形变热处理对定向凝固Cu-Ni-Sn合金组织与性能的影响Effect of thermomechanical treatment on microstructure and properties of directionally solidified Cu-Ni-Sn alloy
孙子强,肖柱,李翰冬,张玉芳,贾延琳,甘雪萍
摘要(Abstract):
通过ProCAST软件模拟了定向凝固温度场分布,优化了定向凝固工艺,制备了?13 mm Cu-15Ni-8Sn合金棒材。首先对合金进行固溶处理,随后进行冷拉拔变形及时效处理。采用光学显微镜、透射电镜、显微硬度仪和力学试验机等研究了合金经不同工艺处理后的组织和性能。结果表明:固溶态棒材经65%冷拉拔变形后,硬度从121 HV上升到了285 HV,平均晶粒尺寸由15.7μm下降到0.94μm。变形态合金组织呈纤维状,形成较强的<111>//X_0方向的丝织构;变形态合金线材在380℃时效过程中,先发生调幅分解,然后析出DO_(22)有序相,60 min时合金硬度达到峰值399 HV,抗拉强度为1446 MPa;时效时间继续延长,进入过时效态,开始析出长条状不连续析出相(DO_3相),其长大形成层片状结构,导致合金性能急剧下降。
关键词(KeyWords): Cu-15Ni-8Sn合金;定向凝固;力学性能;冷拉拔
基金项目(Foundation): 国家重点研发计划(2021YFB3700700);; 国家自然科学基金(52071342)
作者(Author): 孙子强,肖柱,李翰冬,张玉芳,贾延琳,甘雪萍
DOI: 10.13289/j.issn.1009-6264.2024-0174
参考文献(References):
- [1] 李岳桥.热处理工艺对铜镍锡合金力学性能和微观组织的影响[D].太原:中北大学,2021.LI Yue-qiao.Effect of heat treatment process on mechanical properties and microstructure of Cu-Ni-Sn alloy[D].Taiyuan:North University of China,2021.
- [2] 刘洋.高弹性Cu-15Ni-8Sn合金的制备工艺研究[D].北京:北京有色金属研究总院,2013.LIU Yang.Preparation technology of Cu-15Ni-8Sn alloy with high elasticity[D].Beijing:Beijing General Research Institute of Nonferrous Metals,2013.
- [3] 乐海荣,孙德生,吴阳阳,等.喷射成形Cu-15Ni-8Sn合金的显微组织与性能[J].上海钢研,1997(5):18-26.LE Hai-rong,SUN De-sheng,WU Yang-yang,et al.Microstructure and properties of spray formed Cu-15Ni-8Sn alloy[J].Journal of Shanghai Steel & Iron Research,1997(5):18-26.
- [4] Wang J,Zhou X,Li J.Evolution of microstructures and properties of SLM-manufactured Cu-15Ni-8Sn alloy during heat treatment[J].Additive Manufacturing,2020(37):101599.
- [5] Ouyang Y,Gan X P,Zhang S Z,et al.Age-hardening behavior and microstructure of Cu-15Ni-8Sn-0.3Nb alloy prepared by powder metallurgy and hot extrusion[J].Transactions of Nonferrous Metals Society of China,2017,27(9):1947-1955.
- [6] 田宁,赵国旗,张萍,等.热处理对DZ125定向凝固合金组织结构与蠕变行为的影响[J].金属热处理,2022,47(8):188-194.TIAN Ning,ZHAO Guo-qi,ZHANG Ping,et al.Effect of heat treatment on microstructure and creep behavior of directionally solidified alloy DZ125[J].Heat Treatment of Metals,2022,47(8):188-194.
- [7] Liao W,Qiang H,Song W,et al.Effect and mechanism of room temperature rolling,cryogenic rolling and heat treatment on mechanical properties and electrical conductivity of Cu-Ni-Si alloy with continuous directional solidification[J].Journal of Alloys and Compounds,2023,949:169748.
- [8] Wang M,Yang Q R,Jiang Y B,et al.Microstructure evolution and mechanical property of directionally solidified Cu-9Ni-6Sn alloy wire during aging[J].Journal of Materials Research and Technology,2022,21:474-485.
- [9] 刘国怀,张相龙,耿小奇,等.抽拉速率对定向凝固DZ4125合金温度场及晶粒竞争生长的影响[J].航空材料学报,2023,43(2):17-24.LIU Guo-huai,ZHANG Xiang-long,GENG Xiao-qi,et al.Effect of withdrawal rates on temperature field and grain competitive growth of directionally solidified DZ4125 alloy[J].Journal of Aeronautical Materials,2023,43(2):17-24.
