GNPs-Cu/Ti6Al4V复合材料热压烧结工艺优化及组织性能Optimization of hot pressing sintering process and microstructure and properties of GNPs-Cu/Ti6Al4V composites
邹豫,张剑平,罗军明
摘要(Abstract):
以TC4钛合金粉为基体,石墨烯(GNPs)为增强相,采用真空热压法制备了质量分数为0.3%的GNPs-Cu/Ti6Al4V复合材料。通过正交试验探讨了烧结温度、压力、保温时间对复合材料相对密度、显微硬度和抗压强度的影响。结果表明:烧结温度是影响复合材料相对密度、显微硬度和抗压强度的关键因素,压力和保温时间对其影响较小。最优的烧结工艺为温度1150℃、压力35 MPa和保温时间40 min,此时复合材料的相对密度、显微硬度和抗压强度最佳,分别为99.34%,585.4 HV0.1和2382 MPa。GNPs-Cu/Ti6Al4V复合材料中主要除α-Ti和β-Ti外,还存在TiC和Ti_2Cu相,在其压缩断口有较完整GNPs存在。
关键词(KeyWords): GNPs-Cu/Ti6Al4V复合材料;真空热压烧结;正交试验;微观组织;力学性能
基金项目(Foundation): 国家自然科学基金(51764041)
作者(Author): 邹豫,张剑平,罗军明
DOI: 10.13289/j.issn.1009-6264.2021-0067
参考文献(References):
- [1] Yeh C L,Chen W H,Hsu C C.Formation of titanium silicides Ti5Si3 and TiSi2 by self-propagating combustion synthesis[J].Journal of Alloys and Compounds,2006,432(1):90-95.
- [2] Kumar P,Prakash O,Ramamurty U.Micro-and meso-structures and their influence on mechanical properties of selectively laser melted Ti6Al4V[J].Acta Materialia,2018,154(8):246-260.
- [3] Banerjee D,Williams J C.Perspectives on titanium science and technology[J].Acta Materialia,2013,61(3):844-879.
- [4] Hu Y B,Zhao B,Ning F D,et al.In-situ ultrafine three-dimensional quasi-continuous network microstructural TiB reinforced titanium matrix composites fabrication using laser engineered net shaping[J].Materials Letters,2017,195(5):116-119.
- [5] 黄陆军,耿林,彭华新.钛合金与钛基复合材料第二相强韧化[J].中国材料进展,2019,38(3):214-222.HUANG Lu-jun,GENG Lin,PENG Hua-xin.Strengthening and toughening mechanisms of the second phase in titanium alloys and titanium matrix composites[J].Meterial China,2019,38(3):214-222.
- [6] 徐祥,宋玲玲,官雨柔,等.石墨烯增强金属基复合材料制备方法的研究进展[J].材料热处理学报,2019,40(5):24-31.XU Xiang,SONG Ling-ling,GUAN Yu-rou,et al.Research progress in preparation of graphene reinforced metal matrix composites[J].Transactions of Materials and Heat Treatment,2019,40(5):24-31.
- [7] 凌自成,闫翠霞,史庆南,等.石墨烯增强金属基复合材料的制备方法研究进展[J].材料导报,2015,29(7):143-149.LING Zi-cheng,YAN Cui-xia,SHI Qin-nan,et al.Recent progress in preparation methods for metal matrix composite materials reinforced with graphene nanosheets[J].Materials Review,2015,29(7):143-149.
- [8] 郭强,赵蕾,李赞,等.金属材料的石墨烯强韧化[J].中国材料进展,2019,38(3):205-213+250.GUO Qiang,ZHAO Lei,LI Zan,et al.Strengthening and toughening of graphene-reinforced metal matrix composites[J].Material China,2019,38(3):205-213+250.
- [9] Hee K C,Diana Y S,Jaheon K,et al.A route to high surface area,porosity and inclusion of large molecules in crystals[J].Nature:International Weekly Journal of Science,2004,427(6974):523-527.
- [10] Hu Z,Tong G,Lin D,et al.Graphene-reinforced metal matrix nanocomposites-a review[J].Materials Science and Technology,2016,32(9):930-953.
- [11] 孙峰,王凯旋,杨辉,等.石墨烯增强钛基复合材料制备工艺与性能研究[J].钛工业进展,2019,36(1):8-12.SUN Feng,WANG Kai-xuan,YANG Hui,et al.Investigation of graphene reinforced titanium matrix composites preparation process and properties[J].Titanium Industry Progress,2019,36(1):8-12.
- [12] 李岩,张晓臣,宋美慧,等.石墨烯增强钛合金的研究进展[J].黑龙江科学,2018,9(13):14-15.LI Yan,ZHANG Xiao-chen,SONG Mei-hui,et al.Recent progress on graphene/titanium alloy[J].Heilongjiang Science,2018,9(13):14-15.
- [13] 王伟,周海雄,王庆娟,等.石墨烯增强钛基复合材料的摩擦学性能研究[J].兵器材料科学与工程,2019,42(1):26-32.WANG Wei,ZHOU Hai-xiong,WANG Qin-juan,et al.Tribological properties of graphene reinforced titanium matrix composites[J].Ordnance Material Science and Engineering,2019,42(1):26-32.
- [14] 苏颖,左倩,杨刚,等.石墨烯增强钛基复合材料的压缩变形行为研究[J].稀有金属材料与工程,2017,46(12):3882-3886.SU Ying,ZUO Qian,YANG Gang,et al.Compressive properties of the grahpene reinforced titanium composites[J].Rare Metal Materials and Engineering,2017,46(12):3882-3886.
- [15] 姚敬,鲁世强,肖璇,等.热压参数对Laves相TaCr2合金组织及性能的影响[J].材料热处理学报,2017,38(4):54-59.YAO Jin,LU Shi-qiang,XIAO Xuan,et al.Effect of hot pressing parameters on microstructure and mechanical properties of TaCr2 Laves phase alloys[J].Transactions of Materials and Heat Treatment,2017,38(4):54-59.
- [16] 贾碧,李晓博,潘复生,等.热压烧结温度对石墨烯/氧化铝复合材料力学性能的影响[J].材料导报,2020,34(24):24001-24004.JIA Bi,LI Xiao-bo,PAN Fu-sheng,et al.The effect of hot-pressing sintering temperature on graphene-reinforced alumina matrix composites[J].Materials Reports,2020,34(24):24001-24004.
- [17] 吴小龙.细晶复合材料Ti2AlC/Ti-44Al的制备和性能研究[D].重庆:重庆大学,2018.WU Xiao-long.Preparation and mechanical properties of Ti2AlC/Ti-44Al refined composites[D].Chongqing:Chongqing University,2018.
- [18] 李多生,吴文政,周贤良,等.石墨烯/Al复合材料的微观结构及力学性能[J].中国有色金属学报,2015,25(6):1498-1504.LI Duo-sheng,WU Wen-zheng,ZHOU Xian-liang,et al.Microstructure and mechanical properties of graphene/Al composites[J].The Chinese Journal of Nonferrous Metals,2015,25(6):1498-1504.
- [19] Zhao Z Y,Guan R G,Guan X H,et al.Microstructures and properties of graphene-Cu/Al composite prepared by a novel process through clad forming and improving wettability with copper[J].Advanced Engineering Materials,2015,17(5):663-668.
文章评论(Comment):
|
||||||||||||||||||
|
||||||||||||||||||