选区激光熔化合成Ni-Al合金层的组织与性能Microstructure and properties of Ni-Al alloy layer synthesized by selective laser melting
王长浩,叶宏,沈大臣,汪砚青
摘要(Abstract):
采用选区激光熔化技术在20钢基体表面制备了Ni-Al合金层。研究了激光工艺参数对合金层宏观形貌的影响,确定了较优工艺参数。利用扫描电镜(SEM)、X射线衍射(XRD)、能谱仪(EDS)和HVS-1000硬度测试仪等研究了合金层的物相组成、组织形貌、成分分布和硬度。结果表明:在优化工艺参数下利用选区激光熔化技术可在20钢表面制备出组织致密、无明显缺陷且与基体具有良好冶金结合的Ni-Al合金层,合金层主要由Ni3Al和ɑ-Ni两相组成,表层为细小致密的等轴晶,合金层中部为柱状晶,底部为胞状树枝晶,合金层表层显微硬度达到548 HV0. 2,随着与表面距离的增加,显微硬度逐渐降低。脉宽、电流的增加和扫描速率的降低,均可增加合金层宽度;脉宽、扫描速率和电流的增加,合金层的层厚都呈现出先增大后降低的趋势,其中电流180 A,扫描速率150 mm/min,脉宽4. 0 ms,频率12 Hz为最佳工艺。
关键词(KeyWords): 选区激光熔化;Ni-Al合金;激光工艺参数;显微组织;显微硬度
基金项目(Foundation): 重庆理工大学研究生创新基金(YCX2018224);; 重庆市大学生创新创业项目(201711660008)
作者(Author): 王长浩,叶宏,沈大臣,汪砚青
DOI: 10.13289/j.issn.1009-6264.2019-0204
参考文献(References):
- [1]刘六法,卢晨,翟春泉,等.激光退火对Inconel718微观组织和硬度的影响[J].稀有金属材料与工程,2005,34(3):501-504.LIU Liu-fa,LU Chen,ZHAI Chun-quan,et al.Effects of laser annealing on microstructures and hardness of Inconel 718[J]. Rare Metal Materials and Engineering,2005,34(3):501-504.
- [2] Liu F C,Lin X,Yang G L,et al.Microstructure and residual stress of laser rapid formed Inconel 718 nickel-base superalloy[J].Optics and Laser Technology,2011,43(1):208-213.
- [3] Cao J,Liu FC,Lin X,et al.Effect of overlap rate on recrystallization behaviors of laser solid formed Inconel 718 superalloy[J].Optics and Laser Technology,2013,45:228-235.
- [4]杨胶溪,王艳芳,王志成.激光熔覆制备Ni/Ni3Al基双性能材料及其内部微观组织分析[J].中国激光,2015,42(3):199-205.YANG Jiao-xi,WANG Yan-fang,WANG Zhi-cheng. Laser cladding Ni/Ni3Al based double performance materials and internal microstructure analysis[J].Chinese Journal of Lasers,2015,42(3):199-205.
- [5]李强,黄多辉,曹启龙,等.高压下Ni3Al热力学性质的第一性原理研究[J].原子与分子物理学报,2013,30(5):798-803.LI Qiang,HUANG Duo-hui,CAO Qi-long,et al.Thermodynamic properties of Ni3Al under pressure via first-principles calculations[J].Journal of Atomic and Molecular Physics,2013,30(5):798-803.
- [6] Caprio L,Demir A G,Previtali B.Influence of pulsed and continuous wave emission on melting efficiency in selective laser melting[J].Journal of Materials Processing Technology,2018,266:429-441.
- [7] Kourtidou D,Chaliampalias D,Teknetzi A,et al.Synthesis of Al-Ni coatings by pack cementation and examination of their high temperature oxidation resistance[J].AIP Conference Proceedings,2019,2075(1):1-5
- [8] Domitra K,Domitrios C,Christos V,et al. Deposition of Ni-Al coatings by pack cementation and corrosion resistance in high temperature and marine environments[J].Corrosion Science,2018,148:12-23
- [9]李明菲,彭晓,王福会.新型细晶Ni_3Al涂层的制备及其循环氧化行为研究[J].哈尔滨工程大学学报,2011,32(4):536-540.LI Ming-fei,PENG Xiao,WANG Fu-hui. Processing and cyclic oxidation of a novel fine-grained Ni3Al coating[J]. Journal of Harbin Engineering University,2011,32(4):536-540.
- [10]李明菲,彭晓,王福会.新型细晶Ni_3Al涂层的高温氧化行为[J].中国腐蚀与防护学报,2011,31(6):414-418.LI Ming-fei,PENG Xiao,WANG Fu-hui.High temperature oxidation behavior of a novel fine-grained Ni3Al coating[J].Journal of Chinese Society for Corrosion and Protection[J].2011,31(6):414-418.
