氟锆酸钾对AZ31镁合金微弧氧化膜层的影响Effect of K2ZrF6 on coatings of AZ31 magnesium alloy prepared by micro-arc oxidation
庄俊杰,宋仁国,项南,宋若希,熊缨,胡强,王超
摘要(Abstract):
在磷酸盐碱性电解液中加入氟锆酸钾(K_2ZrF_6),利用微弧氧化技术(MAO)在AZ31镁合金表面制备了陶瓷膜层,研究了电解液中K_2ZrF_6对MAO膜层的形貌、相组成和耐腐蚀性能等的影响。结果表明,电解液中添加K_2ZrF_6能使MAO膜层变得更加均匀,也降低了膜层的表面粗糙度,所形成的MAO膜层主要是由Mg O,Mg F2和Zr O2相组成。长时间浸泡和电化学测试结果表明,电解液中添加K_2ZrF_6提高了MAO膜层的耐蚀性。本实验电解液中添加2.5 g/L K_2ZrF_6时,所形成的MAO膜层的耐蚀性最好,而过高浓度K_2ZrF_6会对膜层的耐蚀性产生负作用。
关键词(KeyWords): AZ31镁合金;氟锆酸钾;微弧氧化;显微结构;耐蚀性
基金项目(Foundation): 国家自然科学基金(51371039);; 江苏省材料表面科学与技术重点实验室开放课题
作者(Author): 庄俊杰,宋仁国,项南,宋若希,熊缨,胡强,王超
DOI: 10.13289/j.issn.1009-6264.2016.09.028
参考文献(References):
- [1]Zhang J,Gu Y H,Guo Y J,et al.Electrochemical behavior of biocompatible AZ31 magnesium alloy in simulated body fluid[J].Journal of Materials Science,2012,47(13):5197-5204.
- [2]郅青,高瑾,董超芳,等.AZ91D镁合金微弧氧化膜的腐蚀行为研究[J].金属学报,2008,44(8):986-990.ZHI Qing,GAO Jin,DONG Chao-fang,et al.Corrosion behavior of microarc oxidation film on AZ91D magnesium alloy[J].Acta Metallurgica Sinica,2008,44(8):986-990.
- [3]王淑艳,夏永平,刘莉.电解质对AZ91D镁合金微弧氧化的影响[J].材料热处理学报,2012,33(9):122-128.WANG Shu-yan,XIA Yong-ping,LIU Li.Effects of electrolyte on microarc oxidation of AZ91D magnesium alloy[J].Transactions of Materials and Heat Treatment,2012,33(9):122-128.
- [4]Su P,Wu X,Guo Y,et al.Effects of cathode current density on structure and corrosion resistance of plasma electrolytic oxidation coatings formed on ZK60 Mg alloy[J].Journal of Alloys and Compounds,2009(4758):773-777.
- [5]杨巍,蒋百灵,鲜林云.溶质离子在镁合金微弧氧化氧化膜形成过程中的作用[J].材料热处理学报,2009,30(1):157-160.YANG Wei,JIANG Bai-ling,XIAN Lin-yun.Effects of solute ions on forming process of microarc oxidation coatings on magnesium alloy[J].Transactions of Materials and Heat Treatment,2009,30(1):157-160.
- [6]车广东,刘向东.AZ91D表面微弧氧化陶瓷层形貌及磨损特性分析[J].材料热处理学报,2015,36(6):181-184.CHE Guang-dong,LIU Xiang-dong.Morphology and wear resistance of ceramic coating on surfaces of AZ91D alloy prepared by micro-arc oxidation[J].Transactions of Materials and Heat Treatment,2015,36(6):181-184.
- [7]李小成,郝建民,张亚明,等.电参数对镁合金微弧氧化膜层生长的影响及耐蚀性研究[J].热加工工艺,2012(12):108-110.LI Xiao-cheng,HAO Jian-min,ZHANG Ya-ming,et al.Effects of electrical parameters on growth of Mg alloy micro-arc oxidation coating and corrosion resistance[J].Hot Working Technology,2012(12):108-110.
