再论钢和β铜基合金中贝氏体相变形核机制Re-discussion on the mechanism of bainite nucleation in steels and β copper base alloys
康沫狂,朱明
摘要(Abstract):
在试验用钢和β铜基合金固溶后等温或时效时,贝氏体孕育期是母相中溶质原子向晶体缺陷处和〈001〉晶向上扩散偏聚(形成贫、富溶质原子小区)的过程,即渐变(量变)阶段,为贝氏体形核做准备。当贫溶质小区贫化到以等温或时效温度作为Ms点的成分时,该小区即能进行马氏体样贝氏体切变形核,为突变(质变)阶段。孕育期也是一个受溶质原子扩散控制的过程。贝氏体形核是由过饱和的贝氏体和原始母相间溶质原子浓度差而产生的驱动力驱动。初期贝氏体有马氏体性质,是过饱和的。
关键词(KeyWords): 贝氏体;孕育期;切变形核;相变基元;类Spinodal分解
基金项目(Foundation):
作者(Author): 康沫狂,朱明
参考文献(References):
- [1]Kurjumov G.Trans AIME,1933,105:253-255,In discussiontothe paper entitled studies up Widmanstatten structure,ⅣThe iron-carbon alloys by MehlRF,Barret C S and Smith D W.Publishedin Trans.AIME,1933,105:218.
- [2]Klier E P,Liman T.The bainite reactionin hypoeutectoid steels[J].Trans AIME,1944,158:394.
- [3]Ko T,Cottrel S A.The formation of bainite[J].JISI,1952,172:307.
- [4]Ko T.The formation of bainite in an En21 steel[J].JISI,1953,175:16.
- [5]Entin RI.Elementaryreactioninthe austenite→pearlite andthe austenite→bainite transformation,in Decomposition of Austenite by Diffusion Processes,edited by Zacky VF,Aaronson HI,Inter Science Publishers,NewYork,1962:295.
- [6]Entin RI.钢中贝氏体转变[M].中国工业出版社,1965.
- [7]Aaronson HI,Domain HA,Pound G M.Thermodynamics of the austenite→proeutectoidferrite[J].Trans TMS-AIME,1966,236:753.
- [8]Hsu TY(Xu Zuyao),Mou Y.Thermodynamics of the bainite transformationin Fe-Calloys[J].Acta Metall,1984,32:1469.
- [9]Mou Y,Hsu TY.Bainite formationinlowcarbon Cr-Ni steels[J].Metall Trans A,1988,19A:1695.
- [10]Hsu TY(Xu zuyao).Onthe bainite formation[J].Metall Trans A,1990,21:811.
- [11]Hehemann RF.The bainite transformation,Phase transformations[M].ASM,Metals Park,Ohio,1970:397.
- [12]Hehemann RF,Kinsman K R,Aaronson HI.Adebate onthe bainite reaction[J].Metall Tarans A,1972,3:1077.
- [13]LimC,Wutting M.Prebainite phenomenonin AISI86B80 and 0.5C-5.3Ni steel[J].Acta Metall,1974,22:1215.
- [14]Bojarski Z,Bolds T.Structures and properties of carbon-free bainite[J].Acta Metall,1974,22:1223.
- [15]Bhadeshia HK D H,The bainite transformation:Unresolvedissues[J].Mater Sc and Eng A,1999,237(275):258.
- [16]Caballero F G,Bhadeshia HK D H,et al.Very stronglowtemperature bainite[J].Mater Sci Technol,2002,18:279.
- [17]Garwood R D.J Inst Met,1954-1955,83:64.(转引自余德刚,王世道.贝氏体相变理论[M].上海交通大学出版社,1998:33).
- [18]Garwood R D,Hull D.The orientation relationships of lowtemperature martensite transformationin meta-stableβ-brass[J].Acta Metall,1954,6:98.
