时效温度对GX40CrNiSi25-12奥氏体耐热钢析出相的影响Effect of aging temperature on precipitates of GX40CrNiSi25-12 austenite heat resistant steel
李杰,胡建文,陆子彤
摘要(Abstract):
为了研究高温时效对GX40CrNiSi25-12奥氏体耐热铸钢析出相的影响,采用JMatPro软件模拟其在不同温度下的平衡相图和析出相随温度的变化,通过光学显微镜、扫描电镜和能谱分析等研究了不同温度时效处理对试验钢的析出相的形态、大小、析出位置及硬度的影响。结果表明:850℃时效24 h后,大量细小颗粒状的M_(23)C_6碳化物在基体奥氏体晶粒内析出,在奥氏体晶粒内还发现有少量细针状σ相析出,同时在枝晶处出现密集分布的块状σ相,试验钢的硬度显著升高,达到最大值;950℃时效24 h后,晶内析出相减少,颗粒状M_(23)C_6碳化物偏聚在枝晶附近析出,且出现集聚和长大,导致试验钢的硬度显著下降;1050℃时效24 h后,枝晶骨架中的一次碳化物基本溶入基体中,在晶界处分散的颗粒状M_(23)C_6相呈链状分布,无σ相存在。
关键词(KeyWords): 奥氏体耐热铸钢;高温时效;析出相;热力学模拟;微观组织
基金项目(Foundation):
作者(Author): 李杰,胡建文,陆子彤
DOI: 10.13289/j.issn.1009-6264.2021-0310
参考文献(References):
- [1] 安笑频.双相不锈钢热变形过程晶粒细化的研究[D].邯郸:河北工程大学,2018.AN Xiao-pin.Research on grain refinement during hot deformation of duplex stainless steel[D].Handan:Hebei University of Engineering,2018.
- [2] 刘永长,郭倩颖,李冲,等.Inconel718高温合金中析出相演变研究进展[J].金属学报,2016,52(10):1259-1266.LIU Yong-chang,GUO Qian-ying,LI Chong,et al.Recent progress on evolution of precipitates in Inconel 718 superalloy[J].Acta Metallurgica Sinica,2016,52(10):1259-1266.
- [3] 胡国栋,王培,李殿中,等.新型25Cr-20Ni奥氏体耐热不锈钢750 ℃持久实验过程中析出相演变[J].金属学报,2018,54(11):1705-1714.HU Guo-dong,WANG Pei,LI Dian-zhong,et al.Precipitate evolution in a modified 25Cr-20Ni austenitic heat resistant stainless steel during creep rupture test at 750 ℃[J].Acta Metallurgica Sinica,2018,54(11):1705-1714.
- [4] 杜华云,戴鑫宇,卫英慧,等.新型奥氏体耐热钢C-HRA-5原位拉伸断裂机理[J].钢铁,2020,55(11):118-125.DU Hua-yun,DAI Xin-yu,WEI Ying-hui,et al.In-situ tensile fracture mechanism of new type austenitic heat-resistant steel C-HRA-5[J].Iron and Steel,2020,55(11):118-125.
- [5] 隋永菊,金鑫.310S奥氏体耐热不锈钢高温氧化性能的研究[J].热处理技术与装备,2015,36(6):21-24.SUI Yong-ju,JIN Xin.Study on high temperature oxidation property of 310S austenitic heat resistance stainless steel[J].Heat Treatment Technology and Equipment,2015,36(6):21-24.
- [6] 吴林才,安立聪,杨弋涛.一种节镍经济型双相耐热铸钢的高温氧化[J].材料研究学报,2015,29(12):941-947.WU Lin-cai,AN Li-cong,YANG Yi-tao.High temperature oxidation of a low nickel austenitic heat resistant steel[J].Chinese Journal of Materials Research,2015,29(12):941-947.
- [7] 范晓明,程小奇,游程超,等.变质处理对奥氏体耐热不锈钢组织与性能的影响[J].特种铸造及有色合金,2018,38(4):372-374.FAN Xiao-ming,CHENG Xiao-qi,YOU Cheng-chao,et al.Effects of modification on microstructure and mechanical properties of austenitic heat resistant stainless steels[J].Special Casting and Nonferrous Alloys,2018,38(4):372-374.
- [8] 胡洋,董治中.超高氮马氏体耐热铸钢的高温相解析[J].天津理工大学学报,2019,35(6):1-4.HU Yang,DONG Zhi-zhong.High temperature phase analysis of ultra-high nitrogen martensite heat resistant cast steel[J].Journal of Tianjin University of Technology,2019,35(6):1-4.
- [9] 於晓兰.基于计算机仿真的合金元素对工具钢碳化物析出行为的影响[J].热加工工艺,2015,44(10):116-119.YU Xiao-lan.Effect of alloy elements on precipitation behavior of carbides in high-carbon alloy tool steels based on computer simulation[J].Hot Working Technology,2015,44(10):116-119.
