热输入对22%Cr超低Ni双相不锈钢焊接热影响区组织和耐蚀性的影响Effect of heat input on microstructure and corrosion resistance of welding heat affected zone of 22%Cr ultra-low nickel duplex stainless steel
夏高令,杨银辉,李赵中
摘要(Abstract):
采用动电位极化和双环电化学动电位再活化法(DL-EPR)等研究了不同焊接热输入对超低Ni双相不锈钢热影响区(HAZ)耐蚀性的影响,采用光学显微镜(OM)和透射电镜(TEM)对热影响区的组织结构进行表征。结果表明,热输入后使热影响区的耐腐蚀元素Cr、Mo来不及向铁素体(δ)充分扩散,导致δ相点蚀当量值(PREN)低于奥氏体(γ)相。在热输入为8.48~25.42 kJ/cm的范围内,热影响区中因魏氏奥氏体(WA)出现以及δ相中Cr_2N析出,降低了其耐点蚀性能,点蚀主要集中在δ相上。热输入为29.35 kJ/cm时冷却速率降低,导致热影响区中WA以及δ相中Cr_2N减少,获得了最大点蚀电位E_b,为0.26 V。热影响区中晶内奥氏体(IGA)和晶界奥氏体(GBA)含量的增加和粗化,降低了γ/δ两相界面数量并覆盖了部分δ/δ晶界,使热影响区获得最小晶间敏感值R_a,为58.3%,具有较好的耐晶间腐蚀性能。
关键词(KeyWords): 超低Ni双相不锈钢;热输入;点腐蚀;晶间腐蚀
基金项目(Foundation): 国家自然科学基金(51861019)
作者(Author): 夏高令,杨银辉,李赵中
DOI: 10.13289/j.issn.1009-6264.2022-0656
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