铝热反应法制备Mo增强铜基纳米复合材料的组织与性能Microstructure and property of Mo reinforced copper matrix nanocomposites prepared by thermite reaction
郭铁明,付迎,贾建刚,唐中杰,金硕,吉瑞芳
摘要(Abstract):
采用铝热反应-自蔓延烧结法制备了钼质量分数分别为5%、10%、20%的Mo增强铜基复合材料。采用X射线衍射仪、光学显微镜、扫描电镜和透射电镜分析了复合材料的物相及微观组织形貌,并研究了钼添加量对复合材料力学性能、导电性能、热膨胀系数的影响。结果表明:该工艺制得的复合材料基体晶粒尺寸均达到纳米级,致密度均达到90%以上,硬度较纯铜提高40%以上,导电性能良好(72%IACS以上)。随着钼质量分数的增加,复合材料的硬度增加,致密度、电导率及热膨胀系数下降。当钼质量分数为20%时,复合材料的致密度为91.88%,电导率为72%IACS,硬度是纯铜的2倍,热膨胀系数较纯铜降低了13%,综合性能最佳。复合材料硬化的主要机理为强化相钼和铜基体弹性模量差别引起的模量硬化。
关键词(KeyWords): 铝热反应-自蔓延烧结;Mo;铜基纳米复合材料;力学性能;物理性能
基金项目(Foundation): 国家自然科学基金(51461029);; 甘肃省有色金属新材料重点实验室开放基金(SKL1307);; 兰州理工大学红柳青年基金项目(Q201203)
作者(Author): 郭铁明,付迎,贾建刚,唐中杰,金硕,吉瑞芳
DOI: 10.13289/j.issn.1009-6264.2015.08.002
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