- [8]Hussein R O,Northwood D O,Nie X.The effect of processing parameters and substrate composition on the corrosion resistance of plasma electrolytic oxidation(PEO)coated magnesium alloys[J].Surface and Coatings Technology,2013(237):357-368.
- [9]尚伟,陈白珍,石西昌,等.添加剂对AZ91D镁合金微弧氧化膜的影响[J].稀有金属材料与工程,2009,38(2):335-338.SHANG Wei,CHEN Bai-zhen,SHI Xi-chang,et al.Effects of electrolyte additives on the performance of micro-arc oxide films on AZ91D magnesium alloy[J].Rare Metal Materials and Engineering,2009,38(2):335-338.
- [10]Liu F,Shan D Y,Song Y W,et al.Corrosion behavior of the composite ceramic coating containing zirconium oxides on AM30 magnesium alloy by plasma electrolytic oxidation[J].Corrosion Science,2011,53(11):3845-3852.
- [11]Yao Z P,Gao H H,Jiang Z H,et al.Structure and properties of Zr O2ceramic coatings on AZ91D Mg alloy by plasma electrolytic oxidation[J].Journal of the American Ceramic Society,2008,91(2):555-558.
- [12]Liang J,Srinivasan P B,Blawert C,et al.Comparison of electrochemical corrosion behaviour of Mg O and Zr O2coatings on AM50 magnesium alloy formed by plasma electrolytic oxidation[J].Corrosion Science,2009,51(10):2483-2492.
- [13]葛延峰,蒋百灵,王聪婕,等.镁合金微弧氧化陶瓷层形成及生长过程[J].材料热处理学报,2014,35(12):190-194.GE Yan-feng,JIANG Bai-ling,WANG Cong-jie,et al.Research on formation and growth process of ceramic coatings on magnesium alloy by micro-arc oxidation[J].Transactions of Materials and Heat Treatment,2014,35(12):190-194.
- [14]Liang J,Guo B G,Tian J,et al.Effect of potassium fluoride in electrolytic solution on the structure and properties of microarc oxidation coatings on magnesium alloy[J].Applied Surface Science,2005,252(2):345-351.
- [15]蒋百灵,张淑芬,吴国建,等.镁合金微弧氧化陶瓷层显微结构缺陷与相组成及其耐蚀性[J].中国有色金属学报,2002,12(3):454-457.JIANG Bai-ling,ZHANG Shu-fen,WU Guo-jian,et al.Microflaw and phases constitution of ceramic coating formed by micro-arc oxidation on magnesium alloys and their influence on corrosion-resisitance[J].The Chinese Journal of Nonferrous Metals,2002,12(3):454-457.
- [16]Ghasemi A,Raja V S,Blawert C,et al.The role of anions in the formation and corrosion resistance of the plasma electrolytic oxidation coatings[J].Surface and Coatings Technology,2010,204(9/10):1469-1478.
- [17]Arrabal R,Matykina E,Hashimoto T,et al.Characterization of AC PEO coatings on magnesium alloys[J].Surface and Coatings Technology,2009,203(16):2207-2220.
- [18]Cui X J,Lin X Z,Liu C H,et al.Fabrication and corrosion resistance of a hydrophobic micro-arc oxidation coating on AZ31 Mg alloy[J].Corrosion Science,2015(90):402-412.
- [19]Gao R,Liu Q,Wang J,et al.Fabrication of fibrous szaibelyite with hierarchical structure superhydrophobic coating on AZ31 magnesium alloy for corrosion protection[J].Chemical Engineering Journal,2014(241):352-359.
- [20]Song G,Atrens A,John D S,et al.The anodic dissolution of magnesium in chloride and sule phate solutions[J].Corrosion Science,1997(39):1981-2004.
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