- [11]沈丹青,桂军,张诗怡,等.真空热压法原位合成铁基表面Ni_3Al涂层的研究[J].广州化工,2018,46(15):70-72.SHEN Dan-qing,GUI Jun,ZHANG Shi-yi,et al.Study on hot pressing synthesis of Ni3Al coating on matrix surface[J].Guangzhou Chemical Industry,2018,46(15):70-72.
- [12]林鑫,黄卫东.应用于航空领域的金属高性能增材制造技术[J].中国材料进展,2015,34(9):684-688.LIN Xin,HUANG Wei-dong. High performance metal additive manufacturing technology applied in aviation field[J]. Materials China,,2015,34(9):684-688.
- [13]蒲飞,刘元富,徐向阳,等.激光表面合金化制备Ti C/Ni3Al复合涂层组织及Ti C演变规律[J].材料热处理学报,2014,35(11):185-189.PU Fei,LIU Yuan-fu,XU Xiang-yang,et al.Microstructure and Ti C evolution behavior of Ti C/Ni3Al composite coating produced by laser surface alloying[J].Transactions of Materials and Heat Treatment,2014,35(11):185-189.
- [14]程广萍,韩众亚,高国璨,等.激光反应合成Ni-Al金属间化合物涂层[J].材料热处理学报,2014,35(11):155-160.CHENG Guang-ping,HAN Zhong-ya,GAO Guo-can,et al. Ni-Al intermetallic coatings prepared by laser cladding and reaction synthesis[J].Transactions of Materials and Heat Treatment,2014,35(11):155-160.
- [15] Saurav M,Manowar H,Ankit G,et al. Fabrication and characteristic evaluation of direct metal laser sintered Si C particulate reinforced Ti6Al4V metal matrix composites[J].Journal of Laser Applications,2019,31(1):012005.
- [16]张小伟.金属增材制造技术在航空发动机领域的应用[J].航空动力学报,2016,31(1):10-16.ZHANG Xiao-wei.Application of metal additive manufacturing in aero-engine[J].Journal of aerospace power,2016,31(1):10-16.
- [17] Xia M J,Gu D D,Ma C L,et al. Fragmentation and refinement behavior and underlying thermodynamic mechanism of WC reinforcement during selective laser melting of Ni-based composites[J].Journal of Alloys and Compounds,2019,777:693-702.
- [18] Murr L E,Gaytan S M,Ramirez D A,et al. Metal fabrication by additive manufacturing using laser and electron beam melting technologies[J].Journal of Materials Science and Technology,2012,28(1):1-14.
- [19] Md T R,Russell M,Hussein M,et al. 3D printed high performance strain sensors for high temperature applications[J].Journal of Applied Physics,2018,123(2):024501.
- [20] Norman S,Vicki K,Josiah D,et al.Ultrasonic assessment of additive manufactured Ti-6Al-4V[J].AIP Conference Proceedings,2018,1949(1):020008.
- [21] Tan J H,Wai L E W,Kenneth W,et al.An overview of powder granulometry on feedstock and part performance in the selective laser melting process[J].Additive Manufacturing,2017,18:228-255.
- [22] Gu D D,Shi Q M,Lin K J,et al.Microstructure and performance evolution and underlying thermal mechanisms of Ni-based parts fabricated by selective laser melting[J].Additive Manufacturing,2018,22:265-278.
- [23]赵剑峰,马智勇,谢德巧,等.金属增材制造技术[J].南京航空航天大学学报,2014,46(5):675-683.ZHAO Jian-feng,MA Zhi-yong,XIE De-qiao,et al. Metal additive manufacturing technique[J]. Journal of Nanjing University of Aeronautics&Astronautics,2014,46(5):675-683.
- [24] Alex R,Katherine T G,Alex M B,et al.Designing for big area additive manufacturing[J].Additive Manufacturing,2019,25:275-285
- [25] Abid H,Mohd J,Anil S,et al.Additive manufacturing applications in cardiology:A review[J].The Egyptian Heart Journal,2018,70(4):433-441.
- [26]段锦,吴君,端木繁一,等.激光能量密度分布的测量方法[J].吉林大学学报(理学版),2009,47(2):311-316DUAN Jin,WU Jun,DUANMU Fan-yi,et al.Method for measuring laser energy density distribution[J].Journal of Jilin University(Science Edition),2009,47(2):311-316
- [27]唐淑君,刘洪喜,张晓伟,等.H13钢表面激光选区熔覆Ni-Al金属间化合物涂层的组织与性能[J].红外与激光工程,2014,43(5):1621-1626.TANG Shu-jun,LIU Hong-xi,ZHANG Xiao-wei,et al. Microstructure and property of selective laser cladding Ni-Al intermetallic compound coating on H13 steel surface[J].Infrared and Laser Engineering,2014,43(5):1621-1626.
- [28]陆必志,龙坚战.Ni-Al金属间化合物合成机理的研究[J].硬质合金,2011,28(5):276-282.LU Bi-zhi,LONG Jian-zhan.Study on the synthesis mechanism of Ni-Al intermetallic compound[J].Cemented Carbide,2011,28(5):276-282.
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