再结晶退火对轧制态TiZrNbB合金显微组织及力学性能的影响Effect of recrystallization annealing on microstructure and mechanical properties of rolled TiZrNbB alloy
炊鹏飞,李文刚,程尊鹏,李春梅,郭婉莹,景然,李江华
摘要(Abstract):
通过真空熔炼技术制备了(Ti_(50)Zr_(50))_(89.7)Nb_(10)B_(0.3)(TZNB0.3,at%)合金,对轧制后的合金分别在550、600和650℃进行再结晶退火处理。结果表明:退火后,TZNB0.3合金的相结构主要为β和TiB相,在550℃退火时,仅部分区域发生再结晶,在600和650℃退火时,再结晶过程完成,再结晶区域为大角度晶界,轧制织构和高密度位错被消除,合金的晶粒轻微长大。随着退火温度的升高,合金的强度逐渐降低,伸长率先增加后减小,在600℃退火时,合金的屈服强度为752 MPa,抗拉强度为804 MPa,伸长率为13.3%,弹性模量为65 GPa,表现出良好的综合力学性能。
关键词(KeyWords): TiZrNbB合金;再结晶退火;显微组织;力学性能
基金项目(Foundation): 国家自然科学基金(51701111);; 陕西省自然科学基础研究计划项目(2018JQ5170);; 陕西省教育厅科研计划项目(19JK0184,21JK0560)
作者(Author): 炊鹏飞,李文刚,程尊鹏,李春梅,郭婉莹,景然,李江华
DOI: 10.13289/j.issn.1009-6264.2023-0191
参考文献(References):
- [1] Hu S,Li T,Su Z,et al.Research on suitable strength,elastic modulus and abrasion resistance of Ti-Zr-Nb medium entropy alloys (MEAs) for implant adaptation[J].Intermetallics,2022,140:107401.
- [2] Hu S,Li T,Su Z,et al.A novel TiZrNb medium entropy alloy (MEA) with appropriate elastic modulus for biocompatible materials[J].Materials Science and Engineering B,2021,270:115226.
- [3] Ji P F,Li B,Chen B H,et al.Effect of Nb addition on the stability and biological corrosion resistance of Ti-Zr alloy passivation films[J].Corrosion Science,2020,170:108696.
- [4] Kaur M,Singh K.Review on titanium and titanium based alloys as biomaterials for orthopaedic applications[J].Materials Science and Engineering C,2019,102:844-862.
- [5] Xia C Q,Jiang X J,Wang X Y,et al.Structure and mechanical properties of as-cast (ZrTi)100-xBx alloys[J].Journal of Alloys and Compounds,2015,637:90-97.
- [6] Tamirisakandala S,Bhat R B,Tiley J S,et al.Processing,microstructure,and properties of β titanium alloys modified with boron[J].Journal of Materials Engineering and Performance,2005,14:741-746.
- [7] 白雪,金云学,卢璇,等.增强相含量对原位自生(TiC+TiB)/Ti6Al4V复合材料摩擦磨损性能的影响[J].材料热处理学报,2017,38(5):30-35.BAI Xue,JIN Yun-xue,LU Xuan,et al.Influence of reinforcement content on friction and wear properties of in-situ (TiC+TiB)/Ti6Al4V composites[J].Transactions of Materials and Heat Treatment,2017,38(5):30-35.
- [8] 吴倩,景然,刘以柔,等.TiB/Ti 基复合材料的微观组织和力学性能[J].材料热处理学报,2022,43(6):12-18.WU Qian,JING Ran,LIU Yi-rou,et al.Microstructure and mechanical properties of TiB/Ti matrix composites[J].Transactions of Materials and Heat Treatment,2022,43(6):12-18.
- [9] 向柳,辛社伟,毛小南,等.Ti-15Mo 合金的再结晶行为及动力学[J].材料热处理学报,2020,41(10):137-142.XIANG Liu,XIN She-wei,MAO Xiao-nan,et al.Recrystallization behavior and kinetics of Ti-15Mo alloy[J].Transactions of Materials and Heat Treatment,2020,41(10):137-142.
