2010,58(4):1252-1260.
- [15]卢金斌,徐九华.Ag-Cu-Ti钎料钎焊金刚石的界面微观组织分析[J].焊接学报,2007,28(8):29-32.LU Jin-bin,XU Jiu-hua.Microstructure of interface between Ag-Cu-Ti brazing filler metal and diamond[J].Transactions of the China WeldingInstitution,2007,28(8):29-32.
- [16]Fenglian Sun,Jicai Feng,Dan Li.Bonding of CVD diamond thick films using an Ag-Cu-Ti brazing alloy[J].Journal of Materials ProcessingTechnology,2001,115(3):333-337.
- [17]Xiong Jinhui,Huang Jihua,Zhang Hua,et al.Brazing of carbon fiber reinforced SiC composite and TC4using Ag-Cu-Ti active brazing alloy[J].Materials Science and Engineering:A,2010,527(4-5):1096-1101.
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