热处理温度对YAG粉体及其多孔陶瓷合成的影响Effect of heat treating temperature on synthesis of YAG powders and porous ceramics
宋杰光,李养良,王芳,李世斌,纪岗昌,许婷,熊勇锋
摘要(Abstract):
采用共沉淀法合成的钇铝石榴石(YAG)粉体真空烧结制备多孔陶瓷,通过分析讨论表明,YAG前驱体中绝大部分吸附水蒸发以及绝大部分Al(OH)3和Y(OH)3的分解分别转变成Al2O3和Y2O3失去离子水而产生的失重出现在600℃以下完成。YAG前驱体在1100℃下煅烧后,大量YAG晶相已经形成,而且具有完整的晶型。升高煅烧温度对晶粒尺寸和晶粒形貌的影响显著,也说明YAG粉体颗粒粒径和形貌对最终煅烧温度非常敏感。采用真空烧结技术,成功制备了孔结构均匀规整,大部分微孔径处于5μm左右,且外形保持良好的YAG多孔陶瓷,综合考虑性价比,确定YAG多孔陶瓷的烧结温度为1500℃较为适宜。
关键词(KeyWords): 钇铝石榴石粉体;多孔陶瓷;热处理温度;显微结构
基金项目(Foundation): 国家973计划子项目(5133102);; 江西省教育厅科学技术研究项目(GJJ10614);; 江西省教育科学“十一五”规划课题(09YB449);; 九江学院质量工程项目(10SFXJYS09)
作者(Author): 宋杰光,李养良,王芳,李世斌,纪岗昌,许婷,熊勇锋
DOI: 10.13289/j.issn.1009-6264.2012.05.005
参考文献(References):
- [1]李江,潘裕柏,张俊计,等.共沉淀法制备钇铝石榴石(YAG)纳米粉体[J].硅酸盐学报,2003,31(5):490-493.LI Jiang,PAN Yu-bai,ZHANG Jun-ji,et al.Synthesizing yttrium aluminun garnet(YAG)nanopowder by co-pricipitation method[J].Journal of theChinese Ceramic Society,2003,31(5):490-493.
- [2]Wang S J.Synthesis of yttrium aluminum garnet(YAG)from an ethylenediaminetetraacetic acid precursor[J].Materi Sci Eng B,2006,127:203-206.
- [3]宋杰光,王秀琴,李养良,等.放电等离子烧结ZrB2-YAG-Al2O3复相陶瓷的氧化性能研究[J].材料热处理学报,2010,31(4):10-13.SONG Jie-guang,WANG Xiu-qin,LI Yang-liang,et al.Oxidation resistance of ZrB2-YAG-Al2O3 composite ceramics fabricated by spark plasmasintering[J].Transactions of Materials and Heat Treatment,2010,31(4):10-13.
- [4]Zarzecka M.YAG powder synthesis by the modified citrate process[J].Journal of the European Ceramic Society,2007,27:593-597.
- [5]Frage N,Kalabukhov S,Sverdlov N,et al.Densification of transparent yttrium aluminum garnet(YAG)by SPS processing[J].Journal of the EuropeanCeramic Society,2010,30:3331-3337.
- [6]Laine R M.A new YAG phase produced by liquid-feed flame spray pyrolysis[J].Advanced Materials,2005,17(7):830-833.
- [7]Fernandez A.Highly porous yttrium aluminium garnet(YAG)particles synthesised by a gel supported precipitation(GSP)process[J].Journal ofMaterials Science,2003,38,2331-2335.
- [8]Zhang Y M,Yu H M.Synthesis of YAG powders by the co-precipitation method[J].Ceramics International,2009,35:2077-2081.
- [9]Wang S J,Xu Y B,Lu P.X.Synthesis of yttrium aluminum garnet(YAG)from an ethylenediaminetetraacetic acid precursor[J].Materials Scienceand Engineering B,2006,127:203-206.
- [10]宋杰光,李世斌,纪岗昌,等.合成条件对YAG粉体粒径及显微形貌的影响[J].兵器材料科学与工程,2010,33(6):7-10.SONG Jie-Guang,LI Shi-bin,JI Gang-chang,et al.Effect of synthesis conditions on the particle size and micrograph of YAG powders[J].OrdnanceMaterial Science and Engineering,2010,33(6):7-10.
- [11]闻雷,孙旭东,马伟民.固相反应法制备YAG透明陶瓷[J].硅酸盐学报,2003,31(9):819-822.WEN Lei,SUN Xu-dong,MA Wei-min.Fabrication of transparent YAG ceramics by a solid-state reaction method[J].Journal of the Chinese CeramicSociety,2003,31(9):819-822.
- [12]赵郝炎,廖梅松,胡丽丽.热处理对共沉淀法制备YAG纳米粉体性能的影响[J].人工晶体学报,2006,35(2):395-399.ZHAO Hao-yan,LIAO Mei-song,HU Li-li.Influence of heat treatment on the properties of YAG nano-sized powder by co-precipitation method[J].Journal of Synthetic Crystals,2006,35(2):395-399.
- [13]JiD C,Kim D K,Kriven W M.Sintering behavior of gehlenite.Part I:Self-forming,macro-mesoporous gehlenite-pore-forming mechanism,microstructure,mechanical,and physical properties[J].Journal of American Ceramic Society,2007,90:1760-1773.
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