Y2O3对反应烧结Si3N4/SiC复相陶瓷组织和性能的影响Effect of yttrium oxide additives on microstructure and properties of reaction-sintered Si3N4/SiC multiphase ceramics
耿桂宏,罗绍华,毕晓露,武聪,陈宇红,韩非
摘要(Abstract):
以低压铸造用升液管为研究目的,以Y2O3-Al2O3-Fe2O3为复合烧结助剂,磨切单晶硅废料Si粉和SiC为主料,反应烧结法制备Si3N4/SiC复相陶瓷。研究了Y2O3含量对复合材料结构和力学性能的影响,采用XRD、SEM对复合材料的相组成、微观形貌进行分析。结果表明,反应烧结后试样生成Si3N4结合SiC晶粒为主相的烧结体,并含有少量Sialon晶须及未反应的Si。Y2O3含量对复相陶瓷力学性能影响很大,在分析稀土Y2O3作用机理的基础上,得到2.5%Y2O3优化试样的力学性能优良,相对密度达到88%,维氏硬度达到1.1 GPa,常温抗弯强度50 MPa。
关键词(KeyWords): Si3N4/SiC复相陶瓷;Y2O3;烧结助剂;反应烧结;力学性能
基金项目(Foundation): 宁夏自然科学基金资助项目(NZ0843);; 中央高校基本科研业务费(N100423002);; 河北省应用基础研究计划重点基础研究项目(09963910D);; 北方民族大学自主科研资金项目(1102)
作者(Author): 耿桂宏,罗绍华,毕晓露,武聪,陈宇红,韩非
DOI: 10.13289/j.issn.1009-6264.2012.07.005
参考文献(References):
- [1]Wu X C,Song W H,Huang W D,et al.Simultaneous growth ofα-Si3N4 andβ-SiC nanorods[J].Mater Res Bull,2001,36:847-852.
- [2]Takahashi K,Hisashi M,Yoshida S,et al.Improvement of static fatigue strength of Si3N4/SiC crack-healed under cyclic stress[J].Journal of theEuropean Ceramic Society,2005,25:1953-1959.
- [3]Luo F,Zhu D M,Zhang H,et al.Properties of reaction-bonded SiC/Si3N4 ceramics[J].Mater Sci Eng A,2006,431:285-289.
- [4]Luo F,Zhu D M,Su X L,et al.Properties of hot-pressed of SiC/Si3N4 nanocomposites[J].Mater Sci Eng A,2007,458:7-10.
- [5]Gao J M,Xiao H N,Du H Q.Effect of Y2O3 addition on ammono sol-gel synthesis and sintering of Si3N4-SiC nanocomposite powder[J].CeramicsInternational,2003,29:655-661.
- [6]Baldacim S A,Santos C,Silva O M M,et al.Ceramics composites Si3N4-SiC(W)containing rare earth concentrate(CRE)as sintering aids[J].Mater Sci Eng A,2004,367:312-316.
- [7]Zemanova M,Lecomte E,Sajgalik P,et al.Polysilazane derived micro/nano Si3N4/SiC composites[J].Journal of the European Ceramic Society,2002,22:2963-2968.
- [8]王零森.特种陶瓷[M].湖南:中南大学出版社,2005:193-194.
- [9]Hirano T,Niihara K.Microstructure and mechanical properties of Si3N4/SiC composites[J].Materials Letters,1995,22:249-254.
- [10]Baldacim S A,Santos C,Strecker K,et al.Development and characterization by HRTEM of hot-pressed Si3N4-SiC(W)composites[J].Journal ofMaterials Processing Technology,2005,169:445-451.
- [11]董文麟.氮化硅陶瓷[M].北京:中国建筑工业出版社,1987:52.
- [12]Ohashi M,Kanzaki S,Tabata H.Processing mechanical properties and oxidation behavior of silicon oxynitride ceramics[J].Journal of the AmericanCeramic Society,1991,74(1):109-114.
- [13]周玉.陶瓷材料学[M].北京:科学出版社,2004:342-346.
- [14]Hirano T,Ohji T,Niihara K.Effects of matrix grain size on the mechanical properties of Si3N4/SiC nanocomposites densified with Y2O3[J].Materials Letters,1996,27:53-58.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||