- [10] 庞嘉泰,李传维,郭正洪,等.冷轧及再结晶退火对 TiNbHf 难熔中熵合金力学性能的影响[J].材料热处理学报,2022,43(6):79-85.PANG Jia-tai,LI Chuan-wei,GUO Zheng-hong,et al.Effect of cold rolling and recrystallization annealing on mechanical properties of TiNbHf refractory medium-entropy alloy[J].Transactions of Materials and Heat Treatment,2022,43(6):79-85.
- [11] Hao Y L,Yang R,Niinomi M,et al.Young’s modulus and mechanical properties of Ti-29Nb-13Ta-4.6Zr in relation to α″ martensite[J].Metallurgical and Materials Transactions A,2002,33:3137-3144.
- [12] Vajpai S K,Sharma B,Ota M,et al.Effect of cold rolling and heat-treatment on the microstructure and mechanical properties of β-titanium Ti-25Nb-25Zr alloy[J].Materials Science and Engineering A,2018,736:323-328.
- [13] Xia C Q,Zhang X,Liu S G,et al.Thermo-mechanical processing,microstructure and mechanical properties of TiZrB alloy[J].Materials Science and Engineering A,2018,712:350-357.
- [14] Bulanova M,Firstov S,Gornaya I,et al.The melting diagram of the Ti-corner of the Ti-Zr-Si system and mechanical properties of as-cast compositions[J].Journal of Alloys and Compounds,2004,384:106-114.
- [15] Zhang B,Tang Y,Li S,et al.Effect of Ti on the structure and mechanical properties of TixZr2.5-xTa alloys[J].Entropy,2021,23:1632.
- [16] Majumdar P.Microstructural evaluation of boron free and boron containing heat-treated Ti-35Nb-7.2Zr-5.7Ta alloy[J].Microscopy and Microanalysis,2012,18:295-303.
- [17] Liu B,Raabe D,Eisenlohr P,et al.Dislocation interactions and low-angle grain boundary strengthening[J] Acta Materialia,2011,59:7125-7134.
- [18] Shamsujjoha M.Evolution of microstructures,dislocation density and arrangement during deformation of low carbon lath martensitic steels[J].Materials Science and Engineering A,2020,776:139039.
- [19] Shamsujjoha M,Agnew S R,Fitz-Gerald,J M,et al.High strength and ductility of additively manufactured 316L stainless steel explained[J].Metallurgical and Materials Transactions A,2018,49:3011-3027.
- [20] Zribi Z,Ktari H H,Herbst F,et al.EBSD,XRD and SRS characterization of a casting Al-7wt% Si alloy processed by equal channel angular extrusion:Dislocation density evaluation[J].Materials Characterization,2019,153:190-198.
- [21] Oliveira N T C,Aleixo G,Caram R,et al.Development of Ti-Mo alloys for biomedical applications:microstructure and electrochemical characterization[J] Materials Science and Engineering A,2007,452-453:727-731.
- [22] Kurode D,Niinomi M,Morinaga M,et al.Design and mechanical properties of new b type titanium alloys for implant materials[J].Materials Science and Engineering A,1998,243:244-249.
- [23] Helth A,Pilz S,Kirsten T,et al.Effect of thermomechanical processing on the mechanical biofunctionality of a low modulus Ti-40Nb alloy[J].Journal of the Mechanical Behavior of Biomedical Materials,2017,65:137-150.
- [24] Zhang Y,Kent D,Wang G,et al.An investigation of the mechanical behaviour of fine tubes fabricated from a Ti-25Nb-3Mo-3Zr-2Sn alloy[J].Materials & Design,2015,85:256-265.
- [25] Li Q,Niinomi M,Hieda J,et al.Deformation-induced ω phase in modified Ti-29Nb-13Ta-4.6Zr alloy by Cr addition[J].Acta Biomaterialia,2013,9:8027-8035.
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