铸态GWK镁合金的腐蚀行为及其与组织的关联性Corrosion behavior of as-cast GWK magnesium alloy and its relationship with microstructure
窦志伟,郭锋,康裕,闫晨曦,蔡会生
摘要(Abstract):
分析了Gd、Y元素含量对Mg-Gd-Y-Zr(GWK)合金铸态微观组织和腐蚀性能的影响,并研究了合金的腐蚀行为及其与组织的关联性。结果表明:合金的组织主要由α-Mg固溶体和位于晶界的Mg_5(Gd, Y)化合物组成,α-Mg包括晶内初生α-Mg和晶界附近的共晶α-Mg两部分,共晶α-Mg中含有更高含量的Gd、Y元素。Mg_5(Gd, Y)与共晶α-Mg构成主要的腐蚀微电偶,Mg_5(Gd, Y)作为阳极被优先腐蚀并沿晶界向内部发展,合金由此发生腐蚀并在腐蚀初期形成晶间腐蚀的形貌特征。随着Gd、Y元素含量的增加,Mg_5(Gd, Y)化合物的数量增多,共晶α-Mg的腐蚀电位正移,导致腐蚀微电偶的电极面积和电动势相应增大,合金的电偶腐蚀程度加剧,耐腐蚀性降低。
关键词(KeyWords): GWK镁合金;Gd、Y元素含量;微观组织;微电偶腐蚀
基金项目(Foundation): 内蒙古自治区科技项目(2020GG0318)
作者(Author): 窦志伟,郭锋,康裕,闫晨曦,蔡会生
DOI: 10.13289/j.issn.1009-6264.2023-0595
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