- [10] 宗学文,张斌.DD4合金发动机叶片的定向凝固过程数值模拟[J].真空科学与技术学报,2018,38(8):726-729.ZONG Xue-wen,ZHANG Bin.Numerical simulation on directional solidification of DD4 alloy airplane engine blade[J].Chinese Journal of Vacuum Science and Technology,2018,38(8):726-729.
- [11] 胡鹏,李军,李建国.基于ProCast的镍基单晶高温合金数值模拟[J].热加工工艺,2018,47(1):117-120.HU Peng,LI Jun,LI Jian-guo.Numerical simulation of Ni-based single crystal superalloy based on ProCast[J].Hot Working Technology,2018,47(1):117-120.
- [12] 王檬.铜铁合金的制备及其相关基础研究[D].长沙:中南大学,2021.WANG Meng.Preparation and basic research of Cu-Fe alloy[D].Changsha:Central South University,2021.
- [13] Shi Y F,Guo C J,Yuan M Q,et al.Effect of solidification rate on dendrite segregation and mechanical properties of Cu-15Ni-8Sn alloy prepared by directional solidification[J].Journal of Iron and Steel Research International,2023,30(8):1586-1597.
- [14] 马牧之,李周,肖柱,等.晶界工程处理对超微合金化无氧铜的组织结构与耐热性的影响[J].中国有色金属学报,2022,32(2):386-395.MA Mu-zhi,LI Zhou,XIAO Zhu,et al.Effect of grain boundary engineering treatment on microstructure and thermal stability of an ultra-microalloyed oxygen-free copper[J].Transactions of Nonferrous Metals Society of China,2022,32(2):386-395.
- [15] Yang F,Dong L M,Cai L,et al.Effect of cold drawing strain on the microstructure,mechanical properties and electrical conductivity of low-oxygen copper wires[J].Materials Science and Engineering A,2021,818:141348.
- [16] Sathiaraj G D,Pukenas A,Skrotzki W.Texture formation in face-centered cubic high-entropy alloys[J].Journal of Alloys and Compounds,2020,826:154183.
- [17] Yang S,Song K,Zhou Y,et al.Research progress on Cu-15Ni-8Sn alloys:The effect of microalloying and heat treatment on microstructure and properties[J].Materials,2023,16(17):5913.
- [18] Jiang K X,Zhou Y J,Yang R,et al.Nanophase transformation and strengthening-toughening mechanism of the Cu-15Ni-8Sn alloy during aging[J].Journal of Materials Research and Technology,2023,27:2201-2215.
- [19] 单运启,张彦敏,张朝民,等.形变热处理对Cu-Ni-Si合金组织性能的影响[J].材料热处理学报,2024,45(1):95-102.SHAN Yun-qi,ZHANG Yan-min,ZHANG Chao-min,et al.Effect of thermomechanical treatment on microstructure and properties of Cu-Ni-Si alloy[J].Transactions of Materials and Heat Treatment,2024,45(1):95-102.
- [20] Liu S C,Guo Z K,Zhang S,et al.Effect of B addition on microstructures and properties of Cu-15Ni-8Sn alloy[J].Journal of Alloys and Compounds,2023,947:169644.
- [21] Cheng J J,Gan X P,Li Z,et al.Wear map for sliding wear behavior of Cu-15Ni-8Sn alloy against bearing steel under oil-lubricated condition[J].Journal of Central South University,2020,27(2):311-324.
- [22] 成金娟.超高强耐磨耐蚀Cu-15Ni-8Sn合金的制备及相关性能研究[D].长沙:中南大学,2020.CHENG Jin-juan.Preparation and relative properties research of Cu-15Ni-8Sn alloy with ultrahigh strength,wear and corrosion resistance[D].Changsha:Central South University,2020.
- [23] Guo Z K,Jie J C,Liu J M,et al.Effect of cold rolling on aging precipitation behavior and mechanical properties of Cu-15Ni-8Sn alloy[J].Journal of Alloys and Compounds,2020,848:156275.
- [24] 罗金宝,巢国辉,项燕龙,等.形变热处理对Cu-Sn-P合金微观组织及性能的影响[J].材料热处理学报,2023,44(2):46-52.LUO Jin-bao,CHAO Guo-hui,XIANG Yan-long,et al.Effect of thermomechanical treatment on microstructure and properties of Cu-Sn-P alloy[J].Transactions of Materials and Heat Treatment,2023,44(2):46-52.
- [25] Wang N,Shen Y,An Q,et al.Microstructure evolution and mechanical property of Cu-15Ni-8Sn-0.2 Nb alloy during aging treatment[J].Journal of Materials Science & Technology,2021,86:227-236.
- [26] Jiang Y X,Li Z,Xiao Z,et al.Microstructure and properties of a Cu-Ni-Sn alloy treated by two-stage thermomechanical processing[J].JOM,2019,71(8):2734-2741.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||