锆对20碳钢在锌合金液中腐蚀行为的影响Effect of zirconium on corrosion behavior of carbon steel in molten zinc alloy
刘亚,刘靓,吴长军,王建华,苏旭平
摘要(Abstract):
在20碳钢和Zn-6%Al-3%Mg合金液中分别添加0.6%Zr,用扫描电镜和X射线衍射仪研究了锆元素对20碳钢在Zn-6%Al-3%Mg锌合金液中腐蚀行为的影响。结果表明:20碳钢在510℃的Zn-6%Al-3%Mg和Zn-6%Al-3%Mg-0.6%Zr合金液中的腐蚀程度都随侵蚀时间的增加而增大,但是20碳钢在Zn-6%Al-3%Mg-0.6%Zr合金液中的腐蚀程度明显减轻。随着侵蚀温度的升高,20碳钢在Zn-6%Al-3%Mg-0.6%Zr合金液中的腐蚀深度由缓慢增加转为急剧增大,为减少Zn-6%Al-3%Mg-0.6%Zr合金液对碳钢的腐蚀程度,热浸镀锌温度应低于510℃。含0.6%Zr的20碳钢在Zn-6%Al-3%Mg合金液中经过长时间侵蚀后,可形成较厚的致密Fe-Al化合物层,使含锆20碳钢的腐蚀速率明显低于20碳钢,因此在钢中添加0.6%的锆元素可提高钢制锌锅的使用寿命。
关键词(KeyWords): 20碳钢;锆;Fe-Al合金层;腐蚀行为
基金项目(Foundation): 国家自然科学基金(51271041)
作者(Author): 刘亚,刘靓,吴长军,王建华,苏旭平
DOI: 10.13289/j.issn.1009-6264.2018-0347
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