- [19]Cornelis I,Wayman C M.Phase transformationin metastableβ′-CuZn alloys-Ⅱ.Isothermal transformation[J].Acta Metall,1974,22:301.
- [20]Wu MH,Hamada Y,Wayman C M.Transformation ofα1in Cu-Zn-Al alloys[J].Metall Mater Trans,1994,25A(12):2581.
- [21]Takezawa K,Sato S.Nucleation and growth of bainite crystals in Cu-Zn-Al alloys[J].Metall Trans,1990,21A:1541.
- [22]Chattopadhyay K,Araonson HI.Interfacial structure and crystallographic study of transformationin beta′and beta Cu-Zn alloys,I.Isothermal formation ofalpha sub 1 plates frombeta′[J].Acta Metall,1986,34:695,713.
- [23]Jiang L X,Lu W,Jiang B H,Hsu TY(Xsu Z Y).Kinetic characteristics of bainiteformationin Cu-Zn-Al alloys[J].Transaction of Nonferrous Metals Societyof China,1991,1:57.
- [24]Lu W,Jiang B,Hsu TY(Xsu Z Y).Non-inheritance of ordering of parent phase duringthe bainite formation[J].Scripta Metall,1992,27:861.
- [25]Lu W,Jiang B,Xu Z Y.Morphology and structure of transformation productsformed at intermediate temperature in a Cu-Zn-Al alloy[J].Trans Non-ferrousMetals Society of China,1992,2:51.
- [26]Hsu TY(Xu Zuyao),Zhou X W.Thermodynamics considerationformation mechanismofα1plateinβ-Cu-base alloys[J].Metall Mater Trans A,1994,25A:2555.
- [27]徐祖耀.材料热处理的进展和展望[J].材料热处理学报,2003,24(1):1.
- [28]Zhang X,Jin XJ,Hsu TY(Xu Zuyao).Nucleation mechanismfor bainite[J].JMST,2002,18(1):1.
- [29]Cohen M(eds).Symposiumoninternational conference on bainite[J].Metall Trans A,1990,21A(4,6):767,1343.
- [30]Wayman C M,Aaronson HI.Onthe roles of shear and diffusioninthe formation of plate-shapedtransformation products[J].Matall Mater Trans A,1994,25A(9,12):781,2549.
- [31]Kang MK,Yang Y Q,Wei Q M.Meng X K.Onthe pre-bainite phenomenonin some alloys[J].Metall Mater Trans A,1994,25A(9):1941.
- [32]康沫狂,朱明.关于贝氏体形核和台阶机制———与徐祖耀院士等商榷[J].2005,24(2):1.
- [33]徐祖耀,金学军.简论贝氏休相变的形核与长大———复康沫狂教授等[J].材料热处理学报,2005,26(6):1.
- [34]Kang MK,Zhou M,Zhang MX.Mechanismof bainite Nucleationin steel,iron and cupper alloys[J].JMST,2005,21(4):437.
- [35]Wu XL,Zhang X Y,Meng X K,et al.Formation of carbon poor-regions during pre-bainite transformation[J].Mater Letters,1995,22:141.
- [36]Kang Mo-kuang,Zhang Ming-xing,Zhu Ming.In-situ observation of bainite growth duringisothermal holding[J].Acta Mater,2006,54:2127.
- [37]Kang MK,Sun J L,Yang Q M.Hightemperature transmission electron microscopyin-situstudy of lower bainite carbide precipitation[J].Metall Trans A,1990,214:853.
- [38]Vasudevan P,GrahamL M,Axon HJ.The kinetics of bainite formationin a plain carbon steel[J].JISI,1958,12:386.
- [39]Radcliffe S V,Rollason E C.The kinetics of the formation of bainite in high-purityiron-carbon alloys[J].JISI,1959,1:56.
- [40]Bhadeshia HK D H.Bainite in steels[M].Cambridge University Press,1992:156.