- [10] 王忠民,张忠诚,秦森,等.Zr、Y和Ba-Ca变质对00Cr25Ni7Mo4N钢组织与性能的影响[J].特种铸造及有色合金,2011,31(2):113-115.WANG Zhong-min,ZHANG Zhong-cheng,QIN Sen,et al.Effects of Zr,Y and Ba-Ca modifier on the microstructure and properties of 00Cr25Ni7Mo4N steel[J].Special Casting and Nonferrous Alloys,2011,31(2):113-115.
- [11] 于鸿垚,董建新,谢锡善.新型奥氏体耐热钢HR3C的研究进展[J].世界钢铁,2010,10(2):42-49.YU Hong-yao,DONG Jian-xin,XIE Xi-shan.Research development of new austenitic heat-resistant steel HR3C[J].World Iron and Steel,2010,10(2):42-49.
- [12] Zhou Y H,Liu Y C,Zhou X S,et al.Precipitation and hot deformation behavior of austenitic heat-resistant steels:A review[J].Journal of Materials Science and Technology,2017,33(12):1448-1456.
- [13] 陈启超,游程超,范晓明,等.GX40CrNiSi25-20奥氏体不锈钢的高温氧化性能研究[J].中国铸造装备与技术,2019,54(2):9-14.CHEN Qi-chao,YOU Cheng-chao,FAN Xiao-ming,et al.Study on high temperature oxidation properties of GX40CrNiSi25-20 austenitic stainless steel[J].China Foundry Machinery and Technology,2019,54(2):9-14.
- [14] 乔芝郁,郝士明.相图计算研究的进展[J].材料与冶金学报,2005(2):83-90.QIAO Zhi-yu,HAO Shi-ming.New progress of CALPHAD approach[J].Journal of Materials and Metallurgy,2005(2):83-90.
- [15] Saunders N,Cahn R W,McLean M,et al.Phase diagram calculations for high-temperature structural materials[and discussion][J].Philosophical Transactions.Physical Sciences and Engineering,1995,351(1697):543-561.
- [16] Blair M.Cast Stainless Steels,ASM Handbook,vol.1[M].ASM International Handbook Committee,1990.
- [17] Lopez N,Cid M,Puiggali M.Influence of σ-phase on mechanical properties and corrosion resistance of duplex stainless steels[J].Corrosion Science,1999,41(8):1615-1631.
- [18] Kobayashi D Y.Efeito da fase sigma na resistência à corros?o por pite de a?os inoxidáveis duplex[D].Universidade de S?o Paulo,1995.
- [19] Golański G,Zieliński A,Sroka M,et al.The effect of service on microstructure and mechanical properties of HR3C heat-resistant austenitic stainless steel[J].Materials,2020,13(6):1297.
- [20] Hsieh C C,Lin D Y,Wu W.Precipitation behavior of σ phase in 19Cr-9Ni-2Mn and 18Cr-0.75Si stainless steels hot-rolled at 800 ℃ with various reduction ratios[J].Materials Science and Engineering A,2007,467(1-2):181-189.
- [21] Zucato I,Margarete C M,Machado I F,et al.Microstructural characterization and the effect of phase transformations on toughness of the UNS S31803 duplex stainless steel aged treated at 850 ℃[J].Materials Research,2002,5(3):385-389.
- [22] Jaworski A,Krawczyk ?,Kubiak K.Turbine housing failure due to sigma phase precipitation and embrittlement of niobium-stabilized austenitic steel casting[J].Journal of Materials Engineering and Performance,2020,29(3):1535-1543.
- [23] Ezuber H,El-Houd A,El-Shawesh F.Effects of sigma phase precipitation on seawater pitting of duplex stainless steel[J].Desalination,2006,207(1):268-275.
- [24] 蔡玉林,郑运荣.高温合金的金相研究[M].北京:国防工业出版社,1986.
- [25] 王兆民,王硕,申雷,等.22Cr-25Ni奥氏体耐热钢高温时效的组织及性能[J].金属热处理,2020,45(3):46-49.WANG Zhao-min,WANG Shuo,SHEN Lei,et al.Mechanical and properties of austenitic heat resistant steel 22Cr-25Ni after high temperature aging[J].Heat Treatment of Metals,2020,45(3):46-49.
- [26] 郭倩颖,李彦默,陈斌,等.高温时效处理对S31042耐热钢组织和蠕变性能的影响[J].金属学报,2021,57(1):82-94.GUO Qian-ying,LI Yan-mo,CHEN Bin,et al.Effect of high-temperature ageing on microstructure and creep properties of S31042 heat-resistant steel[J].Acta Metallurgica Sinica,2021,57(1):82-94.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||