H13热作模具钢微弧氧化复合陶瓷层的组织和性能Structure and properties of composite ceramic coatings on H13 steel by hot dipping aluminum and plasma electrolytic oxidation
赵建华,赵国华,李涛,刘鑫,李佳丽,韩二静
摘要(Abstract):
通过热浸镀铝/微弧氧化复合工艺对H13模具钢进行表面改性以提高模具表面质量。在热浸镀铝过程中,将H13钢基体浸入710℃纯铝液6 min,得到了以Fe2Al5为主中间合金层,使得镀层与基体紧密结合。经过微弧氧化处理后,镀铝试样表面铝层转化为氧化铝陶瓷,主要由α-Al2O3和γ-Al2O3相组成。用带有能谱分析装置(EDX)的扫描电镜(SEM)、X射线衍射(XRD)分析了膜层的形貌、成分和相组成。微弧氧化陶瓷层主要由Al、O、Si元素组成,其中O、Si主要来源于硅酸盐电解液。
关键词(KeyWords): 热浸镀铝;微弧氧化;压铸模具;表面改性
基金项目(Foundation): 重庆市科技攻关计划项目(2008AA4029)
作者(Author): 赵建华,赵国华,李涛,刘鑫,李佳丽,韩二静
DOI: 10.13289/j.issn.1009-6264.2012.03.026
参考文献(References):
- [1]Salas O,Kearns K,Carrera S,et al.Tribological behavior of candidate coatings for Al die casting dies[J].Surface and Coatings Technology,2003,172(2-3):117-127.
- [2]Chen Z W.Formation and progression of die soldering during high pressure die casting[J].Materials Science and Engineering A,2005,397:356-369.
- [3]Shih T S,Tu S H.Interaction of steel with pure Al,Al-7Si and A356 alloy[J].Materials Science and Engineering A,2007,455:349-365.
- [4]Nazari K A,Shabestari S G.Effect of micro alloying elements on the interfacial reactions between molten aluminum alloy and tool steel[J].Journal ofAlloys and Compounds,2009,478:523-530.
- [5]Tentardini E K,Kunrath A O,et al.Soldering mechanisms in materials and coatings for aluminum die casting[J].Surface and Coatings Technology,2008,202:3764-3711.
- [6]Hou X X,Yang H,Zhao Y,et al.Effect of Si on the interaction between die casting die and aluminum alloy[J].Materials Letters,2004,58:3424-3427.
- [7]Karpushenkov S A,Shchukin G L,Belanovich A L,et al.Plasma electrolytic ceramic-like aluminum oxide coatings on iron[J].Journal of AppliedElectrochemistry,2010,40:365-374.
- [8]Wang Y L,Jiang Z H,Yao Z P.Preparation and properties of ceramic coating on Q235 carbon steel by plasma electrolytic oxidation[J].CurrentApplied Physics,2009,9:1067-1071.
- [9]Wang D Q,Shi Z Y,Zou L J.A liquid aluminum corrosion resistance surface on steel substrate[J].Journal of Applied Surface Science,2003,214:304-311.
- [10]赵建华,马薇,张文达.微弧氧化陶瓷层对铝基快速模具材料性能的影响[J].材料工程,2010(3):42-45.ZHAO Jian-hua,MA Wei,ZHANG Wen-da.Influence of micro-arc oxidation ceramic coating on mould material properties of A1 alloy for rapid tooling[J].Journal of Materials Engineering,2010(3):42-45.
- [11]Xue W B,Deng Z D,Lai Y C,Chen R Y.Analysis of phase distribution for ceramic coatings formed by microarc oxidation on aluminum alloy[J].Journal of American Ceramic Society,1998,81(5):1365-1368.
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