- [41]Kang Mo-kuang,Qin Xing-pu,Yang Yan-qing.Meta-banitic heat treatment in steels,Proc of the Asian conf on heat treatment of materials,Bejing,ChinaMachine Press,1998:155.
- [42]林慧国,傅代直.钢的奥氏体转变曲线———原理、测试和应用[M].北京:机械工业出版社,1988:234-235,48.
- [43]康沫狂,杨思品,管敦惠.钢中贝氏体[M].上海:上海科学技术出版社,1990:127.
- [44]徐祖耀,刘世楷.贝氏体相变与贝氏体[M].北京:科学出版社,1991:134.
- [45]Xie Z Y,Kang MK,Wu XL.Regular thermodynamic model for interstitial iron-carbon solution[J].Acta Metall Mater,1994,42:1825.
- [46]Wozniak TZ.Austenite double decompositioninto bainite in high carbon steels[J].Advance in Materials Science,2005,5,3(8):80.
- [47]俞德刚,王世道.贝氏体相变理论[M].上海:上海交通大学出版社,1998:20.
- [48]Shen HM,Zhang Z F,Yang Y Q,et al.The pre-bainite transformationin Cu-Zn-Al-Mn alloy[J].Acta Metall Mater,1994,42:657.
- [49]张丽萍,李福金,张思涛,郑肇豪.Cu-Zn-Al记忆合金成份对记忆性的影响[J].机械工程材料,1990,2:7.
- [50]Zhou X W,Hsu TY(Xu Z Y).Thermodynamics of the martensite transformationin Cu-Zn-Al alloys[J].Acta Metall Mater,1991,39(6):1045.
- [51]孟祥康,康沫狂,洪建明.Cu-Zn-Al贝氏体和贝氏体/相界面的精细结构[J].电子显微学报,1994,4:270.
- [52]孟祥康,康沫狂,杨延清,刘东慧.β′→α1型贝氏体相变初期切变行为[J].自然科学进展———国家重点实验室通讯,1993,3:219.
- [53]Meng X K,Kang MK,Yang Y Q,et al.The formation mechanismof plate in beta Cu-Zn-Al alloys[J].Metall Trans A,1993,24A:1.
- [54]Porter D A,Easterling KE.Phase transformationin metals and alloys,Van Nostrand Reinhold Company,NewYork-Cincinnati-Toronto-London-Meibourne,1981:303,353,281-282.
- [55]Friedel J.位错[M].王煜译.北京:科学出版社,1984:235,271.
- [56]Kubo H,Cornils l A,Wayman C M.Morphology and characteristics of spinodally decomposedβbrass[J].Acta Metall,1980,28:405.
- [57]徐祖耀.贝氏体相变简介[J].热处理,2006,21(6):1.
- [58]Kang MK,Chen D M,Yang S P,Hu GL.Time-temperature-transformation diagrams within the mediumrange in some alloy steels[J].Metall Trans A,1992,23A:785.
- [59]孟祥康,陈大明,杨延清,康沫狂.有序βCuZnAl合金贝氏体相变的体激活能的考察[J].金属科学和工艺,1992,11(3,4):7.
- [60]乌曼斯基,芬克尔什坦,布兰捷尔,等.金属物理学基础(物理金属学)[M].中科院金属研究所译,北京:科学出版社,1958:255.
- [61]Massalski TB.Massive transformation,Phase Transformation[M].American Societyfor Metals,Ohio,1970:465.
- [62]Wits J J,Kop TA,Leeuwen YV,et al.Astudy all the austenite-to-ferrite phasetransformationin binarysubstitutional iron alloys[J].Mater Sci Eng,2000,A283:234.
- [63]侯赠寿,赵兴国,侯文艺,梁伟.界面过程控制生长≠扩散控制[J].材料热处理学报,2005,26(3):6.
- [64]侯增寿,马晓霞.相变分类及热力学分析商榷[J].金属热处理,2006,31(增刊):20.
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